Two novel 3D supramolecular architectures with hexamolybdate and phosphotungstate anions were syn- thesized under ionothermal conditions. The structures were named as [Cut（L1）2]2L2[Mo6O19]（1） and [Cur（L3）2]2.5&#...Two novel 3D supramolecular architectures with hexamolybdate and phosphotungstate anions were syn- thesized under ionothermal conditions. The structures were named as [Cut（L1）2]2L2[Mo6O19]（1） and [Cur（L3）2]2.5· H0.5[PW12O40].H2O（2）（L1=2,2＇-bipyridine, L2=4,4＇-bipyridine, L3=2,2＇-biimidazole） and characterized via Fourier transform infrared spectroscopy（FTIR） and FT-Raman spectroscopy analyses. Single-crystal X-ray diffraction analysis revealed that the two compounds crystallized in the space group P1 and were constructed through hydrogen bonding.展开更多
基金Supported by the National Natural Science Foundation of China（No.21301019）, the Youth Foundation of Science and Technology Department of Jilin Province, China（No.20130522129JH）, the National Science Foundation for Post-doctoral Scientists of China（No. 2013 M530135 ） and the Proj ect of the Technology Department of Jilin Province, China（No. ZDZH2011003）.
文摘Two novel 3D supramolecular architectures with hexamolybdate and phosphotungstate anions were syn- thesized under ionothermal conditions. The structures were named as [Cut（L1）2]2L2[Mo6O19]（1） and [Cur（L3）2]2.5· H0.5[PW12O40].H2O（2）（L1=2,2＇-bipyridine, L2=4,4＇-bipyridine, L3=2,2＇-biimidazole） and characterized via Fourier transform infrared spectroscopy（FTIR） and FT-Raman spectroscopy analyses. Single-crystal X-ray diffraction analysis revealed that the two compounds crystallized in the space group P1 and were constructed through hydrogen bonding.
