An exploratory multinuclear magnetic resonance(MR)and magnetic resonance imaging(MRI)study was performed on lithium-ion battery cells with ^(7)Li,^(19)F,and ^(1)H measurements.A variable field superconducting magnet w...An exploratory multinuclear magnetic resonance(MR)and magnetic resonance imaging(MRI)study was performed on lithium-ion battery cells with ^(7)Li,^(19)F,and ^(1)H measurements.A variable field superconducting magnet with a fixed frequency parallel-plate radiofrequency(RF)probe was employed in the study.The magnetic field was changed to set the resonance frequency of each nucleus to the fixed RF probe frequency of 33.7 MHz.Two cartridge-like lithium-ion cells,with graphite anodes and LiNi_(0.5)Mn_(0.3)Co_(0.2)O_(2)(NMC)cathodes,were interrogated.One cell was pristine,and one was charged to a cell voltage of 4.2 V.The results presented demonstrate the great potential of the variable field magnet approach in multinuclear measurement of lithium-ion batteries.These methods open the door for developing faster and simpler methods for detecting,quantifying,and interpreting MR and MRI data from lithium-ion and other batteries.展开更多
We explore the use of the parallel-plate resonator for the study of thin cuboid samples over a wide range of magnetic resonance frequencies.The parallel-plate resonator functions at frequencies from tens to hundreds o...We explore the use of the parallel-plate resonator for the study of thin cuboid samples over a wide range of magnetic resonance frequencies.The parallel-plate resonator functions at frequencies from tens to hundreds of MHz.Seven parallel-plate resonators are presented and discussed in a frequency range from 8 to 500 MHz.Magnetic resonance experiments were performed on both horizontal and vertical bore magnet systems with lithium and hydrogen nuclei.Parallel-plate radiofrequency(RF)probes are easy to build and easy to optimize.Experiments and simulations showed good sensitivity of the parallel-plate RF probe geometry with a small decrease in sensitivity at higher frequencies.展开更多
基金BJB thanks the Canada Chairs program for a Research Chair in MRI of Materials[950e230894]an NSERC Discovery Grant[2015-6122]GRG thanks NSERC for a Discovery Grant[RGPIN-2017-06095].
文摘An exploratory multinuclear magnetic resonance(MR)and magnetic resonance imaging(MRI)study was performed on lithium-ion battery cells with ^(7)Li,^(19)F,and ^(1)H measurements.A variable field superconducting magnet with a fixed frequency parallel-plate radiofrequency(RF)probe was employed in the study.The magnetic field was changed to set the resonance frequency of each nucleus to the fixed RF probe frequency of 33.7 MHz.Two cartridge-like lithium-ion cells,with graphite anodes and LiNi_(0.5)Mn_(0.3)Co_(0.2)O_(2)(NMC)cathodes,were interrogated.One cell was pristine,and one was charged to a cell voltage of 4.2 V.The results presented demonstrate the great potential of the variable field magnet approach in multinuclear measurement of lithium-ion batteries.These methods open the door for developing faster and simpler methods for detecting,quantifying,and interpreting MR and MRI data from lithium-ion and other batteries.
基金the Canada Chairs program for a Research Chair in MRI of Materials[950-230894]an NSERC Discovery Grant[2015-6122].GRG thanks NSERC for a Discovery Grant[RGPIN-2017-06095].
文摘We explore the use of the parallel-plate resonator for the study of thin cuboid samples over a wide range of magnetic resonance frequencies.The parallel-plate resonator functions at frequencies from tens to hundreds of MHz.Seven parallel-plate resonators are presented and discussed in a frequency range from 8 to 500 MHz.Magnetic resonance experiments were performed on both horizontal and vertical bore magnet systems with lithium and hydrogen nuclei.Parallel-plate radiofrequency(RF)probes are easy to build and easy to optimize.Experiments and simulations showed good sensitivity of the parallel-plate RF probe geometry with a small decrease in sensitivity at higher frequencies.
