SYNTHESIS AND REACTIVITY OF SPIROHYDRIDOPHOSPHORANE CONTAINING α-AMINOACETOXY GROUP

Reaction of glycine with phosphorus trichloride in presence of triethylamine has urnished the ovel spirohydridophosphorane.Its structure has been characterized by elemental analysis,n.m.r.spectra and mass spectrum.The compound reacted with phenylisothiocyanate to give 2-phenyliminothiazolid-5-one.

NEW SYNTHETIC ROUTE TO ALKOXYPHOSPHORNES

A series of hydridophosphoranes reacted with benzenesulfenic esters to give the corresponding alkoxyphosphoranes in good fields.