A general synthetic strategy for N, P co-doped graphene supported metal-rich noble metal phosphides for hydrogen generation

The exploitation of electrocatalysts with high activity and durability for HER is desirable for future energy systems,but it is still a challenge.NMPs have attracted increasing attentions,but the preparation process often needs toxic regents or dangerous reaction conditions.Herein,we develop a general green method to fabricate metal-rich NMPs anchored on NPG through pyrolyzing DNA cross-linked complexes.The obtained Ru_(2) P-NPG exhibits an ultrasmall overpotential of 7 mV at 10 mA cm^(2) and ultralow Tafel slope of 33 mV dec^(-1) in 1.0 mol L?1 KOH,even better than that of commercial Pt/C.In addition,Ru 2 P-NPG also shows low overpotentials of 29 and 78 mV in 0.5 mol L^(-1) H_(2)SO_(4) and 1.0 mol L^(-1) PBS,respectively.The superior activity can be attributed to the ultrafine dispersion of Ru 2 P nanoparticles for more accessible sites,more defects formed for abundant active sites,the two-dimensional plane structure for accelerated electron transfer and mass transport,as well as the regulation of electron distribution of the catalyst.Moreover,the synthetic method can also be applied to prepare other metal-rich noble metal phosphides(Pd_(3)P-NPG and Rh_(2)P-NPG),which also exhibits high activity for HER.This work provides an effective strategy for designing NMP-based electrocatalysts.

Rules of Changes in Soil Nutrients and Enzyme Activities of Larix principis-rupprechtii in Different Forest Ages

In this study,three different ages of Larix principis-rupprechtii forests in 5,10 and 20 years were selected as the research objects,and the changes in soil nutrient and soil enzyme activities in different growth stages were analyzed. The results showed that the contents of organic matter and available phosphorus in the soil of different growth stages showed a significant downward trend with the increase of soil depth.For different forest ages in the same soil layer,the soil available phosphorus content declined with the increase of the forest age. The organic matter content of 40-60 cm in 20 years of forest age was the lowest in July,which was 4. 17 g/kg,significantly lower than that in other soil layers. Besides,the soil available phosphorus content of 5 years of forest age reached the maximum in July,with an average of 4. 44 mg/kg,which was higher than the available phosphorus content in soil in May and September,but the difference between the three months was not significant. The changes in ammonium nitrogen and nitrate nitrogen content in soil with different forest ages were consistent with the changes in the soil depth,showing a downward trend. In the new leaf stage,the ammonium nitrogen content of the L. principis-rupprechtii forest land in5 years of age at 20-40 and 40-60 cm of the soil depth was 13. 47 and 9. 09 mg/kg,respectively,which was 46. 9% and 64. 2% lower than that at 0-20 cm( 25. 36 mg/kg) of the soil depth. The soil nitrate nitrogen content of 20 years of forest age was 19. 24 mg/kg,which was25. 8% lower than that of 10 years of forest age,showing significant difference( P < 0. 05). In addition,with the increase of the age of L. principis-rupprechtii,soil catalase( CAT),alkaline phosphatase( ALP) and urease( Ure) decreased,and the decline of ALP was slow,while CAT and Ure decreased significantly. In summary,it is concluded that the soil fertility of forest land declined with the increase of forest age on the basis of change trend of soil nutrient and soil enzyme activity in the surveyed forest age.

Spacecraft damage infrared detection algorithm for hypervelocity impact based on double-layer multi-target segmentation

To detect spacecraft damage caused by hypervelocity impact,we propose an advanced spacecraft defect extraction algorithm based on infrared imaging detection.The Gaussian mixture model(GMM)is used to classify the temperature change characteristics in the sampled data of the infrared video stream and reconstruct the image to obtain the infrared reconstructed image(IRRI)reflecting the defect characteristics.The designed segmentation objective function is used to ensure the effectiveness of image segmentation results for noise removal and detail preservation,while taking into account the complexity of IRRI(that is,the required trade-offs are different).A multi-objective optimization algorithm is introduced to achieve balance between detail preservation and noise removal,and a multi-objective evolutionary algorithm based on decomposition(MOEA/D)is used for optimization to ensure damage segmentation accuracy.Experimental results verify the effectiveness of the proposed algorithm.