Micropipe and step structures on 6H-SiC (0001) surface were investigated by an atomic force microscopy (AFM). On the facet,all micropipes examined are the origins of spiral steps,indicating that dislocations inter...Micropipe and step structures on 6H-SiC (0001) surface were investigated by an atomic force microscopy (AFM). On the facet,all micropipes examined are the origins of spiral steps,indicating that dislocations intersect the surface at these points. Micropipes are empty-core super-dislocations as originally described by Frank. The micropipe radius increases with the square of the dislocation Burgers vector. From the center to the periphery,step structures change with different surface inclinations. Regular step is observed within the central faceted area. Step bunching and atomically rough surfaces are observed within the peripheral convex area. If the inclination with respect to the (0001) plane is large enough,step bunching of 15R-SiC can be observed.展开更多
Power offset is zero-order term in the capacity versus signal-to-noise ratio curve. In this paper, approximate analysis of power offset is presented to describe MIMO system with uniform linear antenna arrays of fixed ...Power offset is zero-order term in the capacity versus signal-to-noise ratio curve. In this paper, approximate analysis of power offset is presented to describe MIMO system with uniform linear antenna arrays of fixed length. It is assumed that the number of receive antenna is larger than that of transmit antenna. Spatially Correlated MIMO Channel is approximated by tri-diagonal toeplitz matrix. The determinant of tri-diagonal toeplitz matrix, which is fitted by elementary curve, is one of the key factors related to power offset. Based on the curve fitting, the determinant of tri-diagonal toeplitz matrix is mathematically tractable. Consequently, the expression of local extreme points can be derived to optimize power offset. The simulation results show that approximation above is accurate in local extreme points of power offset. The proposed expression of local extreme points is helpful to approach optimal power offset.展开更多
In this study, used tea leaves (UTLs) were pyrolyzed to obtain used tea-leaf biochar (UTC), and then the UTC was used as an adsorbent to remove ciprofioxacin (CIP) from aqueous solutions. Batch experiments were ...In this study, used tea leaves (UTLs) were pyrolyzed to obtain used tea-leaf biochar (UTC), and then the UTC was used as an adsorbent to remove ciprofioxacin (CIP) from aqueous solutions. Batch experiments were conducted to investigate the CIP adsorption performance and mechanism. The results showed that the CIP-adsorbing ability first increased and then declined as the UTC pyrolysis temperature increased. The UTC obtained at 450℃ presented excellent CIP-absorbing ability at pH 6 and 40℃. The maximum monolayer adsorption capacity was 238.10 mg/g based on the Langrnuir isotherm model. The pseudo-second-order kinetic equation agreed well with the CIP adsorption process, which was controlled by both external boundary layer diffusion and intra-particle diffusion. The characterization analysis revealed that the - OH groups, G=C bonds of aromatic rings, C- H groups in aromatic tings and phenolic C - O bonds play vital roles in the CIP adsorption process, and that the N - C, N - O, O- C-O and C- OH groups of UTC were consumed in large quantities. π-π interactions, hydrogen bonding and electrostatic attraction are inferred as the main adsorption mechanisms. The present work provides not only a feasible and promising approach for UTLs utilization but also a potential adsorbent material for removing high concentrations of CIP from aqueous solutions.展开更多
In view of the risks induced by the inhibitory effects of applying impracticably large amounts of sewage sludge biochar(SSB)to the alkaline soil,this field study investigated the influence of moderate biochar amendmen...In view of the risks induced by the inhibitory effects of applying impracticably large amounts of sewage sludge biochar(SSB)to the alkaline soil,this field study investigated the influence of moderate biochar amendments(0,1500,4500,and 9000 kg/hm2)on corn growth,alkaline soil properties,and the uptake of potentially toxic elements(PTEs).The results showed that applying more SSB would decrease the ammonium nitrogen concentration and increase the available phosphorus and potassium concentrations,which inhibited corn plant growth because of high background nutrient levels of the alkaline soil.When the alkaline soil was amended with 1500 kg/hm2 SSB,the dry weight of 100 niblets increased from 32.11 g in the control to 35.07 g.There was no significant variation in the total concentration of PTEs in the soil.The concentrations of Mn,Ni,Cu,and Zn in niblets decreased from 5.54,0.83,2.26,and 27.15 mg/kg in the control to 4.47,0.62,1.30,and 23.45 mg/kg,respectively.Accordingly,the health risk from corn consumption was significantly reduced.Furthermore,the combination of SSB and fertilizer improved corn growth and reduced the risk of consumption of PTEs.Therefore,considering the increase in corn fruit yield and the decrease in consumption risk,applying 1500 kg/hm2 of biochar to alkaline soils is a realistically achievable rate,which can broaden the utilization of SSB for remediation of different types of soil.展开更多
基金National High-Technology Research and Development Program of China (No2004AA31G030)
文摘Micropipe and step structures on 6H-SiC (0001) surface were investigated by an atomic force microscopy (AFM). On the facet,all micropipes examined are the origins of spiral steps,indicating that dislocations intersect the surface at these points. Micropipes are empty-core super-dislocations as originally described by Frank. The micropipe radius increases with the square of the dislocation Burgers vector. From the center to the periphery,step structures change with different surface inclinations. Regular step is observed within the central faceted area. Step bunching and atomically rough surfaces are observed within the peripheral convex area. If the inclination with respect to the (0001) plane is large enough,step bunching of 15R-SiC can be observed.
文摘Power offset is zero-order term in the capacity versus signal-to-noise ratio curve. In this paper, approximate analysis of power offset is presented to describe MIMO system with uniform linear antenna arrays of fixed length. It is assumed that the number of receive antenna is larger than that of transmit antenna. Spatially Correlated MIMO Channel is approximated by tri-diagonal toeplitz matrix. The determinant of tri-diagonal toeplitz matrix, which is fitted by elementary curve, is one of the key factors related to power offset. Based on the curve fitting, the determinant of tri-diagonal toeplitz matrix is mathematically tractable. Consequently, the expression of local extreme points can be derived to optimize power offset. The simulation results show that approximation above is accurate in local extreme points of power offset. The proposed expression of local extreme points is helpful to approach optimal power offset.
基金the financial support of the Industry Leading Key Projects of Fujian Province(No.2015H0044)the Key Project of Young Talent of Institute of Urban Environment,Chinese Academy of Sciences(No.IUEZD201402)+1 种基金the China-Japanese Research Cooperative Program(No.2016YFE0118000)the Scientific and Technological Major Special Project of Tianjin City(No.16YFXTSF00420)
文摘In this study, used tea leaves (UTLs) were pyrolyzed to obtain used tea-leaf biochar (UTC), and then the UTC was used as an adsorbent to remove ciprofioxacin (CIP) from aqueous solutions. Batch experiments were conducted to investigate the CIP adsorption performance and mechanism. The results showed that the CIP-adsorbing ability first increased and then declined as the UTC pyrolysis temperature increased. The UTC obtained at 450℃ presented excellent CIP-absorbing ability at pH 6 and 40℃. The maximum monolayer adsorption capacity was 238.10 mg/g based on the Langrnuir isotherm model. The pseudo-second-order kinetic equation agreed well with the CIP adsorption process, which was controlled by both external boundary layer diffusion and intra-particle diffusion. The characterization analysis revealed that the - OH groups, G=C bonds of aromatic rings, C- H groups in aromatic tings and phenolic C - O bonds play vital roles in the CIP adsorption process, and that the N - C, N - O, O- C-O and C- OH groups of UTC were consumed in large quantities. π-π interactions, hydrogen bonding and electrostatic attraction are inferred as the main adsorption mechanisms. The present work provides not only a feasible and promising approach for UTLs utilization but also a potential adsorbent material for removing high concentrations of CIP from aqueous solutions.
基金supported by the National Key Research and Development Project[2020YFC1908904]Science and Technology Program of Xiamen[3502Z20193076]+1 种基金Natural Science Foundation of Fujian Province[2019J01135]Strategic Priority Research Program of the Chinese Academy of Sciences[XDA23020504]。
文摘In view of the risks induced by the inhibitory effects of applying impracticably large amounts of sewage sludge biochar(SSB)to the alkaline soil,this field study investigated the influence of moderate biochar amendments(0,1500,4500,and 9000 kg/hm2)on corn growth,alkaline soil properties,and the uptake of potentially toxic elements(PTEs).The results showed that applying more SSB would decrease the ammonium nitrogen concentration and increase the available phosphorus and potassium concentrations,which inhibited corn plant growth because of high background nutrient levels of the alkaline soil.When the alkaline soil was amended with 1500 kg/hm2 SSB,the dry weight of 100 niblets increased from 32.11 g in the control to 35.07 g.There was no significant variation in the total concentration of PTEs in the soil.The concentrations of Mn,Ni,Cu,and Zn in niblets decreased from 5.54,0.83,2.26,and 27.15 mg/kg in the control to 4.47,0.62,1.30,and 23.45 mg/kg,respectively.Accordingly,the health risk from corn consumption was significantly reduced.Furthermore,the combination of SSB and fertilizer improved corn growth and reduced the risk of consumption of PTEs.Therefore,considering the increase in corn fruit yield and the decrease in consumption risk,applying 1500 kg/hm2 of biochar to alkaline soils is a realistically achievable rate,which can broaden the utilization of SSB for remediation of different types of soil.