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WO_(3)/g-C_(3)N_(4)复合光催化剂制备及其可见光催化性能 被引量:6
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作者 黄有鹏 吴福礼 +1 位作者 李兵 杨本宏 《复合材料学报》 EI CAS CSCD 北大核心 2021年第12期4265-4272,共8页
将自制层状石墨相氮化碳(g-C_(3)N_(4))和WO_(3)纳米片均匀混合,经煅烧制备WO_(3)/g-C_(3)N_(4)复合半导体。利用XRD、SEM、TEM、UV-Vis DRS和PL对其进行表征。结果表明,g-C_(3)N_(4)呈现类石墨烯状片层结构,WO_(3)为纳米片状结构,且分... 将自制层状石墨相氮化碳(g-C_(3)N_(4))和WO_(3)纳米片均匀混合,经煅烧制备WO_(3)/g-C_(3)N_(4)复合半导体。利用XRD、SEM、TEM、UV-Vis DRS和PL对其进行表征。结果表明,g-C_(3)N_(4)呈现类石墨烯状片层结构,WO_(3)为纳米片状结构,且分散在g-C_(3)N_(4)表面;与WO_(3)复合后,UV-Vis吸收边发生了红移,拓宽了g-C_(3)N_(4)对可见光的响应。以罗丹明B(RhB)为模拟污染物,考察WO_(3)/g-C_(3)N_(4)的光催化降解性能。WO_(3)/g-C_(3)N_(4)质量比为1∶5时,表现出最佳的光催化活性,可见光照60 min后,RhB降解率可达到94.9%。光催化剂具有良好的稳定性,重复使用6次后,RhB的降解率依然达到88.9%。光催化机制研究表明,超氧自由基(·O^(−)_(2))是光催化降解RhB的主要活性物种。 展开更多
关键词 WO_(3)/g-C_(3)N_(4) 复合半导体 罗丹明B 光催化降解 纳米片
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Paleogeography control of Indian monsoon intensification and expansion at 41 Ma 被引量:14
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作者 Xiaomin Fang Maodu Yan +7 位作者 Weilin Zhang Junsheng Nie Wenxia Han fuli wu Chunhui Song Tao Zhang Jinbo Zan Yongpeng Yang 《Science Bulletin》 SCIE EI CSCD 2021年第22期2320-2328,M0004,共10页
As a crucial part of the Asian monsoon stretching from tropical India to temperate East Asia, the Indian monsoon(IM) contributes predominant precipitation over Asian continent. However, our understanding of IM’s onse... As a crucial part of the Asian monsoon stretching from tropical India to temperate East Asia, the Indian monsoon(IM) contributes predominant precipitation over Asian continent. However, our understanding of IM’s onset, development and the underlying driving mechanisms is limited. Increasing evidence indicates that the IM began in the Eocene or even the Paleocene and was unexceptionally linked to the early rise of the Tibetan Plateau(TP). These were challenged by the heterogeneous and diachronous uplift of the TP and all the reported records were confined to tropical zone under tropical monsoon driven by the Intertropical Convergence Zone(ITCZ) that is irrelevant to the TP. Therefore, reliable paleoclimatic records from the extra-tropical IM region is crucial to reveal how the tropical IM expanded to subtropical and temperate zones and what driving factors might be related to it. Here we present robust Eocene paleoenvironmental records from central Yunnan(~26°N) in subtropical East Asia. The multiproxy results of two sites demonstrate a consistent sudden switch from a dry environment in the early Eocene to a seasonally wet one at 41 Ma, suggesting a jump of the tropical IM to the southern subtropical zone at 41 Ma.The full collision of India with Asia, and the resulting changes in paleogeography at 41 Ma(closure of the Neotethys sea, retreat of the Paratethys seas, fast northward movement of the southern margin of the TP and rise of the central TP), aided by synchronous Antarctic cooling, might have worked together to drive the IM enhancement and northward expansion. 展开更多
关键词 Asia paleogeography Indian tropical monsoon Eocene paleoenvironment Subtropical monsoon onset Driven factors and forcings
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