Syngas fuel such as hydrogen and carbon monoxide generated by solar energy is a promising method to use solar energy and overcome its fluctuation effectively.This study proposes a combined cooling,heating,and power sy...Syngas fuel such as hydrogen and carbon monoxide generated by solar energy is a promising method to use solar energy and overcome its fluctuation effectively.This study proposes a combined cooling,heating,and power system using the reversible solid oxide fuel cell assisted by solar energy to produce solar fuel and then supply energy products for users during the period without solar radiation.The system runs a solar-assisted solid oxide electrolysis cell mode and a solid oxide fuel cell mode.The thermodynamic models are constructed,and the energetic and exergetic performances are analyzed.Under the design work conditions,the SOEC mode’s overall system energy and exergy efficiencies are 19.0%and 20.5%,respectively.The electrical,energy and exergy efficiencies in the SOFC mode are 51.4%,71.3%,and 45.2%,respectively.The solid oxide fuel cell accounts for 60.0%of total exergy destruction,caused by the electrochemical reactions’thermodynamic irreversibilities.The increase of operating temperature of solid oxide fuel cell from 800℃to 1050℃rises the exergy and energy efficiencies by 11.3%and 12.3%,respectively.Its pressure from 0.2 to 0.7 MPa improves electrical efficiency by 13.8%while decreasing energy and exergy efficiencies by 5.2%and 6.0%,respectively.展开更多
Syngas fuel generated by solar energy integrating with fuel cell technology is one of the promising methods for future green energy solutions to carbon neutrality.This paper designs a novel solar-driven solid oxide el...Syngas fuel generated by solar energy integrating with fuel cell technology is one of the promising methods for future green energy solutions to carbon neutrality.This paper designs a novel solar-driven solid oxide electrolyzer system integrated with waste heat for syngas production.Solar photovoltaic and parabolic trough collecter together drive the solid oxide electrolysis cell to improve system efficiency.The thermodynamic models of components are established,and the energy,exergy,and exergoeconomic analysis are conducted to evaluate the system’s performance.Under the design work conditions,the solar photovoltaic accounts for 88.46%of total exergy destruction caused by its less conversion efficiency.The exergoeconomic analysis indicates that the fuel cell component has a high exergoeconomic factor of 89.56%due to the large capital investment cost.The impacts of key parameters such as current density,operating temperature,pressure and mole fraction on system performances are discussed.The results demonstrate that the optimal energy and exergy efficiencies are achieved at 19.04%and 19.90%when the temperature,pressure,and molar fraction of H_(2)O are 1223.15 K,0.1 MPa,and 50%,respectively.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51876064 and 52090064)the Bureau of Shihezi Science&Technology(Grant No.2021ZD02)。
文摘Syngas fuel such as hydrogen and carbon monoxide generated by solar energy is a promising method to use solar energy and overcome its fluctuation effectively.This study proposes a combined cooling,heating,and power system using the reversible solid oxide fuel cell assisted by solar energy to produce solar fuel and then supply energy products for users during the period without solar radiation.The system runs a solar-assisted solid oxide electrolysis cell mode and a solid oxide fuel cell mode.The thermodynamic models are constructed,and the energetic and exergetic performances are analyzed.Under the design work conditions,the SOEC mode’s overall system energy and exergy efficiencies are 19.0%and 20.5%,respectively.The electrical,energy and exergy efficiencies in the SOFC mode are 51.4%,71.3%,and 45.2%,respectively.The solid oxide fuel cell accounts for 60.0%of total exergy destruction,caused by the electrochemical reactions’thermodynamic irreversibilities.The increase of operating temperature of solid oxide fuel cell from 800℃to 1050℃rises the exergy and energy efficiencies by 11.3%and 12.3%,respectively.Its pressure from 0.2 to 0.7 MPa improves electrical efficiency by 13.8%while decreasing energy and exergy efficiencies by 5.2%and 6.0%,respectively.
基金supported by the National Natural Science Foundation of China(No.52276007)the Major Program of the National Natural Science Foundation of China(No.52090064)。
文摘Syngas fuel generated by solar energy integrating with fuel cell technology is one of the promising methods for future green energy solutions to carbon neutrality.This paper designs a novel solar-driven solid oxide electrolyzer system integrated with waste heat for syngas production.Solar photovoltaic and parabolic trough collecter together drive the solid oxide electrolysis cell to improve system efficiency.The thermodynamic models of components are established,and the energy,exergy,and exergoeconomic analysis are conducted to evaluate the system’s performance.Under the design work conditions,the solar photovoltaic accounts for 88.46%of total exergy destruction caused by its less conversion efficiency.The exergoeconomic analysis indicates that the fuel cell component has a high exergoeconomic factor of 89.56%due to the large capital investment cost.The impacts of key parameters such as current density,operating temperature,pressure and mole fraction on system performances are discussed.The results demonstrate that the optimal energy and exergy efficiencies are achieved at 19.04%and 19.90%when the temperature,pressure,and molar fraction of H_(2)O are 1223.15 K,0.1 MPa,and 50%,respectively.
