The monophthalocyanine complexes of samarium and terbium containing axial 2-mercaptobenzothiazole（Pc Sm（MBT）（1））, 2-（2-benzoxazol-2-yl） phenolate（Pc Tb（OON）（2）） or 2-（2-benzothiazol-2-yl）phenolate（Pc...The monophthalocyanine complexes of samarium and terbium containing axial 2-mercaptobenzothiazole（Pc Sm（MBT）（1））, 2-（2-benzoxazol-2-yl） phenolate（Pc Tb（OON）（2）） or 2-（2-benzothiazol-2-yl）phenolate（Pc Tb（SON）（3）） ligands were synthesized and identified by elemental, LDI-TOF and X-ray（for 1） analysis.Photoluminescence（PL） and electroluminescence（EL） spectra of the compounds contained only emission bands of phthalocyanine and axial ligands but did not contain the bands of f-f transitions.It was found that among the complexes 1, 2, 3 the latter had highest photoconductivity（~10–7 S/cm） and photovoltaic properties.An organic photovoltaic device（OPV） of configuration of ITO/3/C60/Alq3/Al revealed open-circuit voltage（VOC） of 0.24 V and short current density（ISC） of 0.3 μA/cm2 under illumination by a xenon lamp at 17 m W/cm2.展开更多
基金Project supported by the Russian Foundation of Basic Research(13-0397046,13-02-97044)grant(the agreement of August 27,2013 № 02.В.49.21.0003 between The Ministry of Education and Science of the Russian Federation and Lobachevsky State University of Nizhni Novgorod)
文摘The monophthalocyanine complexes of samarium and terbium containing axial 2-mercaptobenzothiazole（Pc Sm（MBT）（1））, 2-（2-benzoxazol-2-yl） phenolate（Pc Tb（OON）（2）） or 2-（2-benzothiazol-2-yl）phenolate（Pc Tb（SON）（3）） ligands were synthesized and identified by elemental, LDI-TOF and X-ray（for 1） analysis.Photoluminescence（PL） and electroluminescence（EL） spectra of the compounds contained only emission bands of phthalocyanine and axial ligands but did not contain the bands of f-f transitions.It was found that among the complexes 1, 2, 3 the latter had highest photoconductivity（~10–7 S/cm） and photovoltaic properties.An organic photovoltaic device（OPV） of configuration of ITO/3/C60/Alq3/Al revealed open-circuit voltage（VOC） of 0.24 V and short current density（ISC） of 0.3 μA/cm2 under illumination by a xenon lamp at 17 m W/cm2.
