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NiO/TiO_(2)异质结构纳米管阵列膜对不锈钢的光生阴极保护及其储能性能 被引量:1
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作者 金飘 官自超 +4 位作者 梁燕 谭凯 王霞 宋光铃 杜荣归 《物理化学学报》 SCIE CAS CSCD 北大核心 2021年第3期66-72,共7页
本工作通过修饰TiO_(2)制备半导体复合膜,提高其光吸收和光电化学性能,以期应用于光生阴极保护。先采用阳极氧化法在Ti表面制备TiO_(2)纳米管阵列膜,再应用水热处理法在膜表面沉积NiO纳米颗粒,形成具有异质结构纳米管复合膜。利用扫描... 本工作通过修饰TiO_(2)制备半导体复合膜,提高其光吸收和光电化学性能,以期应用于光生阴极保护。先采用阳极氧化法在Ti表面制备TiO_(2)纳米管阵列膜,再应用水热处理法在膜表面沉积NiO纳米颗粒,形成具有异质结构纳米管复合膜。利用扫描电子显微镜、X-射线衍射、X-射线光电子能谱、紫外-可见吸收光谱、光致发光谱和光电化学技术对制备的纳米膜进行表征。结果表明,与纯TiO_(2)纳米管膜比较,NiO/TiO_(2)纳米管复合膜的光吸收扩展到可见光区。白光照射下,其在0.5 mol·L^(−1) KOH和1 mol·L^(−1) CH3OH混合液中的光电流密度达到176μA·cm^(−2),是纯TiO_(2)纳米管膜的2倍。复合膜具有良好的光生阴极保护作用,与0.5 mol·L^(−1) NaCl溶液中的403不锈钢耦连后,可使其电极电位下降440 mV,在光照2.5 h再转为暗态后,因具有电荷储存能力还可继续提供约15.5 h的阴极保护效应。 展开更多
关键词 阳极氧化 水热处理 TiO_(2)纳米管 NIO 光电化学 光生阴极保护 不锈钢
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Inhibition Effects of Pyrazine and Piperazine on the Corrosion of Mg-10Gd-3Y-0.5Zr Alloy in an Ethylene Glycol Solution 被引量:1
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作者 Daobing Huang Yuanqiang Tu +1 位作者 guangling song Xingpeng Guo 《American Journal of Analytical Chemistry》 2013年第6期36-38,共3页
The corrosion and inhibition effect of magnesium-based rare-earth containing alloy Mg-10Gd-3Y-0.5Zr (GW103) was studied in an ethylene glycol (EG) solution mixed with organic inhibitors. The inhibition efficiencies of... The corrosion and inhibition effect of magnesium-based rare-earth containing alloy Mg-10Gd-3Y-0.5Zr (GW103) was studied in an ethylene glycol (EG) solution mixed with organic inhibitors. The inhibition efficiencies of piperazine and pyrazine inhibitors on the corrosion of GW103 were compared by means of potentiodynamic polarization curve, electrochemical impedance spectroscopy (EIS) and weight loss measurements. It was found that the corrosion process of GW103 alloy in EG solution was hindered by these two inhibitors and the inhibition of pyrazine was more effective than that of piperazine. It was implied that pyrazine could be an effective inhibitor for GW103 in an ethylene glycol coolant solution. 展开更多
关键词 GW103 COOLANT INHIBITOR CORROSION
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Investigation of microbial corrosion inhibition of Cu-bearing 316L stainless steel in the presence of acid producing bacterium Acidithiobacillus caldus SM-1 被引量:1
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作者 Yuqiao Dong Jiaqi Li +6 位作者 Dake Xu guangling song Dan Liu Haipeng Wang M.Saleem Khan Ke Yang Fuhui Wang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第5期176-186,共11页
Stainless steel(SS)has unsatisfied corrosion resistance in many aggressive environments,particularly under a low p H condition in the bioleaching industry.In this study,through surface analyses and electrochemical mea... Stainless steel(SS)has unsatisfied corrosion resistance in many aggressive environments,particularly under a low p H condition in the bioleaching industry.In this study,through surface analyses and electrochemical measurements,the corrosion resistance of a novel Cu-bearing 316L SS was evaluated in the presence of an acid-producing bacterium,Acidithiobacillus caldus SM-1 that was able to create an extremely acidic corrosive environment.The significantly enhanced anti-microbiologically-inducedcorrosion performance could be explained by the intracellular reactive oxygen species(ROS)and Fenton reaction on the Cu-bearing 316L SS. 展开更多
关键词 Stainless steel Acid-producing bacteria Copper ion Reactive oxygen species Corrosion resistance
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