The title compound CuC14H22N2O9 was crystallized in the monoclinicspace group P21/n(# 14), with a= 9. 032(1), b= 13. 044(6), c= 14. 779(7) A, β=101. 50(3)°, V= 1706. 9(1) A 3, Dc= 1.54 g/cm3, Z=4, Mr= 425. 54, ...The title compound CuC14H22N2O9 was crystallized in the monoclinicspace group P21/n(# 14), with a= 9. 032(1), b= 13. 044(6), c= 14. 779(7) A, β=101. 50(3)°, V= 1706. 9(1) A 3, Dc= 1.54 g/cm3, Z=4, Mr= 425. 54, λ(Mo-Ka) =0. 71069A, μ= 13. 3 cm-1, F(000) = 780, the final R= 0. 058 and Rw= 0. 083 for2322 observable reflections with I> 3δ(I). The Cu atom is coordinated by two Natoms and three O atoms from cdta (cdta = trans-cyclohexane-1, 2-diamine-N, N,N’,N’-tetra-acetate) which acts as pentadentate ligand.展开更多
The title compound was crystallized in the monoclinic system, spacegroup P21/c(#14), with a= 9. 201 (1), b= 17. 690 (4), c= 10. 949 (4) A, β=108. 97(1)°, V= 1685. 4 A3, D. = 1. 46 g/cm3, Z= 2, Mr = 755. 76, λ(M...The title compound was crystallized in the monoclinic system, spacegroup P21/c(#14), with a= 9. 201 (1), b= 17. 690 (4), c= 10. 949 (4) A, β=108. 97(1)°, V= 1685. 4 A3, D. = 1. 46 g/cm3, Z= 2, Mr = 755. 76, λ(MoKa) =0. 71073A, μ= 13. 2 cm-1, F(000) = 748, final R= 0. 055 and R.= 0. 058 for 1056observable reflections with I≥3δ(I). In the complex each Cu atom is coordinated byfour bridging bidentate benzoate ligands and one THF.展开更多
文摘The title compound CuC14H22N2O9 was crystallized in the monoclinicspace group P21/n(# 14), with a= 9. 032(1), b= 13. 044(6), c= 14. 779(7) A, β=101. 50(3)°, V= 1706. 9(1) A 3, Dc= 1.54 g/cm3, Z=4, Mr= 425. 54, λ(Mo-Ka) =0. 71069A, μ= 13. 3 cm-1, F(000) = 780, the final R= 0. 058 and Rw= 0. 083 for2322 observable reflections with I> 3δ(I). The Cu atom is coordinated by two Natoms and three O atoms from cdta (cdta = trans-cyclohexane-1, 2-diamine-N, N,N’,N’-tetra-acetate) which acts as pentadentate ligand.
文摘The title compound was crystallized in the monoclinic system, spacegroup P21/c(#14), with a= 9. 201 (1), b= 17. 690 (4), c= 10. 949 (4) A, β=108. 97(1)°, V= 1685. 4 A3, D. = 1. 46 g/cm3, Z= 2, Mr = 755. 76, λ(MoKa) =0. 71073A, μ= 13. 2 cm-1, F(000) = 748, final R= 0. 055 and R.= 0. 058 for 1056observable reflections with I≥3δ(I). In the complex each Cu atom is coordinated byfour bridging bidentate benzoate ligands and one THF.
