Tensile deformation and fracture characteristics of polyimide/montmorillonite nanocomposite films are investigated to enhance the particular mechanical properties and understand the effective factors in dominating the...Tensile deformation and fracture characteristics of polyimide/montmorillonite nanocomposite films are investigated to enhance the particular mechanical properties and understand the effective factors in dominating the mechanical properties of nanocomposites, such as the nanolayer, matrix and nanolayer/matrix interface. How to contribute to the mechanical properties of nanocomposite film is a very complex problem. In this paper, these factors are analyzed based on the addition amount and fracture mechanics. The results indicate that the specimen at 20 wt% MMT breaks prematurely with a fracture strength （σb = 78 MPa） much lower than that （σb = 128 MPa） at the 1 wt% MMT. However, the Young＇s modulus （3.2 GPa） of the former is higher than that （1.9 GPa） of the latter. Fractography also indicates that the brittle cracking formed in high content addition is the main cause of failure but microscopically ductile fracture morphology still exists locally. And for the trace element addition, the smaller threading slipping veins are evenly distributed on the entire fracture section of these films. Therefore, these characteristics would presumably be associated with both the concentration effects of size of nanocomposite sheets and the increasing deformation harmony in nanolayers.展开更多
基金Project supported by the National Basic Research Program of China (No.2004CB619304)the Hundred TalentsProgram of Chinese Academy of Sciences, Key Research Programme of Beijing City Science and Technology Committee(No.H020420020230).
文摘Tensile deformation and fracture characteristics of polyimide/montmorillonite nanocomposite films are investigated to enhance the particular mechanical properties and understand the effective factors in dominating the mechanical properties of nanocomposites, such as the nanolayer, matrix and nanolayer/matrix interface. How to contribute to the mechanical properties of nanocomposite film is a very complex problem. In this paper, these factors are analyzed based on the addition amount and fracture mechanics. The results indicate that the specimen at 20 wt% MMT breaks prematurely with a fracture strength （σb = 78 MPa） much lower than that （σb = 128 MPa） at the 1 wt% MMT. However, the Young＇s modulus （3.2 GPa） of the former is higher than that （1.9 GPa） of the latter. Fractography also indicates that the brittle cracking formed in high content addition is the main cause of failure but microscopically ductile fracture morphology still exists locally. And for the trace element addition, the smaller threading slipping veins are evenly distributed on the entire fracture section of these films. Therefore, these characteristics would presumably be associated with both the concentration effects of size of nanocomposite sheets and the increasing deformation harmony in nanolayers.
