The electrodeposition of neodymium on Pt and Cu electrodes was investigated in DMSO containing NdCl3 and a small mount of water at room temperature. Cyclic voltammetry indicated that the reduction process of Nd(III) o...The electrodeposition of neodymium on Pt and Cu electrodes was investigated in DMSO containing NdCl3 and a small mount of water at room temperature. Cyclic voltammetry indicated that the reduction process of Nd(III) on the Pt cathode was complicated. The one-step reduction wave showed two steps by adding 0.3 mol/L ethylenediamine(EN). A delicate yellow, lustrous, strongly adhering film on the Cu electrode was obtained using potentiostatic electrolysis at -1.80 V (vs. aq SCE).展开更多
文摘The electrodeposition of neodymium on Pt and Cu electrodes was investigated in DMSO containing NdCl3 and a small mount of water at room temperature. Cyclic voltammetry indicated that the reduction process of Nd(III) on the Pt cathode was complicated. The one-step reduction wave showed two steps by adding 0.3 mol/L ethylenediamine(EN). A delicate yellow, lustrous, strongly adhering film on the Cu electrode was obtained using potentiostatic electrolysis at -1.80 V (vs. aq SCE).
