In order to promote the development of road traffic in our country,it is necessary to strengthen the research on municipal road construction technology,constantly innovate construction technology and construction tech...In order to promote the development of road traffic in our country,it is necessary to strengthen the research on municipal road construction technology,constantly innovate construction technology and construction technique,and then effectively ensure the rapid development of urban traffic.This paper mainly elaborates on asphalt road surface regeneration technology,modified asphalt concrete,concrete road surface anti-cracking technology,three-dimensional printing technology,composite material road surface,polymer composite materials,etc.,to ensure the development of urban transportation and the quality of municipal road projects.展开更多
In order to improve the quality of bored piles in bridge construction and ensure the overall quality of the bridge,we analyzed a series of problems in the construction process of bored piles,then propose corresponding...In order to improve the quality of bored piles in bridge construction and ensure the overall quality of the bridge,we analyzed a series of problems in the construction process of bored piles,then propose corresponding quality control measures,in hopes of improving quality control of bored piles in bridge construction in our country.展开更多
California Bearing Ratio(CBR)test is highly professional and requires a high level of skills.In order to improve the accuracy of the test results,the relevant staff will not only need to understand the rules and proce...California Bearing Ratio(CBR)test is highly professional and requires a high level of skills.In order to improve the accuracy of the test results,the relevant staff will not only need to understand the rules and procedures involved in the test,they would also need to be meticulous in their work to avoid human errors,provide good data support for highway engineering,and improve the overall quality of the project.Therefore,this paper presents an analysis of the application of CBR test in highway engineering,which can provide reference for engineering and promote the development of the highway industry.展开更多
Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can...Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can be used as light-harvesting materials in solar energy utilization such as photocatalytic methanol steam reforming.In this work,we report an atomically precise Cu_(13)cluster protected by dual ligands of thiolate and phosphine that can be viewed as the assembly of one top Cu atom and three Cu_(4)tetrahedra.The Cu_(13)H_(10)(SR)_(3)(PR’_(3))_(7)(SR=2,4-dichlorobenzenethiol,PR’_(3)=P(4-FC_(6)H_(4))_(3))cluster can give rise to highly efficient light-driven activity for methanol steam reforming toward H_(2)production.展开更多
Climate warming has made the planting area of Hami melon expand northward to Barry Bakai Town,Altay City,near 47° N. Climate events often induce the occurrence of pests and diseases in crops,affecting the steady ...Climate warming has made the planting area of Hami melon expand northward to Barry Bakai Town,Altay City,near 47° N. Climate events often induce the occurrence of pests and diseases in crops,affecting the steady production of Hami melon. In 2013,pests and diseases occurred seriously,resulting in low yield and poor quality of Hami melon. Based on the production survey data of Hami melon in recent20 years,the interaction of various meteorological factors in different time and different intervals of various factors was analyzed in this paper to explore the characteristics of the meteorological factors that cause diseases and influence the quality of Hami melon.展开更多
Asphalt pavement is currently one of the main components in the construction of roads and bridges.However,from a practical point of view,various quality problems are prone to occur in the surface layer of asphalt pave...Asphalt pavement is currently one of the main components in the construction of roads and bridges.However,from a practical point of view,various quality problems are prone to occur in the surface layer of asphalt pavement,which will lead to the poor overall quality of road and bridge projects.Therefore,it should be applied reasonably.Advanced testing technologies are used to test the mixture quality,compaction,segregation,thickness,and other aspects of the asphalt pavement surface layer,so as to improve the quality of the asphalt pavement surface layer,and then improve the overall quality of road and bridge construction.Therefore,this paper mainly analyzes the technologies for asphalt pavement surface layer testing in road and bridge engineering construction.展开更多
This study aimed to propose road crack detection method based on infrared image fusion technology.By analyzing the characteristics of road crack images,this method uses a variety of infrared image fusion methods to pr...This study aimed to propose road crack detection method based on infrared image fusion technology.By analyzing the characteristics of road crack images,this method uses a variety of infrared image fusion methods to process different types of images.The use of this method allows the detection of road cracks,which not only reduces the professional requirements for inspectors,but also improves the accuracy of road crack detection.Based on infrared image processing technology,on the basis of in-depth analysis of infrared image features,a road crack detection method is proposed,which can accurately identify the road crack location,direction,length,and other characteristic information.Experiments showed that this method has a good effect,and can meet the requirement of road crack detection.展开更多
Based on the as-built load test of a large bridge,this paper introduces the procedure of the prestressed concrete continuous rigid frame bridge load test.Numerical analysis of the bridge was carried out by simulating ...Based on the as-built load test of a large bridge,this paper introduces the procedure of the prestressed concrete continuous rigid frame bridge load test.Numerical analysis of the bridge was carried out by simulating and establishing a finite element model,and comparative analysis was carried out with the measured values.The results show that the calculated values were basically consistent with the measured values,which showed that the establishment method of the model was reasonable,and the mechanical performance of the bridge met the service requirements of the designed live load.展开更多
Objective: To investigate the clinical diagnostic value of peripheral lung cancer using multi-slice CT (MSCT) perfu- sion imaging and the relationship with microvessel density (MVD). Methods: 38 patients with pulmonar...Objective: To investigate the clinical diagnostic value of peripheral lung cancer using multi-slice CT (MSCT) perfu- sion imaging and the relationship with microvessel density (MVD). Methods: 38 patients with pulmonary masses proved by pathology including 25 cases of peripheral lung cancer and 13 cases of benign masses were studied prospectively with GE Lightspeed Qx/I plus 16-slice helical CT perfusion imaging, and 25 patients with lung cancer were comparative studied with its MVD calculated using LSAB. With the CT perfusion 2-body tumor software, the parameters of CT perfusion including blood value (BV), blood flow (BF), mean transit time (MTT) and permeability surface (PS) were analyzed. Results: The four param- eter values in lung cancer were all higher than that in pulmonary benign masses, and there were significant differences among BV, MTT and PS (P<0.05), especially in BV (P<0.01). The MVD value of lung cancer was higher than that of pulmonary benign masses (P<0.05), and the MVD of adenocarcinoma was higher than that of squamous cell carcinoma (P<0.05). In 25 cases with lung cancer, there was positive correlation only between BV and MVD value (r=0.852, P<0.01). Conclusion: It is helpful to diagnose the peripheral lung cancer with MSCT perfusion imaging and to differentiate from pulmonary benign masses, its bases are MVD pathologically.展开更多
A novel collaborative beamforming algorithm is proposed in a wireless communication system with multiple transmitters and one receiver. All transmitters take part in the collaboration and the weighted message is trans...A novel collaborative beamforming algorithm is proposed in a wireless communication system with multiple transmitters and one receiver. All transmitters take part in the collaboration and the weighted message is transmitted simultaneously. In order to maximize the beamforming gain, the transmitters use one bit feedback information to adjust the phase offset. It tracks the direction in which the signal strength at the receiver can increase. The directional search and perturbation theory is used to achieve the phase alignment. The feasibility of the proposed algorithm is proved both experimentally and theoretically. Simulation results show that the proposed algorithm can improve the convergent speed of the phase alignment.展开更多
The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide(O_3/H_2O_2 process) to degrade o-phenylenediamine(o-PDA) in a simulated wastewater. A rotor–stator reactor(RSR) was e...The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide(O_3/H_2O_2 process) to degrade o-phenylenediamine(o-PDA) in a simulated wastewater. A rotor–stator reactor(RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA(η) as well as the overall gas-phase volumetric mass transfer coefficient(KGa) were determined under different operating conditions of H_2O_2 concentration, initial o-PDA concentration, temperature of reaction, initial p H and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate(rCOD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer(GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone(O_3 process), and it was noted that η, KGa and rCODachieved by O_3/H_2O_2 process was 24.4%,31.6% and 25.2% respectively higher than those of O_3 process, indicating that H_2O_2 can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.展开更多
Plastic forming is one of enabling and fundamental technologies in advanced manufacturing chains. Design optimization is a critical way to improve the performance of the forming system, exploit the advantages of high ...Plastic forming is one of enabling and fundamental technologies in advanced manufacturing chains. Design optimization is a critical way to improve the performance of the forming system, exploit the advantages of high productivity, high product quality, low production cost and short time to market and develop precise, accurate, green, and intelligent(smart) plastic forming technology. However, plastic forming is quite complicated, relating to multi-physics field coupling,multi-factor influence, multi-defect constraint, and triple nonlinear, etc., and the design optimization for plastic forming involves multi-objective, multi-parameter, multi-constraint, nonlinear,high-dimensionality, non-continuity, time-varying, and uncertainty, etc. Therefore, how to achieve accurate and efficient design optimization of products, equipment, tools/dies, and processing as well as materials characterization has always been the research frontier and focus in the field of engineering and manufacturing. In recent years, with the rapid development of computing science, data science and internet of things(Io T), the theories and technologies of design optimization have attracted more and more attention, and developed rapidly in forming process. Accordingly, this paper first introduced the framework of design optimization for plastic forming. Then, focusing on the key problems of design optimization, such as numerical model and optimization algorithm,this paper summarized the research progress on the development and application of the theories and technologies about design optimization in forming process, including deterministic and uncertain optimization. Moreover, the applicability of various modeling methods and optimization algorithms was elaborated in solving the design optimization problems of plastic forming. Finally, considering the development trends of forming technology, this paper discusses some challenges of design optimization that may need to be solved and faced in forming process.展开更多
An experimental investigation on the behavior and characteristics of interfacial waves in downward inclined rectangular channel was conducted. The interfacial waves were traced and measured by us-ing conductance techn...An experimental investigation on the behavior and characteristics of interfacial waves in downward inclined rectangular channel was conducted. The interfacial waves were traced and measured by us-ing conductance technique. The wav patterns were distinguished and defined. The characteristics of the interfacial waves, such as time-averaged film thickness, wave height, wave propagation speed,wavlength and wave frequency, were systematically examined in terms of gas and liquid superficial volumetric fiuxes. The effect of the inclination and flow channel geometry of the test section on the interfacial wav was also investigated.展开更多
Multiple viral infections in insect vectors with synergistic effects are common in nature,but the underlying mechanism remains elusive.Here,we find that rice gall dwarf reovirus(RGDV)facilitates the transmission of ri...Multiple viral infections in insect vectors with synergistic effects are common in nature,but the underlying mechanism remains elusive.Here,we find that rice gall dwarf reovirus(RGDV)facilitates the transmission of rice stripe mosaic rhabdovirus(RSMV)by co-infected leafhopper vectors.RSMV nucleoprotein(N)alone activates complete anti-viral autophagy,while RGDV nonstructural protein Pns11 alone induces pro-viral incomplete autophagy.In co-infected vectors,RSMVexploits Pns11-induced autophagosomes to assemble enveloped virions via N-Pns11-ATG5 interaction.Furthermore,RSMV could effectively propagate in Sf9 cells.Expression of Pns11 in Sf9 cells or leafhopper vectors causes the recruitment of N from the ER to Pns11-induced autophagosomes and inhibits N-induced complete autophagic flux,finally facilitating RSMV propagation.In summary,these results demonstrate a previously unappreciated role of autophagy in the regulation of the direct synergistic interaction during co-transmission of two distinct arboviruses by insect vectors and reveal the functional importance of virus-induced autophagosomes in rhabdovirus assembly.展开更多
It remains elusive to realize the distinct catalysis of isomeric catalysts because it becomes challenging to identify structural isomers in the polydisperse nanoparticles.Herein we investigate catalysis of two geometr...It remains elusive to realize the distinct catalysis of isomeric catalysts because it becomes challenging to identify structural isomers in the polydisperse nanoparticles.Herein we investigate catalysis of two geometric isomers for 36-gold-atom nanoclusters with different Au cores arrangements but the same thiolate ligands,thereby providing access to isomer catalysts readily participate in a desired reaction.Compared to the Au_(36)(SR)_(24)with a one-dimensional(1D)layout of Au4 tetrahedral units,the Au_(36)(SR)_(24)with a two-dimensional(2D)layout of Au4 tetrahedral units is more effective for the intramolecular hydroamination of alkyne.Our study suggests that the exposed Au sties of the two Au_(36)(SR)_(24)catalysts favor different reaction intermediates and pathways.The intramolecular H transfer leads to intermediates with the C-N and with C=N for the 1D and 2D Au_(36)(SR)_(24)respectively,and hence the different on-site and off-site pathways for the successive reaction steps account for the different performances of the two Au_(36)(SR)_(24)catalysts.展开更多
文摘In order to promote the development of road traffic in our country,it is necessary to strengthen the research on municipal road construction technology,constantly innovate construction technology and construction technique,and then effectively ensure the rapid development of urban traffic.This paper mainly elaborates on asphalt road surface regeneration technology,modified asphalt concrete,concrete road surface anti-cracking technology,three-dimensional printing technology,composite material road surface,polymer composite materials,etc.,to ensure the development of urban transportation and the quality of municipal road projects.
文摘In order to improve the quality of bored piles in bridge construction and ensure the overall quality of the bridge,we analyzed a series of problems in the construction process of bored piles,then propose corresponding quality control measures,in hopes of improving quality control of bored piles in bridge construction in our country.
文摘California Bearing Ratio(CBR)test is highly professional and requires a high level of skills.In order to improve the accuracy of the test results,the relevant staff will not only need to understand the rules and procedures involved in the test,they would also need to be meticulous in their work to avoid human errors,provide good data support for highway engineering,and improve the overall quality of the project.Therefore,this paper presents an analysis of the application of CBR test in highway engineering,which can provide reference for engineering and promote the development of the highway industry.
基金financial support from National Natural Science Foundation of China(22125202,21932004,22101128)Natural Science Foundation of Jiangsu Province(BK20220033)。
文摘Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can be used as light-harvesting materials in solar energy utilization such as photocatalytic methanol steam reforming.In this work,we report an atomically precise Cu_(13)cluster protected by dual ligands of thiolate and phosphine that can be viewed as the assembly of one top Cu atom and three Cu_(4)tetrahedra.The Cu_(13)H_(10)(SR)_(3)(PR’_(3))_(7)(SR=2,4-dichlorobenzenethiol,PR’_(3)=P(4-FC_(6)H_(4))_(3))cluster can give rise to highly efficient light-driven activity for methanol steam reforming toward H_(2)production.
文摘Climate warming has made the planting area of Hami melon expand northward to Barry Bakai Town,Altay City,near 47° N. Climate events often induce the occurrence of pests and diseases in crops,affecting the steady production of Hami melon. In 2013,pests and diseases occurred seriously,resulting in low yield and poor quality of Hami melon. Based on the production survey data of Hami melon in recent20 years,the interaction of various meteorological factors in different time and different intervals of various factors was analyzed in this paper to explore the characteristics of the meteorological factors that cause diseases and influence the quality of Hami melon.
文摘Asphalt pavement is currently one of the main components in the construction of roads and bridges.However,from a practical point of view,various quality problems are prone to occur in the surface layer of asphalt pavement,which will lead to the poor overall quality of road and bridge projects.Therefore,it should be applied reasonably.Advanced testing technologies are used to test the mixture quality,compaction,segregation,thickness,and other aspects of the asphalt pavement surface layer,so as to improve the quality of the asphalt pavement surface layer,and then improve the overall quality of road and bridge construction.Therefore,this paper mainly analyzes the technologies for asphalt pavement surface layer testing in road and bridge engineering construction.
文摘This study aimed to propose road crack detection method based on infrared image fusion technology.By analyzing the characteristics of road crack images,this method uses a variety of infrared image fusion methods to process different types of images.The use of this method allows the detection of road cracks,which not only reduces the professional requirements for inspectors,but also improves the accuracy of road crack detection.Based on infrared image processing technology,on the basis of in-depth analysis of infrared image features,a road crack detection method is proposed,which can accurately identify the road crack location,direction,length,and other characteristic information.Experiments showed that this method has a good effect,and can meet the requirement of road crack detection.
文摘Based on the as-built load test of a large bridge,this paper introduces the procedure of the prestressed concrete continuous rigid frame bridge load test.Numerical analysis of the bridge was carried out by simulating and establishing a finite element model,and comparative analysis was carried out with the measured values.The results show that the calculated values were basically consistent with the measured values,which showed that the establishment method of the model was reasonable,and the mechanical performance of the bridge met the service requirements of the designed live load.
基金Supported by a grant from the Scientific Research Foundation of the Educational Department of Liaoning province (No. 20272277).
文摘Objective: To investigate the clinical diagnostic value of peripheral lung cancer using multi-slice CT (MSCT) perfu- sion imaging and the relationship with microvessel density (MVD). Methods: 38 patients with pulmonary masses proved by pathology including 25 cases of peripheral lung cancer and 13 cases of benign masses were studied prospectively with GE Lightspeed Qx/I plus 16-slice helical CT perfusion imaging, and 25 patients with lung cancer were comparative studied with its MVD calculated using LSAB. With the CT perfusion 2-body tumor software, the parameters of CT perfusion including blood value (BV), blood flow (BF), mean transit time (MTT) and permeability surface (PS) were analyzed. Results: The four param- eter values in lung cancer were all higher than that in pulmonary benign masses, and there were significant differences among BV, MTT and PS (P<0.05), especially in BV (P<0.01). The MVD value of lung cancer was higher than that of pulmonary benign masses (P<0.05), and the MVD of adenocarcinoma was higher than that of squamous cell carcinoma (P<0.05). In 25 cases with lung cancer, there was positive correlation only between BV and MVD value (r=0.852, P<0.01). Conclusion: It is helpful to diagnose the peripheral lung cancer with MSCT perfusion imaging and to differentiate from pulmonary benign masses, its bases are MVD pathologically.
基金supported by the National Natural Science Foundation of China(6130115561571003)+2 种基金the Ministry of Education(MCM20130111)the Funds for the Central Universities(ZYGX2014J001)the State Grid Power(W2015000333)
文摘A novel collaborative beamforming algorithm is proposed in a wireless communication system with multiple transmitters and one receiver. All transmitters take part in the collaboration and the weighted message is transmitted simultaneously. In order to maximize the beamforming gain, the transmitters use one bit feedback information to adjust the phase offset. It tracks the direction in which the signal strength at the receiver can increase. The directional search and perturbation theory is used to achieve the phase alignment. The feasibility of the proposed algorithm is proved both experimentally and theoretically. Simulation results show that the proposed algorithm can improve the convergent speed of the phase alignment.
基金Supported by the National Natural Science Foundation of China(21276013,21676008)Specialized Research Fund for the Doctoral Program of Higher Education of China(20130010110001)
文摘The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide(O_3/H_2O_2 process) to degrade o-phenylenediamine(o-PDA) in a simulated wastewater. A rotor–stator reactor(RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA(η) as well as the overall gas-phase volumetric mass transfer coefficient(KGa) were determined under different operating conditions of H_2O_2 concentration, initial o-PDA concentration, temperature of reaction, initial p H and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate(rCOD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer(GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone(O_3 process), and it was noted that η, KGa and rCODachieved by O_3/H_2O_2 process was 24.4%,31.6% and 25.2% respectively higher than those of O_3 process, indicating that H_2O_2 can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.
基金the National Natural Science Foundation of China (Nos. 51775441&51835011)the National Science Fund for Excellent Young Scholars (No.51522509)Research Fund of the State Key Laboratory of Solidification Processing (NWPU) of China (KP201608)。
文摘Plastic forming is one of enabling and fundamental technologies in advanced manufacturing chains. Design optimization is a critical way to improve the performance of the forming system, exploit the advantages of high productivity, high product quality, low production cost and short time to market and develop precise, accurate, green, and intelligent(smart) plastic forming technology. However, plastic forming is quite complicated, relating to multi-physics field coupling,multi-factor influence, multi-defect constraint, and triple nonlinear, etc., and the design optimization for plastic forming involves multi-objective, multi-parameter, multi-constraint, nonlinear,high-dimensionality, non-continuity, time-varying, and uncertainty, etc. Therefore, how to achieve accurate and efficient design optimization of products, equipment, tools/dies, and processing as well as materials characterization has always been the research frontier and focus in the field of engineering and manufacturing. In recent years, with the rapid development of computing science, data science and internet of things(Io T), the theories and technologies of design optimization have attracted more and more attention, and developed rapidly in forming process. Accordingly, this paper first introduced the framework of design optimization for plastic forming. Then, focusing on the key problems of design optimization, such as numerical model and optimization algorithm,this paper summarized the research progress on the development and application of the theories and technologies about design optimization in forming process, including deterministic and uncertain optimization. Moreover, the applicability of various modeling methods and optimization algorithms was elaborated in solving the design optimization problems of plastic forming. Finally, considering the development trends of forming technology, this paper discusses some challenges of design optimization that may need to be solved and faced in forming process.
文摘An experimental investigation on the behavior and characteristics of interfacial waves in downward inclined rectangular channel was conducted. The interfacial waves were traced and measured by us-ing conductance technique. The wav patterns were distinguished and defined. The characteristics of the interfacial waves, such as time-averaged film thickness, wave height, wave propagation speed,wavlength and wave frequency, were systematically examined in terms of gas and liquid superficial volumetric fiuxes. The effect of the inclination and flow channel geometry of the test section on the interfacial wav was also investigated.
基金supported by the National Natural Science Foundation of China(31920103014,31970160)the Natural Science Foundation of Fujian Province(2020J06015)。
文摘Multiple viral infections in insect vectors with synergistic effects are common in nature,but the underlying mechanism remains elusive.Here,we find that rice gall dwarf reovirus(RGDV)facilitates the transmission of rice stripe mosaic rhabdovirus(RSMV)by co-infected leafhopper vectors.RSMV nucleoprotein(N)alone activates complete anti-viral autophagy,while RGDV nonstructural protein Pns11 alone induces pro-viral incomplete autophagy.In co-infected vectors,RSMVexploits Pns11-induced autophagosomes to assemble enveloped virions via N-Pns11-ATG5 interaction.Furthermore,RSMV could effectively propagate in Sf9 cells.Expression of Pns11 in Sf9 cells or leafhopper vectors causes the recruitment of N from the ER to Pns11-induced autophagosomes and inhibits N-induced complete autophagic flux,finally facilitating RSMV propagation.In summary,these results demonstrate a previously unappreciated role of autophagy in the regulation of the direct synergistic interaction during co-transmission of two distinct arboviruses by insect vectors and reveal the functional importance of virus-induced autophagosomes in rhabdovirus assembly.
基金supports from Fundamental Research Funds for the Central Universities,Programs for high-level entrepreneurial and innovative talents introduction of Jiangsu Province,and Scientific and Technological Innovation Foundation of Shunde Graduate School of USTB(No.BK19BE024).
文摘It remains elusive to realize the distinct catalysis of isomeric catalysts because it becomes challenging to identify structural isomers in the polydisperse nanoparticles.Herein we investigate catalysis of two geometric isomers for 36-gold-atom nanoclusters with different Au cores arrangements but the same thiolate ligands,thereby providing access to isomer catalysts readily participate in a desired reaction.Compared to the Au_(36)(SR)_(24)with a one-dimensional(1D)layout of Au4 tetrahedral units,the Au_(36)(SR)_(24)with a two-dimensional(2D)layout of Au4 tetrahedral units is more effective for the intramolecular hydroamination of alkyne.Our study suggests that the exposed Au sties of the two Au_(36)(SR)_(24)catalysts favor different reaction intermediates and pathways.The intramolecular H transfer leads to intermediates with the C-N and with C=N for the 1D and 2D Au_(36)(SR)_(24)respectively,and hence the different on-site and off-site pathways for the successive reaction steps account for the different performances of the two Au_(36)(SR)_(24)catalysts.