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熔融制样—X射线荧光光谱法测定小取样量地球化学样品中的主量元素 被引量:2
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作者 赵红坤 郝亚波 +2 位作者 田有国 高祥照 刘亚轩 《物探与化探》 CAS 北大核心 2020年第4期778-783,共6页
X射线荧光光谱法(XRF)是地球化学标准物质均匀性检验的重要方法之一,但目前应用XRF法对标准物质进行均匀性检验还存在争议。由于均匀性检验要求称样量为最小取样量,而采用常规粉末压片或熔融制样进行XRF均匀性检验时称样量一般均大于最... X射线荧光光谱法(XRF)是地球化学标准物质均匀性检验的重要方法之一,但目前应用XRF法对标准物质进行均匀性检验还存在争议。由于均匀性检验要求称样量为最小取样量,而采用常规粉末压片或熔融制样进行XRF均匀性检验时称样量一般均大于最小取样量,得到的结果在理论上不足以支撑样品在最小取样量条件下是否均匀。本研究称取0.1 g样品,以四硼酸锂、偏硼酸锂和氟化锂(质量比为45∶10∶5)为混合熔剂,碘化氨为脱模剂,熔融制备样片;采用经验系数法建立了SiO2、Al2O3、TFe2O3、MgO、CaO、Na2O、K2O、Ti、P和Mn共10个测量组分的标准曲线,各组分校正曲线的相关系数在0.9973~1.0000之间。对制样条件的实验优化结果表明,样品与熔剂比为1∶4,以2滴0.2 g/mL碘化氨为脱模剂,在1050℃熔融10 min,熔融制得的样片成型效果最好。对方法参数进行了研究,各组分相对标准偏差值在0.2%~5.3%之间,相对误差小于6.2%,方法精密度和方法准确度均较高。与常规称样量0.65 g熔片结果相比,两种方法实验结果一致。本研究为X射线荧光光谱法在地球化学标准物质均匀性检验中的应用提供了依据。 展开更多
关键词 熔融制样 X射线荧光光谱法 小取样量 主量元素
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Study on the Nutrition Characteristics of Different K Use Efficiency Cotton Genotypes to K Deficiency Stress 被引量:9
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作者 JIANG Cun-cang CHEN Fang +4 位作者 gao xiang-zhao LU Jian-wei WAN Kai-yuan NIAN Fu-zhao WANG Yun-hua 《Agricultural Sciences in China》 CAS CSCD 2008年第6期740-745,共6页
To study the mechanism of plant K use efficiency, both K high and low use efficiency cotton genotypes, 103 and 122, respectively, were selected from 86 cotton cultivars (Gossypium hirsutum L.). The research was cond... To study the mechanism of plant K use efficiency, both K high and low use efficiency cotton genotypes, 103 and 122, respectively, were selected from 86 cotton cultivars (Gossypium hirsutum L.). The research was conducted using pot experiment for planting cotton on without K (0.0 g kg-1 soil) and with K (0.4 g kg-1 soil) treatments in 2005. Experimental result showed that, with K deficiency stress, genotype 103 grew much better than genotype 122 except that its lower leaves showed the symptoms of K deficiency, whereas all the leaves of genotype 122 showed the symptoms of K deficiency. Root dry matter weights of treatments for genotype 103 with and without K application were 1.07 and 1.25 times of genotype 122. It indicated that the root system of genotype 103 was well developed and has better nutrition uptake capability than that of genotype 122. The result also showed that the cotton shoots of genotype 103 were 1.07 and 1.13 times over genotype 122 on treatments of with and without K application. It indicated that genotype 103 has stronger transport organs. In genotype 103, plants, dry matter, and potassium were mainly transported to cotton bolls. The boll dry weight of genotype 103 was 2.58 times in without K treatment and 1.90 times in with K treatment over genotype 122. The potassium accumulation in bolls of genotype 122 was only 49.3% of that in genotype 103. Potassium accumulation in the other organs of genotype 103 was relatively low compared with in bolls. This indicated that the distribution of K and organic matter in genotype 103 was more efficient than genotype 122. The main differences between high K efficiency cotton genotype 103 and low K efficiency genotype 122 lie in their potassium nutrition and organic matter using efficiency on uptake, transportation, accumulation, distribution, and utilization. 展开更多
关键词 cotton (Gossypium hirsutum L.) potassium use efficiency GENOTYPE uptake capability distribution ability
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