Origin of C type adakite magmas in the NE Xing＇an block, NE China and tectonic implication

In this paper, we report new whole-rock geochemical and zircon U–Pb data for monzogranites in the NE Xing'an block. These data constrained the petrogenesis of C type(high Sr/Y) adakitic rocks and showed the spatial extent of the influence of the Mongol-Okhostsk ocean tectonic regime and the collision between the Jiamusi Massif and Songliao Terrane. New zircon laser-ablation inductivity coupled plasma mass spectrometry(LA-ICP-MS) U–Pb data indicated that the monzogranites in the studied area were emplaced in the Early Jurassic(~180 Ma). These rocks were characterized by unusally high SiO_2(C67.49), and Sr(461–759 ppm), but strikingly low Y(4.63–8.06 ppm) and HREE(P HREE = 3.83–6.49 ppm, Yb = 0.5–0.77 ppm)contents, with therefore high Sr/Y(67.2–119) and(La/Yb)N(29.7–41.5) ratios, showing the geochemical characteristics of C type adakitic granite. The data displayed negligible Eu anomalies(Eu/Eu~ = 0.77–1.08), LREE-enriched and pronounced negative Nb and Ta anomalies. The C-typeadakites in the studied area were most likely derived from the partial melting of a thickened lower continental curst. The magma source is most likely dominated by amphibolites and garnet amphibolites. In combination with previously-reported data from igneous rocks from the Mesozoic in NE China, we conclude that the Xing'an block was influenced by the Mongol-Okhotsk subduction tectonic system, and experiences compressive settings from the amalgamation of the Jiamusi block in the east of the CAOB.

Age and geochemistry of Early Ordovician A-type granites in the Northeastern Songnen Block,NE China

Early Ordovician A-type granites in the northeastern(NE) Songnen Block NE China were studied to better understand the geodynamic settings in this region.This research presents new zircon U–Pb ages and wholerock geochemical data for the Early Ordovician granites in the NE Songnen Block. Zircon U–Pb dating indicates that the granite in the Cuibei, Hongxing, and Meixi areas in the NE Songnen Block formed in the Early Ordovician with ages of 471–479 Ma. The granites show geochemical characteristics of high SiO2 and K2 O compositions and low FeOT, MgO, CaO, and P2 O5 compositions. They belong to a high K calc-alkaline series and display a weak peraluminous featurPe with A/CNK values of 0.98–1.14. The rocks have aREE composition of 249.98–423.94 ppm,and are enriched in LREE with(La/Yb)Nvalues of2.87–9.87, and display obvious Eu anomalies(d Eu =0.01–0.29). Trace elements of the studied granites are characterized by enrichment in Rb, Th, U, Pb, Hf, and Sm,and depletion of Ba, Nb, Ta, and Sr. They display geochemical features of high Zr +Y + Nb+Ce values(324–795 ppm) and Ga/Al ratios consistent with A-type granites. Based on particular geochemical features, such as high Rb/Nb(7.98–24.19) and Y/Nb(1.07–3.43), the studied A-type granites can be further classified as an A2-type subgroup. This research indicates that the Early Ordovician A-type granites were formed by the partial melting of ancient crust in an extensional setting. Lower Sr/Y and(Ho/Yb)Nratios indicate that plagioclase and amphibole are residual in the source, and garnet is absent, implying that the magma was generated at low levels of pressure. By contrast, the contemporaneous granites in the SE Xing'an Block suggest a subduction-related tectonic setting, and its adakitic property indicates a thickened continental crust.We suggest that the Paleo-Asian Ocean plate between the Xing'an and Songnen blocks subducted northward during the Early Ordovician. Meanwhile, the NE Songnen Block was exposed to a passive continental margin tectonic setting.

The Influence Law of Oil Relative Permeability on Water Cut

Water cut is a key evaluation parameter for reservoir development evaluation. Relative permeability curve reflects reservoir characteristics and fluid characteristics. It is important to figure out the influence law of oil relative permeability on water cut. Based on the 269 relative permeability curves of Bohai oilfields, the distribution of oil index of Bohai oilfields were studied. On the basis, combined with Corey expression of relative permeability and fractional flow equation, the theoretical relationship between oil index and water cut increasing rate was established. Three end points of water cut increasing rate curve were proposed and the influence law between three end points and oil index was studied. The results show that the oil index has a linear relationship with three end points. When the value of water oil mobile ratio is large than 1, with the increase of oil index, maximum value of water cut increasing rate gradually increase. When the value of water oil mobile ratio is less than 10, oil index has great effect on recovery percent when water cut increasing rate reaches to the maximum value as well as water cut when water cut increasing rate reaches to the maximum value. The application of SS field shows that the theoretical value is consistent with the field data.

Study on Development Law of Complex Fluvial Reservoir under Water

The Bozhong oilfield (Hereinafter referred to as BZ oilfield) is a typical representative of complex fluvial reservoirs in the Bohai Sea, located in the southern Bohai Sea, with an average porosity of 30.3% and an average permeability of 643 × 10-3 μm2, belonging to medium high porosity and permeability reservoir, the reservoir has good connectivity, and the average underground crude oil viscosity is 5 mPa·s. There are many plane fault blocks, and the longitudinal oil well section is long, so the oil-water relationship is very complex. With the further development of the oilfield, the vertical and horizontal oil-water movement law, residual oil distribution and potential are unclear, resulting in rapid bottom water coning, unbalanced injection and production in the oilfield, and increasingly prominent contradictions among layers, planes and layers in the oilfield. Through numerical simulation analysis and comparison of displacement law and recovery degree under different influence conditions, this paper studies the development effect of actual sand body under different influence conditions such as different well types, different development methods and well layout positions, and takes appropriate development methods for the oilfield, which is of great significance to improve the development effect of the oilfield.

Stable Production Technology for Horizontal Well Development in Shallow Water Delta Oilfield of Bohai Bay, China

BZ Oilfield is a medium-sized oilfield with shallow delta facies deposits in Bohai Bay of China,compared with fluvial and delta facies oilfields,there is no mature experience for reference of reservoir configuration,well pattern arrangement and development model in offshore oilfields in China.In view of the difficulty in describing the reservoir configuration of shallow water delta,the single distributary sand dam in shallow water delta is characterized by well-seismic combination and multi-attribute constraints.The mathematical mechanism model of pinch-out position of sand body is established,fine characterization of BZ shallow water delta reservoir is put forward.The horizontal well pattern arrangement type for shallow water delta reservoir is proposed and the method of well pattern optimization based on vertical displacement theory is put forward.A method of inversion of reservoir connectivity using production dynamic data by numerical well testing is proposed and a new method for optimizing water injection rate in water injection wells is proposed aiming at the difficulty of recognizing injection-production connectivity of shallow water delta reservoirs.The fine configuration of BZ shallow water delta reservoir based on distributary sand dam is proposed,which guides the recognition of remaining oil distribution law.By deploying adjustment wells,the water flooding coincidence degree of actual drilling is 86% compared with that of pre-drilling prediction,which indicates that the research results of reservoir configuration can effectively guide the understanding of oilfield geology.Through the theoretical well arrangement type of vertical displacement of single sand body in horizontal wells of shallow water delta reservoir,a high water flooding recovery rate of 35% is achieved in primary well pattern.The connectivity coefficients of injection-production boundary of shallow water delta reservoir configuration are calculated,and the water injection distribution coefficients are obtained by normalizing the directional coefficients.This paper presents a configuration method based on multi-attribute fusion under the constraints of sedimentary process.In this paper,a shallow water delta reservoir configuration method based on multi-attribute fusion constrained by sedimentary process is proposed,and the injection-production connectivity coefficient and injection well distribution coefficient of the configuration boundary are calculated.

Understanding the excretion rates of methylmercury and inorganic mercury from human body via hair and fingernails

Effective biomarkers are necessary to better understand the human mercury(Hg) exposure levels. However, mismatched biomarker sampling method causes extra uncertainty in assessing the risk of Hg exposure. To compare the differences between hair and fingernail, and further understand the excretion rates of methylmercury(MeHg) and inorganic mercury(IHg) via hair and fingernails, the total mercury(THg), Me Hg, and IHg concentrations in paired hair and fingernail samples were investigated through paired samples collected from two typical mining areas, Wanshan mercury mine area(WMMA) and Hezhang zinc smelting area(HZSA). The positive correlation in THg, MeHg, and IHg concentrations( p < 0.01) between hair and fingernail samples indicated that those two biomarkers can be corrected in application of assessing human Hg exposure. Compared to fingernails, the hair was suggested to be a more sensitive biomarker as the concentration of THg, MeHg and IHg were 2~4 times higher than those in fingernails. Furthermore, the amounts of THg, MeHg, and IHg excreted via hair were 70~226 times higher than that excreted via fingernails, and the hair plays a more important role than fingernails in the excretion of Hg from human bodies. Present study therefore provides some new insights to better understand the fate of human assimilated Hg.