Main observation and conclusion Inspired by the nitrogen fixation process on MoFe nitrogenase,asymmetrical coordinated Fe grafted onto 1T MoS_(2) were successfully synthesized.The unique electron-rich structure with a...Main observation and conclusion Inspired by the nitrogen fixation process on MoFe nitrogenase,asymmetrical coordinated Fe grafted onto 1T MoS_(2) were successfully synthesized.The unique electron-rich structure with asymmetrical coordination made the 1T Fe_(0.1)Mo_(0.9)S_(2) layered material actively react with water and dinitrogen at room temperature and atmosphere pressure.展开更多
基金The work was supported by the Science and Technology Commission of National Natural Science Foundation of China(Nos.21901156,21975148 and 21771124)the Shanghai Municipality(Nos.19JC1412600,18QA1402400 and 18230743400)+4 种基金Z.Feng thanks the startup funding from Oregon State University.The XAS measurements were done at 9-BM of Advanced Photon Source,which is a U.S.Department of Energy(DOE)Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No.DE-AC02-06CH11357.T.Cheng and H.Yang thanks the Natural Science Foundation of Jiangsu Province(Grant No.SBK20190810)the Jiangsu Province High-Level Talents(JNHB-106)the China Postdoctoral Science Foundation(No.2019M660128)the Collaborative Innova-tion Center of Suzhou Nano Science&Technology,the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the 111 Project.
文摘Main observation and conclusion Inspired by the nitrogen fixation process on MoFe nitrogenase,asymmetrical coordinated Fe grafted onto 1T MoS_(2) were successfully synthesized.The unique electron-rich structure with asymmetrical coordination made the 1T Fe_(0.1)Mo_(0.9)S_(2) layered material actively react with water and dinitrogen at room temperature and atmosphere pressure.
