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Solvent-free aerobic oxidation of ethylbenzene over supported Ni catalysts using molecular oxygen at atmospheric pressure 被引量:5
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作者 g.raju P.Shiva Reddy +2 位作者 J.Ashok B.Mahipal Reddy A.Venugopal 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第3期293-297,共5页
We investigated the aerobic oxidation of ethylbenzene in the absence of solvent or any additive carried out over Ni on different types of supports namely SiO2, hydroxyapatite, SBA-15, and USY Zeolites. The oxidation o... We investigated the aerobic oxidation of ethylbenzene in the absence of solvent or any additive carried out over Ni on different types of supports namely SiO2, hydroxyapatite, SBA-15, and USY Zeolites. The oxidation of ethylbenzene activities was measured in a round bottom flask immersed in oil bath at known reaction temperature. The physicochemical characteristics of the catalysts were examined by BET surface area, XRD, FT-IR and the oxidation activities were correlated with the acidities of the catalysts obtained by TPD of NH3. It was observed that both hydroxyapatite and USY (13% Na2O) supported Ni catalysts displayed higher ethylbenzene conversion and 80% selectivity towards acetophenone. 展开更多
关键词 nickel SBA-15 zeolites HYDROXYAPATITE ethylbenzene oxidation TPD of NH3
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Artificial neural network-based merging score for Meta search engine 被引量:2
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作者 P.Vijaya g.raju Santosh Kumar Ray 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第10期2604-2615,共12页
Several users use metasearch engines directly or indirectly to access and gather data from more than one data sources. The effectiveness of a metasearch engine is majorly determined by the quality of the results and i... Several users use metasearch engines directly or indirectly to access and gather data from more than one data sources. The effectiveness of a metasearch engine is majorly determined by the quality of the results and it returns and in response to user queries. The rank aggregation methods which have been proposed until now exploits very limited set of parameters such as total number of used resources and the rankings they achieved from each individual resource. In this work, we use the neural network to merge the score computation module effectively. Initially, we give a query to different search engines and the top n list from each search engine is chosen for further processing our technique. We then merge the top n list based on unique links and we do some parameter calculations such as title based calculation, snippet based calculation, content based calculation, domain calculation, position calculation and co-occurrence calculation. We give the solutions of the calculations with user given ranking of links to the neural network to train the system. The system then rank and merge the links we obtain from different search engines for the query we give. Experimentation results reports a retrieval effectiveness of about 80%, precision of about 79% for user queries and about 72% for benchmark queries. The proposed technique also includes a response time of about 76 ms for 50 links and 144 ms for 100 links. 展开更多
关键词 metasearch engine neural network retrieval of documents ranking list
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