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高强抗蠕变水性抗菌聚氨酯及其生物降解性能
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作者 王兆飞 樊康鑫 +7 位作者 姚皖生 周意杨 董晓宇 牛宇洁 董勇 张佰尧 张国兵 丁运生 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第1期18-24,共7页
以聚乳酸多元醇、聚四氢呋喃二醇、异佛尔酮二异氰酸酯、二甲胺基丙胺二异丙醇等原料合成了水性聚氨酯预聚体(PLA-WPU-C-pre);再通入二氧化碳(CO_(2))与PLA-WPU-C-pre在水中反应,经搅拌乳化后得到聚乳酸基水性聚氨酯乳液(PLA-WPU);在乳... 以聚乳酸多元醇、聚四氢呋喃二醇、异佛尔酮二异氰酸酯、二甲胺基丙胺二异丙醇等原料合成了水性聚氨酯预聚体(PLA-WPU-C-pre);再通入二氧化碳(CO_(2))与PLA-WPU-C-pre在水中反应,经搅拌乳化后得到聚乳酸基水性聚氨酯乳液(PLA-WPU);在乳液成膜过程中,以1,6-二碘己烷为交联剂实现了PLA-WPU的固化交联,得到高强抗蠕变水性抗菌聚氨酯(PLA-WPU-C)。研究探讨了聚乳酸多元醇用量、交联和退火时间对PLA-WPU-C力学性能、抗菌性能和生物降解性能的影响。结果表明,PLA-WPU-C具有较好的生物降解与抗菌性能,当聚四氢呋喃二醇与聚乳酸多元醇的摩尔比为3:1、退火时间为1 h时,交联PLA-WPU力学性能较好(27.8 MPa和384%)。 展开更多
关键词 聚乳酸多元醇 水性聚氨酯 高强度 生物降解 抗菌 抗蠕变
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二氧化碳响应型高效乳化/去乳化水性聚氨酯的制备及性能 被引量:2
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作者 徐梁峰 王兆飞 +4 位作者 董晓宇 杨公雯 张国兵 方华高 丁运生 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第7期8-13,共6页
以异佛尔酮二异氰酸酯、聚醚二元醇、二甲胺基丙胺二异丙醇、丙烯酸羟乙酯等为原料合成了含有碳碳双键的聚氨酯预聚体,将其与温敏性单体甲基丙烯酸二甲氨基乙酯混合,通过自由基共聚制备了一系列二氧化碳响应型水性聚氨酯-聚甲基丙烯酸... 以异佛尔酮二异氰酸酯、聚醚二元醇、二甲胺基丙胺二异丙醇、丙烯酸羟乙酯等为原料合成了含有碳碳双键的聚氨酯预聚体,将其与温敏性单体甲基丙烯酸二甲氨基乙酯混合,通过自由基共聚制备了一系列二氧化碳响应型水性聚氨酯-聚甲基丙烯酸二甲氨基乙酯(WPU-co-PDM)乳液,并对乳液和涂层进行了测试与表征。结果表明,聚甲基丙烯酸二甲氨基乙酯(PDMAEMA)对热和pH双重响应促进了乳液在常温下的乳化/去乳化过程,含有温敏结构单元的聚氨酯乳化和去乳化过程更加高效,其膜的耐水性和耐热性能较好。 展开更多
关键词 水性聚氨酯 聚甲基丙烯酸二甲氨基乙酯 亲疏水性调控 耐水性 力学性能
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Effects of Drought Stress Simulated by Polyethylene Glycol on Seed Germination, Root and Seedling Growth, and Seedling Antioxidant Characteristics in Job’s Tears 被引量:4
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作者 Can Wang Lingbo Zhou +5 位作者 guobing zhang Yan Xu Xu Gao Ne Jiang Liyi zhang Mingbo Shao 《Agricultural Sciences》 2018年第8期991-1006,共16页
Two Job’s tears cultivars, yy18-1 (high resistance to drought stress) and yy12-7 (susceptible to drought stress) were used to investigate the responses of seed germination, root and seedling growth, and seedling anti... Two Job’s tears cultivars, yy18-1 (high resistance to drought stress) and yy12-7 (susceptible to drought stress) were used to investigate the responses of seed germination, root and seedling growth, and seedling antioxidant characteristics to drought stress simulated by polyethylene glycol (PEG) 6000 solutions with 0, -0.05, -0.1, -0.15, and -0.2 MPa osmotic potentials. The results showed that the germination energy, germination rate, germination index, root and seedling lengths, root and seedling diameters, root and seedling fresh masses, root and seedling dry masses, and seedling relative water content (RWC) decreased with the decrease of the osmotic potential of PEG 6000 solution. The contents of hydrogen peroxide (H2O2), malondialdehyde (MDA), and proline in seedling increased with the decrease of the osmotic potential of PEG 6000 solution. The activities of peroxidase (POD), catalase (CAT), ascorbate peroxidase (APX), and glutathione reductase (GR) in seedling increased and then decreased with the decrease of osmotic potential of PEG 6000 solution. -0.1 MPa was the optimal osmotic potential of PEG 6000 solution simulated drought stress at germination stage for Job’s tears. The proline content and activities of POD and CAT were important mechanisms for the maintenance of drought resistance in Job’s tears seedling. 展开更多
关键词 ANTIOXIDANT CHARACTERISTICS Drought Stress Germination GROWTH Job’s TEARS Polyethylene GLYCOL
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Wide tunable laser based on electrically regulated bandwidth broadening in polymer-stabilized cholesteric liquid crystal 被引量:1
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作者 HONGBO LU CHENG WEI +8 位作者 QIANG zhang MIAO XU YUNSHENG DING guobing zhang JUN ZHU KANG XIE XIAOJUAN zhang ZHIJIA HU LONGZHEN QIU 《Photonics Research》 SCIE EI CSCD 2019年第2期137-143,共7页
Electrically responsive photonic crystals represent one of the most promising intelligent material candidates for technological applications in optoelectronics. In this research, dye-doped polymer-stabilized cholester... Electrically responsive photonic crystals represent one of the most promising intelligent material candidates for technological applications in optoelectronics. In this research, dye-doped polymer-stabilized cholesteric liquid crystals(PSCLCs) with negative dielectric anisotropy were fabricated, and mirrorless lasing with an electrically tunable wavelength was successfully achieved. Unlike conventional liquid-crystal lasers, the proposed laser aided in tuning the emission wavelength through controlling the reflection bandwidth based on gradient pitch distribution. The principal advantage of the electrically controlled dye-doped PSCLC laser is that the electric field is applied parallel to the helical axis, which changes the pitch gradient instead of rotating the helix axis, thus keeping the heliconical structure intact during lasing. The broad tuning range(~110 nm) of PSCLC lasers,coupled with their stable emission performance, continuous tunability, and easy fabrication, leads to its numerous potential applications in intelligent optoelectronic devices, such as sensing, medicine, and display. 展开更多
关键词 WIDE TUNABLE laser electrically polymer-stabilized
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Band-gap-tailored random laser 被引量:1
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作者 HONGBO Lu JIAN XING +7 位作者 CHENG WEI JIANGYING XIA JUNQING SHA YUNSHENG DING guobing zhang KANG XIE LONGZHEN QIU ZHIJIA Hu 《Photonics Research》 SCIE EI 2018年第5期390-395,共6页
A band-gap-tailored random laser with a wide tunable range and low threshold through infrared radiation is demonstrated. When fluorescent dyes are doped into the liquid crystal and heavily doped chiral agent system,we... A band-gap-tailored random laser with a wide tunable range and low threshold through infrared radiation is demonstrated. When fluorescent dyes are doped into the liquid crystal and heavily doped chiral agent system,we demonstrate a wavelength tuning random laser instead of a side-band laser, which is caused by the combined effect of multi-scattering of liquid crystal(LC) and band-gap control. Through rotating the infrared absorbing material on the side of the LC cell, an adjustable range for random lasing of 80 nm by infrared light irradiation was observed. 展开更多
关键词 LENGTH LC Band-gap-tailored random laser
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