A mathematical model was developed to describe the interaction of multiple physical fields in a slag bath during electroslag remelting (ESR) process with a current-conductive mould. The distributions of current dens...A mathematical model was developed to describe the interaction of multiple physical fields in a slag bath during electroslag remelting (ESR) process with a current-conductive mould. The distributions of current density, magnetic induction intensity, electromagnetic force, Joule heating, fluid flow and temperature were simulated. The model was verified by temperature measurements during remelting 12CrMoVG steel with a slag of 50wt%-70wt% CaF2, 20wt%-30wt% CaO, 10wt%-20wt% A1203, and 〈10wt% SiO2 in a 600 mm diameter current-conductive mould. There is a good agreement between the calculated temperature results and the measured data in the slag bath. The calculated results show that the maximum values of current density, electromagnetic force and Joule heating are in the region between the comer electrodes and the conductivity element. The characteristics of current density distribution, magnetic induction intensity, electromagnetic force, Joule heating, velocity patterns and temperature profiles in the slag bath during ESR process with current-conductive mould were analyzed.展开更多
Electroslag casting(ESC)is an important method to produce high quality castings.In this study,the ESC up-pulling inner mold method(EUPIM)was used to produce hollow cylindrical castings with the multiple consumable ele...Electroslag casting(ESC)is an important method to produce high quality castings.In this study,the ESC up-pulling inner mold method(EUPIM)was used to produce hollow cylindrical castings with the multiple consumable electrodes.The radial deformation,the axial and radial internal stress of the inner mold,and the axial internal stress of the slag shell were analyzed using the finite element method(FEM)with the aid of ANSYS software.The ProCAST software was used to calculate the specific heat,heat conductivity and density curve of Cu.Simulation results show that the radial deformation,the axial and radial internal stress of the inner mold,and the axial internal stress of the slag shell near the slag-metal interface of hollow cylndrical casting gradually increase from 0 s to 360 s after the ESC starting(slagging)process but before applying the up-pulling force.The suitable initial up-pulling moment of the inner mold is at around 180-198 s after the starting process.展开更多
Experimental investigation and thermodynamic calculation were carried out to study the effect of slag on alloying elements during electroslag remelting with developing a thermodynamic model to control titanium and alu...Experimental investigation and thermodynamic calculation were carried out to study the effect of slag on alloying elements during electroslag remelting with developing a thermodynamic model to control titanium and aluminum in in got.The thermodynamic model based on ion and molecule coexistence theory and conservation law of element atoms was established to analyze the change in aluminum and titanium along the height of ingot.The results show that low CaO slag is suitable for electroslag remelting of metal containing high titanium-to-aluminum ratio.As electroslag remelting process consists of slag temperature-rising and temperature-stable periods,TiO2 should be added into water-cooled copper mold during temperature-rising period in order to keep the thermodynamic equilibrium between titanium and aluminum,and the amount of TiO2 is the difference value calculated by the reaction between titanium and alumina at 1477 and 1677℃.展开更多
With ificreasing demand for large cylindrical forgings, a new technology--electroslag remelting (ESR) for direct manufacture of hollow ingots rather than solid ingots has been developed. The main features of the pro...With ificreasing demand for large cylindrical forgings, a new technology--electroslag remelting (ESR) for direct manufacture of hollow ingots rather than solid ingots has been developed. The main features of the process include a T-shaped current supplying mould (CSM), double power supply, an ingot withdrawing system, a metal level automatic control system based on a level sensor using the electromagnetic eddy current method, and the exchange of a consumable multi-electrode. ANSYS software was used to calculate the fluid flow and heat transfer in the slag bath 1 and metal pool of this ESR hollow ingot process with its T-shaped CSM. The mathematmal model was Verified by measuring the geometry of the liquid metal pool as observed in the macrostructure of 4650 mm (external diameter)/ 4450 mm (internal diameter) hollow ingots by sulphur print method: the. observed shape and depth of the s!ag bath were consistent with the simulated results. Simulation of the ESR process can improve understanding of the process and allow better operating parameters to be selected.展开更多
The composition of a slag system has been shown to be particularly important and influential for the new technology of electroslag remelting withdrawal process.The oxidation of the GH984G alloy elements,in contact wit...The composition of a slag system has been shown to be particularly important and influential for the new technology of electroslag remelting withdrawal process.The oxidation of the GH984G alloy elements,in contact with different contents of CaF_(2)–CaO–Al_(2)O_(3)–MgO–TiO_(2)–SiO_(2)in various slag systems,has been investigated in the present study by performing slag–metal equilibrium experiments and ion and molecule coexistence theory analysis.The results show that CaF_(2)and MgO have only a minor effect on the oxidation rates of Al and Ti in the GH984G superalloys.However,it was found that SiO_(2)would intensify the oxidation degree of Al and Ti,and Al was found to become easier oxidized than Ti.Moreover,CaO was found to reduce the activity of SiO_(2)and,thereby,also the oxidation degree of Al and Ti.Also,TiO_(2)was found to reduce the oxidation rate of Ti and instead increase the oxidation rate of Al.Finally,the effect of Al_(2)O_(3)on the oxidation of Al and Ti was observed to be opposite to that of TiO_(2).The calculated results were found to be in good agreement with experimental measurements.Moreover,viscosity experiments showed that CaO would rapidly increase the viscosity of the slag at low temperatures,and that the viscosity of the slag would increase with an increase in SiO_(2)content.展开更多
55Cr17Mo1VN high nitrogen martensitic stainless steel is usually applied to the high-quality mold,which is largely produced by the pressurized electro slag remelting process.The microstructure evolution of quenching a...55Cr17Mo1VN high nitrogen martensitic stainless steel is usually applied to the high-quality mold,which is largely produced by the pressurized electro slag remelting process.The microstructure evolution of quenching and tempering heat treatment were investigated and an optimal heat treatment process to achieve excellent mechanical properties was found out.The main precipitates in the steel included carbon-rich type M_(23)C_(6) and nitrogen-rich type M_(2)N.With increasing austenitizing temperature,the equivalent diameter of the precipitates got fined,and retained austenite content increased significantly when the austenitizing temperature exceeded 1020℃.The fracture mode gradually changed from brittle fracture to ductile fracture with increasing tempering temperature from 200 to 550℃.The experimental steel tempered at 350℃ achieved a good combination of hardness(60.6 HRC)and strength(2299.2 MPa)to meet service requirements.Flake M_(23)C_(6) precipitated along martensite lath boundaries and the secondary hardening phenomenon occurred when the tempering temperature was 450℃.Due to the high nitrogen content,M_(2)N precipitated from the inside of laths and matrix when tempered at 550℃.展开更多
Current-conductive mold was recently developed to extend electroslag remelting(ESR)functions to overcome some solidification defects by changing the current path.The macrostructures,microstructures,macrosegregation,an...Current-conductive mold was recently developed to extend electroslag remelting(ESR)functions to overcome some solidification defects by changing the current path.The macrostructures,microstructures,macrosegregation,and microsegregation of the Inconel 718 ingots produced by the custom laboratory-scale ESR furnace under different current paths(the classical ESR and the single power,and two circuits ESR process with current-conductive mold(ESR-STCCM))with the same power input were compared and investigated.The results indicate that when the ingot was produced during ESR and ESR-STCCM processes,at the same power input,the pool depth was 104 and 90 mm,respectively.A flatter and shallower molten pool was obtained during ESR-STCCM process.Moreover,compared with a classical ESR ingot,the cooling rate of the centerline of ESR-STCCM ingot was increased from 12.7 to 16.7 K min^(−1).The increased cooling rates caused by decreased melting rate and thinner slag skin reduced the growth angle of columnar crystal to the vertical axis and the secondary dendrite arm spacing.Furthermore,the macrosegregation and microsegregation of segregation elements for ESR-STCCM process were dramatically reduced compared with ESR process.The average volume fraction of Laves phase was reduced from 7.39%to 6.14%,and the segregation of Nb in Laves phase was significantly reduced.展开更多
A numerical model coupled with a multi-physical field based on dynamic formation of slag skin is established.After validation by comparing the experimental and simulation results of depth of metal pool,slag skin thick...A numerical model coupled with a multi-physical field based on dynamic formation of slag skin is established.After validation by comparing the experimental and simulation results of depth of metal pool,slag skin thickness and melt rate,it is utilized to investigate the effect of melt current on the coupled multi-physical field,slag skin thickness,metal pool depth and the heat flow distribution during electroslag remelting(ESR)Inconel 625 solidification process.The results showed that with the increase in the melt current,the velocities of ESR system and the temperature of metal pool increased,whereas the highest temperature of slag bath firstly decreased and then increased.With the increase in the melt current,the slag skin thickness,metal pool depth and melt rate increased.Furthermore,the characteristics of the heat flow distribution and the effect of melt current on the heat flow distribution were analysed.展开更多
基金supported by China Postdoctoral Science Foundation (No.20100471452)
文摘A mathematical model was developed to describe the interaction of multiple physical fields in a slag bath during electroslag remelting (ESR) process with a current-conductive mould. The distributions of current density, magnetic induction intensity, electromagnetic force, Joule heating, fluid flow and temperature were simulated. The model was verified by temperature measurements during remelting 12CrMoVG steel with a slag of 50wt%-70wt% CaF2, 20wt%-30wt% CaO, 10wt%-20wt% A1203, and 〈10wt% SiO2 in a 600 mm diameter current-conductive mould. There is a good agreement between the calculated temperature results and the measured data in the slag bath. The calculated results show that the maximum values of current density, electromagnetic force and Joule heating are in the region between the comer electrodes and the conductivity element. The characteristics of current density distribution, magnetic induction intensity, electromagnetic force, Joule heating, velocity patterns and temperature profiles in the slag bath during ESR process with current-conductive mould were analyzed.
基金financially supported by the National Natural Science Foundation of China(Nos:51674070,U1560203,51434004,51475313)the Fundamental Research Funds for the Central Universities,China(Grant no.:N162504006)
文摘Electroslag casting(ESC)is an important method to produce high quality castings.In this study,the ESC up-pulling inner mold method(EUPIM)was used to produce hollow cylindrical castings with the multiple consumable electrodes.The radial deformation,the axial and radial internal stress of the inner mold,and the axial internal stress of the slag shell were analyzed using the finite element method(FEM)with the aid of ANSYS software.The ProCAST software was used to calculate the specific heat,heat conductivity and density curve of Cu.Simulation results show that the radial deformation,the axial and radial internal stress of the inner mold,and the axial internal stress of the slag shell near the slag-metal interface of hollow cylndrical casting gradually increase from 0 s to 360 s after the ESC starting(slagging)process but before applying the up-pulling force.The suitable initial up-pulling moment of the inner mold is at around 180-198 s after the starting process.
基金the National Natural Science Foundation of China(Grant Nos.51674070,U1560203 and 51674172)Natural Science Foundation of Jiangsu Province(Grant Nos.BK20150334 and 20150336)the Open Foundation of The State Key Laboratory of Refractories and Metallurgy(Grant No.G201607).
文摘Experimental investigation and thermodynamic calculation were carried out to study the effect of slag on alloying elements during electroslag remelting with developing a thermodynamic model to control titanium and aluminum in in got.The thermodynamic model based on ion and molecule coexistence theory and conservation law of element atoms was established to analyze the change in aluminum and titanium along the height of ingot.The results show that low CaO slag is suitable for electroslag remelting of metal containing high titanium-to-aluminum ratio.As electroslag remelting process consists of slag temperature-rising and temperature-stable periods,TiO2 should be added into water-cooled copper mold during temperature-rising period in order to keep the thermodynamic equilibrium between titanium and aluminum,and the amount of TiO2 is the difference value calculated by the reaction between titanium and alumina at 1477 and 1677℃.
基金Item Sponsored by National Natural Science Foundation of China(51204041)National High Technology Research and Development Program(863 Program) of China(2012AA03A502)+1 种基金Fundamental Research Funds for the Central Universities of China(N130402016)Program for Liaoning's Innovative Research Team in University of China(LT20120008)
文摘With ificreasing demand for large cylindrical forgings, a new technology--electroslag remelting (ESR) for direct manufacture of hollow ingots rather than solid ingots has been developed. The main features of the process include a T-shaped current supplying mould (CSM), double power supply, an ingot withdrawing system, a metal level automatic control system based on a level sensor using the electromagnetic eddy current method, and the exchange of a consumable multi-electrode. ANSYS software was used to calculate the fluid flow and heat transfer in the slag bath 1 and metal pool of this ESR hollow ingot process with its T-shaped CSM. The mathematmal model was Verified by measuring the geometry of the liquid metal pool as observed in the macrostructure of 4650 mm (external diameter)/ 4450 mm (internal diameter) hollow ingots by sulphur print method: the. observed shape and depth of the s!ag bath were consistent with the simulated results. Simulation of the ESR process can improve understanding of the process and allow better operating parameters to be selected.
基金supported by the National Key Research and Development Program(2017YFB0305201)the National Natural Science Foundation of China(Grant Nos.51674070,51874085)"Innovation&Entrepreneurship Talents"Introduction Plan of Jiangsu Province in 2018.
文摘The composition of a slag system has been shown to be particularly important and influential for the new technology of electroslag remelting withdrawal process.The oxidation of the GH984G alloy elements,in contact with different contents of CaF_(2)–CaO–Al_(2)O_(3)–MgO–TiO_(2)–SiO_(2)in various slag systems,has been investigated in the present study by performing slag–metal equilibrium experiments and ion and molecule coexistence theory analysis.The results show that CaF_(2)and MgO have only a minor effect on the oxidation rates of Al and Ti in the GH984G superalloys.However,it was found that SiO_(2)would intensify the oxidation degree of Al and Ti,and Al was found to become easier oxidized than Ti.Moreover,CaO was found to reduce the activity of SiO_(2)and,thereby,also the oxidation degree of Al and Ti.Also,TiO_(2)was found to reduce the oxidation rate of Ti and instead increase the oxidation rate of Al.Finally,the effect of Al_(2)O_(3)on the oxidation of Al and Ti was observed to be opposite to that of TiO_(2).The calculated results were found to be in good agreement with experimental measurements.Moreover,viscosity experiments showed that CaO would rapidly increase the viscosity of the slag at low temperatures,and that the viscosity of the slag would increase with an increase in SiO_(2)content.
基金This research was sponsored by the National Natural Science Foundation of China(Grant Nos.U1960203,U1908223,and 51774074)Talent Project of Revitalizing Liaoning(Grant No.XLYC1902046)+1 种基金State Key Laboratory of Metal Material for Marine Equipment and Application(Grant No.HG-SKL(2019)13)the"Innovation&Entrepreneurship Talents”Introduction Plan of Jiangsu Province in 2018.
文摘55Cr17Mo1VN high nitrogen martensitic stainless steel is usually applied to the high-quality mold,which is largely produced by the pressurized electro slag remelting process.The microstructure evolution of quenching and tempering heat treatment were investigated and an optimal heat treatment process to achieve excellent mechanical properties was found out.The main precipitates in the steel included carbon-rich type M_(23)C_(6) and nitrogen-rich type M_(2)N.With increasing austenitizing temperature,the equivalent diameter of the precipitates got fined,and retained austenite content increased significantly when the austenitizing temperature exceeded 1020℃.The fracture mode gradually changed from brittle fracture to ductile fracture with increasing tempering temperature from 200 to 550℃.The experimental steel tempered at 350℃ achieved a good combination of hardness(60.6 HRC)and strength(2299.2 MPa)to meet service requirements.Flake M_(23)C_(6) precipitated along martensite lath boundaries and the secondary hardening phenomenon occurred when the tempering temperature was 450℃.Due to the high nitrogen content,M_(2)N precipitated from the inside of laths and matrix when tempered at 550℃.
基金This project was supported by the National Natural Science Foundation of China(Grant Nos.51674070,51874085,and U1435205)Also,this project was supported by the Transformation Project of Major Scientific and Technological Achievements in Shenyang(Grant No.Z17-5-003)and the"Innovation&Entrepreneurship Talents”Introduction Plan of Jiangsu Province in 2018.
文摘Current-conductive mold was recently developed to extend electroslag remelting(ESR)functions to overcome some solidification defects by changing the current path.The macrostructures,microstructures,macrosegregation,and microsegregation of the Inconel 718 ingots produced by the custom laboratory-scale ESR furnace under different current paths(the classical ESR and the single power,and two circuits ESR process with current-conductive mold(ESR-STCCM))with the same power input were compared and investigated.The results indicate that when the ingot was produced during ESR and ESR-STCCM processes,at the same power input,the pool depth was 104 and 90 mm,respectively.A flatter and shallower molten pool was obtained during ESR-STCCM process.Moreover,compared with a classical ESR ingot,the cooling rate of the centerline of ESR-STCCM ingot was increased from 12.7 to 16.7 K min^(−1).The increased cooling rates caused by decreased melting rate and thinner slag skin reduced the growth angle of columnar crystal to the vertical axis and the secondary dendrite arm spacing.Furthermore,the macrosegregation and microsegregation of segregation elements for ESR-STCCM process were dramatically reduced compared with ESR process.The average volume fraction of Laves phase was reduced from 7.39%to 6.14%,and the segregation of Nb in Laves phase was significantly reduced.
基金supported by Special funding project for research and development of key core technologies and common technologies in Shanxi Province(20201102017)supported by National Natural Science Foundations of China(Grant No.51874085 and 52274323)the Fundamental Research Funds for the Central Universities(Grant No.N2125030).
文摘A numerical model coupled with a multi-physical field based on dynamic formation of slag skin is established.After validation by comparing the experimental and simulation results of depth of metal pool,slag skin thickness and melt rate,it is utilized to investigate the effect of melt current on the coupled multi-physical field,slag skin thickness,metal pool depth and the heat flow distribution during electroslag remelting(ESR)Inconel 625 solidification process.The results showed that with the increase in the melt current,the velocities of ESR system and the temperature of metal pool increased,whereas the highest temperature of slag bath firstly decreased and then increased.With the increase in the melt current,the slag skin thickness,metal pool depth and melt rate increased.Furthermore,the characteristics of the heat flow distribution and the effect of melt current on the heat flow distribution were analysed.