Improved QoS-Secure Routing in MANET Using Real-Time Regional ME Feature Approximation

Mobile Ad-hoc Network(MANET)routing problems are thoroughly studied several approaches are identified in support of MANET.Improve the Quality of Service(QoS)performance of MANET is achieving higher performance.To reduce this drawback,this paper proposes a new secure routing algorithm based on real-time partial ME(Mobility,energy)approximation.The routing method RRME(Real-time Regional Mobility Energy)divides the whole network into several parts,and each node’s various characteristics like mobility and energy are randomly selected neighbors accordingly.It is done in the path discovery phase,estimated to identify and remove malicious nodes.In addition,Trusted Forwarding Factor(TFF)calculates the various nodes based on historical records and other characteristics of multiple nodes.Similarly,the calculated QoS Support Factor(QoSSF)calculating by the Data Forwarding Support(DFS),Throughput Support(TS),and Lifetime Maximization Support(LMS)to any given path.One route was found to implement the path of maximizing MANET QoS based on QoSSF value.Hence the proposed technique produces the QoS based on real-time regional ME feature approximation.The proposed simulation implementation is done by the Network Simulator version 2(NS2)tool to produce better performance than other methods.It achieved a throughput performance had 98.5%and a routing performance had 98.2%.

Evaluation of Codebook Design Using SCMA Scheme Based on A_(n) and D_(n) Lattices

The sparse code multiple access(SCMA)scheme is a Non-Orthogonal Multiple Access(NOMA)type of scheme that is used to handle the uplink com-ponent of mobile communication in the current generation.A need of the 5G mobile network is the ability to handle more users.To accommodate this,the SCMA allows each user to deploy a variety of sub-carrier broadcasts,and several consumers may contribute to the same frequency using superposition coding.The SCMA approach,together with codebook design for each user,is used to improve channel efficiency through better management of the available spectrum.How-ever,developing a codebook with a greater number of value sets is still another challenge.With enhanced techniques of encoding and decoding for 5G networks,mapping the multidimensional constellations in the SCMA system plays a signif-icant role in improving the system performance and enhancing the overall system performance.The creation of a codebook utilizing the SCMA approach in con-junction with the lattice theory is suggested in this study.The prototype is shaped using a popular lattice,such as A n and D n,as the basis.Afterward,from the primary lattice constellation,the multidimensional complex mother constellation with the most noticeable variance in power is discovered.The lattice-based cod-ing is generated by combining the codebooks with the mother constellation,and the codes in the matrices are mapped by rotating the constellations in this context.The suggested technique,in conjunction with the investigation of novel SCMA codebook sets,provides improved performance in terms of Bit Error Rate(BER)and complexity with regard to Signal to Noise Ratio(SNR).Finally,the bit error rate is reduced for various SNRs during transmission in the channel.

Opportunistic Routing with Multi-Channel Cooperative Neighbour Discovery

Due to the scattered nature of the network,data transmission in a dis-tributed Mobile Ad-hoc Network(MANET)consumes more energy resources(ER)than in a centralized network,resulting in a shorter network lifespan(NL).As a result,we build an Enhanced Opportunistic Routing(EORP)protocol architecture in order to address the issues raised before.This proposed routing protocol goal is to manage the routing cost by employing power,load,and delay to manage the routing energy consumption based on theflooding of control pack-ets from the target node.According to the goal of the proposed protocol techni-que,it is possible to manage the routing cost by applying power,load,and delay.The proposed technique also manage the routing energy consumption based on theflooding of control packets from the destination node in order to reduce the routing cost.Control packet exchange between the target and all the nodes,on the other hand,is capable of having an influence on the overall efficiency of the system.The EORP protocol and the Multi-channel Cooperative Neighbour Discovery(MCCND)protocol have been designed to detect the cooperative adja-cent nodes for each node in the routing route as part of the routing path discovery process,which occurs during control packet transmission.While control packet transmission is taking place during the routing path discovery process,the EORP protocol and the Multi-channel Cooperative Neighbour Discovery(MCCND)protocol have been designed to detect the cooperative adjacent nodes for each node in the routing.Also included is a simulation of these protocols in order to evaluate their performance across a wide range of packet speeds using Constant Bit Rate(CBR).When the packet rate of the CBR is 20 packets per second,the results reveal that the EORP-MCCND is 0.6 s quicker than the state-of-the-art protocols,according to thefindings.Assuming that the CBR packet rate is 20 packets per second,the EORP-MCCND achieves 0.6 s of End 2 End Delay,0.05 s of Routing Overhead Delay,120 s of Network Lifetime,and 20 J of Energy Consumption efficiency,which is much better than that of the state-of-the-art protocols.

Photoelectrochemical study of MoO_3 assorted morphology films formed by thermal evaporation

Molybdenum oxide nanostructured thin films were grown on fluorine doped tin oxide（FTO）, indium doped tin oxide（ITO） and ordinary glass substrates by thermal evaporation process without vacuum and catalysts using molybdenum trioxide（MoO） powder as a source material and oxygen as a carrier gas.Various morphologies including nanobelts, disks and hexagonal rod-like nanostructures were obtained by changing the source and substrate temperatures during the growth of MoOthin films. Structural parameters, morphology, composition and surface features of the films were characterized by XRD, SEM, EDAX,XPS, AFM and Raman spectroscopy. The films were orthorhombic in structure with preferred orientation along（0 1 0） plane. Morphology analysis reveals randomly aligned nanobelts with 40 nm in thickness and a width of 800 nm and 3–12 mm in length. The disks have 1.5 μm diameters, 1 μm thickness and hexagonal rod-like nanostructures with a length, breath and width of 2 μm, 1 μm and 100 nm are formed. The samples were investigated under dark and photocurrent conditions in HSOaqueous solution as a function of applied potential. The photocurrent density of samples prepared on ITO and FTO substrate samples were compared and the results are discussed.

Metathesis synthesis, characterization, spectral and photoactivity studies of Ln_(2/3)MoO_4(Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er and Y)

Rare earth ortho-oxomolybdates of composition Ln2/aMoO4 （Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er and Y） were prepared by metathesis reaction. All these materials were characterized by powder X-ray diffraction, Fourier transform-infrared spectroscopy （FT-IR） and UV-Vis diffuse reflectance spectra. The Rietveld analysis of all the samples was carried out to obtain the unit cell parameters and reliability factors. All the materials were crystallized in tetragonal lattice with I41/a space group. The infrared spectra of all the samples were characterized by bands due to MoO42 units. The bandgap energies of all the samples were obtained from UV-Vis DRS spectra. The luminescence spectra of Ln2/3MoO4 （Ln=Pr, Eu and Dy） showed characteristic transitions of the rare earth ions. The visible light photocatalytic activity of all the samples was studied against degradation of methylene blue.

Degradation of Methylene Blue and Rhodamine B Using a New Visible Light-Responsive Photocatalyst, KSb_2PO_(8-x)N_y

Potassium phosphatoantimonates, KSb2PO8 （KSbPO） and KSb2PO8-xNy （KSbPON）, are prepared by solidstate method. Urea is employed as a source of nitrogen for N-doping. Structural, morphological and optical properties of both KSbPO and KSbPON are characterized by powder X-ray diffraction （PXRD）, scanning electron microscopy, energydispersive spectroscopy, Fourier transform infrared spectroscopy and UV-visible diffuse reflectance spectroscopy. Both samples are found to crystallize in a monoclinic lattice with Cc space group. The d-lines of KSbPO and KSbPON are refined by least square fitting the PXRD data, using POWD software to obtain their unit cell parameters. The bandgap energy （Eg） of both pristine and N-doped KSbPO is found from their Kubelka-Munk plot. The KSbPON/visible photocatalytic degradation of methylene blue and rhodamine B has been investigated in aqueous heterogeneous suspension. The generation of .OH in the presence of KSbPON during the photoreaction is verified by a fluorescence technique using terephthalic acid （TA） as a probe.

Enhanced Photocatalytic Activity of N-doped Li_2VPO_6 Under Visible Light Irradiation

Substitutional doping of framework heteroatoms in photocatalysts is one ot the approaches tor harvesting visible light. The present work aims to utilize the visible light for photocatalytic degradation of organic pollutant by tailoring the bandgap energy of Li2VPO6 through nitrogen doping. Li2VPO6 and N-doped Li2VPO6 are prepared by solid- state method. These materials were characterized by powder X-ray diffraction, energy-dispersive spectra, Raman spectra, UV-Vis diffuse reflectance spectra （UV-Vis DRS）, and 31p MAS NMR. The absorption edge of N-doped Li2VPO6 iS shifted to longer wavelength region considerably. The photocatalytic activity was tested against the degradation of methylene blue. The higher visible light photocatalytic activity of N-doped Li2VPO6 compared to pristine Li2VPO6 was discussed. The catalysts are stable even after fourth cycle of photodegradation.