The application of nanomaterials in energy and environmental fields has recently made great progress.As a key element in the nuclear industry,the discharge of uranium(U(VI))contained wastewater usually induces environ...The application of nanomaterials in energy and environmental fields has recently made great progress.As a key element in the nuclear industry,the discharge of uranium(U(VI))contained wastewater usually induces environmental issues and waste of resources.Although the catalytically generated H_(2)O_(2)by nanomaterials has recently shown application potential in extracting U(VI)from water,low-cost and highly efficient nanocatalysts are still urgently needed.In this work,a cheap and readily available piezocatalyst of calcium phosphate nanorods was successfully fabricated by calcining chicken bones.Under ultrasonication,H_(2)O_(2)was produced and used to extract U(VI)from water.It is worth noting that the yield of H_(2)O_(2)reached 179.7μmol·g^(−1)·h^(−1),and the extraction efficiency of U(VI)in water reached 97.16%(100 ppm)within 330 min.Through the capture and quantitative analysis of the active species,it is found that the generation of H_(2)O_(2)depends on the combination of soluble oxygen and piezoelectrons,which thus dominates the extraction of U(VI).This simple and powerful piezocatalytic strategy greatly reduces the cost of H_(2)O_(2)production for U(VI)extraction in water,and is of great significance for the treatment of U(VI)-containing wastewater.展开更多
At present,it is very important to create new types of mirrors,nonlinear light frequency transformers and optical filters with controlled optical properties.In this connection,it is of great interest to study photonic...At present,it is very important to create new types of mirrors,nonlinear light frequency transformers and optical filters with controlled optical properties.In this connection,it is of great interest to study photonic crystals.Their dielectric permittivity varies periodically in space with a period permitting Bragg diffraction of light.In this paper,we have investigated the optical properties of mesoporous three-dimensional(3D)opal-type and one-dimensional(1D)anodic alumina photonic crystals,filled with different dielectrics,ferroelectrics and piezoelectrics.We have compared the optical properties of initial mesoporous photonic crystals and filled with different substances.The possibility of mesoporous photonic crystals using selective narrow-band light filters in Raman scattering experiments and nonlinear mirrors has been analyzed.The electromagnetic field enhancing in the case of exciting light frequency close to the stop band edges has been established.The optical harmonics and subharmonics generation in mesoporous crystals,filled with ferroelectrics and piezoelectrics was proposed.展开更多
基金funded by the National Natural Science Foundation of China(Nos.22376060,U2267222,and U21A20290)Qinghai Provincial Science and Technology Project(No.2021-ZJ-925).
文摘The application of nanomaterials in energy and environmental fields has recently made great progress.As a key element in the nuclear industry,the discharge of uranium(U(VI))contained wastewater usually induces environmental issues and waste of resources.Although the catalytically generated H_(2)O_(2)by nanomaterials has recently shown application potential in extracting U(VI)from water,low-cost and highly efficient nanocatalysts are still urgently needed.In this work,a cheap and readily available piezocatalyst of calcium phosphate nanorods was successfully fabricated by calcining chicken bones.Under ultrasonication,H_(2)O_(2)was produced and used to extract U(VI)from water.It is worth noting that the yield of H_(2)O_(2)reached 179.7μmol·g^(−1)·h^(−1),and the extraction efficiency of U(VI)in water reached 97.16%(100 ppm)within 330 min.Through the capture and quantitative analysis of the active species,it is found that the generation of H_(2)O_(2)depends on the combination of soluble oxygen and piezoelectrons,which thus dominates the extraction of U(VI).This simple and powerful piezocatalytic strategy greatly reduces the cost of H_(2)O_(2)production for U(VI)extraction in water,and is of great significance for the treatment of U(VI)-containing wastewater.
基金supported by Russian Foundation for Basic Research(RFBR)(grants 15-02-02882,16-08-00618,16-02-00488,16-52-00026)National Natural Science Foundation of China(Nos.51471162,51671183,51502294)China Scholarship Council.
文摘At present,it is very important to create new types of mirrors,nonlinear light frequency transformers and optical filters with controlled optical properties.In this connection,it is of great interest to study photonic crystals.Their dielectric permittivity varies periodically in space with a period permitting Bragg diffraction of light.In this paper,we have investigated the optical properties of mesoporous three-dimensional(3D)opal-type and one-dimensional(1D)anodic alumina photonic crystals,filled with different dielectrics,ferroelectrics and piezoelectrics.We have compared the optical properties of initial mesoporous photonic crystals and filled with different substances.The possibility of mesoporous photonic crystals using selective narrow-band light filters in Raman scattering experiments and nonlinear mirrors has been analyzed.The electromagnetic field enhancing in the case of exciting light frequency close to the stop band edges has been established.The optical harmonics and subharmonics generation in mesoporous crystals,filled with ferroelectrics and piezoelectrics was proposed.
