Ho^(3+)-Yb^(3+) co-doped and Ho^(3+)-Yb^(3+)-Li^+ tri-doped TiO_2 nanocrystals were prepared using the sol-gel method. Effects of the calcination temperature and Li^+ ions doping on the structure and upconversion lumi...Ho^(3+)-Yb^(3+) co-doped and Ho^(3+)-Yb^(3+)-Li^+ tri-doped TiO_2 nanocrystals were prepared using the sol-gel method. Effects of the calcination temperature and Li^+ ions doping on the structure and upconversion luminescence properties of Ho^(3+)-Yb^(3+) co-doped TiO_2 nanocrystals were investigated. The upconversion luminescence of nanocrystals was enhanced with the reduction of the crystal lattice symmetry and the crystallinity improvement of the matrix, which were facilitated by the calcination temperature change and Li^+ ions doping. The lowest lattice symmetry and the best crystallinity of the matrix resulted in the maximum luminescence intensity.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.51352002)the China Postdoctoral Science Foundation (Grant No.2017M611166)
文摘Ho^(3+)-Yb^(3+) co-doped and Ho^(3+)-Yb^(3+)-Li^+ tri-doped TiO_2 nanocrystals were prepared using the sol-gel method. Effects of the calcination temperature and Li^+ ions doping on the structure and upconversion luminescence properties of Ho^(3+)-Yb^(3+) co-doped TiO_2 nanocrystals were investigated. The upconversion luminescence of nanocrystals was enhanced with the reduction of the crystal lattice symmetry and the crystallinity improvement of the matrix, which were facilitated by the calcination temperature change and Li^+ ions doping. The lowest lattice symmetry and the best crystallinity of the matrix resulted in the maximum luminescence intensity.
