The 1H and 13C NMR spectra of the dinuclear complexes of molybdenum(VI) withethylenediaminetetraacetic acid ([Mo(VI)]2-EDTA) and 3,12-bis(carboxymethyl)-6.9-dioxa-3,12-diazatetra-decanedioic acid(tMo(VI)]2-EGTA) at va...The 1H and 13C NMR spectra of the dinuclear complexes of molybdenum(VI) withethylenediaminetetraacetic acid ([Mo(VI)]2-EDTA) and 3,12-bis(carboxymethyl)-6.9-dioxa-3,12-diazatetra-decanedioic acid(tMo(VI)]2-EGTA) at various temperatures were measured. The solutionstructure of the two dinuclear complexes was determined and the possible exchange process of theisomers is suggested展开更多
文摘The 1H and 13C NMR spectra of the dinuclear complexes of molybdenum(VI) withethylenediaminetetraacetic acid ([Mo(VI)]2-EDTA) and 3,12-bis(carboxymethyl)-6.9-dioxa-3,12-diazatetra-decanedioic acid(tMo(VI)]2-EGTA) at various temperatures were measured. The solutionstructure of the two dinuclear complexes was determined and the possible exchange process of theisomers is suggested
