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Thermodynamic Properties of CaCl<sub>2</sub>-CaF<sub>2</sub>-CaO System: Phase Diagram Investigation 被引量:1
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作者 Julien Claquesin Mathieu Gibilaro +3 位作者 Laurent Massot Olivier Lemoine gilles bourges Pierre Chamelot 《Materials Sciences and Applications》 2021年第4期139-151,共13页
The CaCl<sub>2</sub>-CaF<sub>2</sub>-CaO phase diagram was investigated in the CaO low region (<40 mol.%). CaCl<sub>2</sub>-CaF<sub>2</sub> and CaCl<sub>2</s... The CaCl<sub>2</sub>-CaF<sub>2</sub>-CaO phase diagram was investigated in the CaO low region (<40 mol.%). CaCl<sub>2</sub>-CaF<sub>2</sub> and CaCl<sub>2</sub>-CaO binary diagrams, constituting the ternary system, were first studied by Differential Scanning Calorimetry (DSC) measurements and X-Ray Diffraction (XRD) characterization;a good agreement was obtained between the phase diagram models calculated with FactSage&reg;software (FTsalt database) and present experimental data. As the CaF<sub>2</sub>-CaO liquidus could not be measured by DSC due to the high melting temperature, this diagram was calculated using FTsalt database combined with FToxid database of FactSage<sup>&reg;</sup> software. The ternary phase diagram was obtained by calculations and exhibits an eutectic at the composition CaCl<sub>2</sub>-CaF<sub>2</sub>-CaO (78.2-15.7-6.1 mol.%) melting at 637&deg;C, and five peritectic points. Measurements of relevant vertical cross-sections for three CaCl<sub>2</sub>-CaF<sub>2</sub> compositions (50-50, 40-60 and 30-70 mol.%) up to 18 mol.% CaO are in agreement with the ternary phase diagram model. For each section, the liquidus temperature is constant up to around 11 mol.% CaO and then sharply increases. Moreover, an increase of CaF<sub>2</sub> content in CaCl<sub>2</sub>-CaF<sub>2</sub> melt leads to a decrease of the CaO solubility in isothermal condition. 展开更多
关键词 Differential Scanning Calorimetry (DSC) Phase Diagram Calcium Chloride Calcium Fluoride Calcium Oxide Ternary System
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