A novel coordination polymer,formulated as Zn_(6)(TIB)_(4)(BPTC)_(3)(DMA)_(4)(H_(2)O)_(10)[TIB=1,3,5-tris(1-imidazolyl)-benzene,H_(4)BPTC=3,3',5,5'-biphenyltetracarboxylate],has been synthesized and structural...A novel coordination polymer,formulated as Zn_(6)(TIB)_(4)(BPTC)_(3)(DMA)_(4)(H_(2)O)_(10)[TIB=1,3,5-tris(1-imidazolyl)-benzene,H_(4)BPTC=3,3',5,5'-biphenyltetracarboxylate],has been synthesized and structurally characterized.Further investigations reveal that it presents a new topology(topological symbol{6^(2).8^(4)}{6^(3)}4{6^(5).8}6{6^(6)}2)based on self-penetration,and shows interesting fluorescent properties.展开更多
基金We are thankful for financial support from the 973 Program(Nos.2014CB932101,2013CB933200)the National Natural Science Foundation of China(Nos.21471148,21141006)the Natural Science Foundation of Fujian Province(No.2011J05038).
文摘A novel coordination polymer,formulated as Zn_(6)(TIB)_(4)(BPTC)_(3)(DMA)_(4)(H_(2)O)_(10)[TIB=1,3,5-tris(1-imidazolyl)-benzene,H_(4)BPTC=3,3',5,5'-biphenyltetracarboxylate],has been synthesized and structurally characterized.Further investigations reveal that it presents a new topology(topological symbol{6^(2).8^(4)}{6^(3)}4{6^(5).8}6{6^(6)}2)based on self-penetration,and shows interesting fluorescent properties.
