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基于焦磷酸哌嗪阻燃硬质聚氨酯泡沫制备及性能 被引量:1
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作者 刘梦茹 黄福临 +3 位作者 孙俊杰 刘秀玉 朱庆明 唐刚 《过程工程学报》 CAS CSCD 北大核心 2023年第4期571-579,共9页
能源危机促使建筑材料朝着高质量方向发展,硬质聚氨酯泡沫(RPUF)是性能优异的保温材料,但易点燃,有潜在的安全隐患,因此需要对其进行阻燃处理。焦磷酸哌嗪(PAPP)是一款磷氮复合的阻燃剂,将其添加至RPUF体系中,可解决RPUF阻燃性差的问题... 能源危机促使建筑材料朝着高质量方向发展,硬质聚氨酯泡沫(RPUF)是性能优异的保温材料,但易点燃,有潜在的安全隐患,因此需要对其进行阻燃处理。焦磷酸哌嗪(PAPP)是一款磷氮复合的阻燃剂,将其添加至RPUF体系中,可解决RPUF阻燃性差的问题。采用极限氧指数(LOI)、热重(TG)、锥形量热(CCT)等研究PPAP/RPUF的阻燃性能和燃烧性能。扫描电镜(SEM)展示了RPUF微观泡孔结构,结果表明,PAPP的加入使泡孔结构的不均性和破损性增加。阻燃测试表明:PAPP能有效抑制材料的滴落,添加50wt%的PAPP,复合材料的LOI值最高,为22.7vol%,且UL-94测试通过V-0级别。TG测试表明:PAPP的分解分为三个阶段,其第二阶段的分解速率最大,分解产生的酸性物质使RPUF拥有更高的残炭率,其中PAPP50/RPUF在700℃时残炭量为34.4wt%,炭渣在凝聚相起到阻隔热量和可燃气体的释放的作用;CCT测试证实了PAPP抑制材料燃烧热的释放,其中PAPP50/RPUF燃烧产生的热释放速率峰值(PHRR)和总热释放(THR)较纯样降低了54%和41%。机械测试表明,PAPP使PPAP/RPUF的导热系数增加,抗压强度减少。 展开更多
关键词 硬质聚氨酯泡沫 焦磷酸哌嗪 阻燃 复合材料 热稳定性
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Prevalence and Determinants of Secondhand Smoke Exposure Among Adolescent Girls-China,2019
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作者 fulin huang Xinying Zeng +2 位作者 Xinbo Di Lin Xiao Shiwei Liu 《China CDC weekly》 2022年第44期977-981,共5页
Summary What is already known about this topic?The rate of secondhand smoke(SHS)exposure among female junior high students in 2013-2014 in China was 69.9%.What is added by this report?The rate of SHS among adolescent ... Summary What is already known about this topic?The rate of secondhand smoke(SHS)exposure among female junior high students in 2013-2014 in China was 69.9%.What is added by this report?The rate of SHS among adolescent girls in 2019 in China was 62.8%,with 60.8%in junior high and 65.3%in senior high school,meanwhile,higher SHS exposure was correlated to higher grade levels,senior high school over junior high school,urban areas,those with more pocket money,those who’ve attempted smoking,exposure to tobacco advertisements,those with parents who smoke,those with close friends who smoke,use of e-cigarettes,and belief that SHS exposure is detrimental to health.What are the implications for public health practice?The rate of SHS exposure among adolescent girls in China still remains extraordinarily high.Targeted public health initiatives to curb SHS exposure among adolescent girls are urgently needed in China. 展开更多
关键词 SMOKE EXPOSURE MONEY
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Distribution of methane and its homologues in low-layer atmosphere over eastern China and seas 被引量:1
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作者 fulin huang Xunhua Zhang +3 位作者 Xianghua Xia Zuji Qiang Changgong Lin Yingkai Zhang 《Chinese Science Bulletin》 SCIE EI CAS 1998年第22期1902-1908,共7页
Systematic, fixed_point and long observations and sample testing make clear distributions of methane and the homologues in the low_layer air over eastern China and sea areas. Within about 250 km from epicenter of mode... Systematic, fixed_point and long observations and sample testing make clear distributions of methane and the homologues in the low_layer air over eastern China and sea areas. Within about 250 km from epicenter of moderate and strong earthquakes, oil_gas areas have methane concentration anomaly and CO\-2 anomaly in the low_layer atmosphere around the earthquakes, have a temperature increase by 1-6℃ at the occurrence of moderate and strong earthquakes and indicate that concentration anomaly of methane family in the low_layer air can be used as an important index for petroleum geochemical exploration. 展开更多
关键词 METHANE and HOMOLOGUE low_layer ATMOSPHERE earthquake satellite thermal infrared anomaly.
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