Recent progress in fluorinated electrolytes for improving the performance of Li–S batteries

Lithium–sulfur(Li–S) batteries represent a "beyond Li-ion" technology with low cost and high theoretical energy density and should fulfill the ever-growing requirements of electric vehicles and stationary energy storage systems. However, the sulfur-based conversion reaction in conventional liquid electrolytes results in issues like the so-called shuttle effect of polysulfides and lithium dendrite growth, which deteriorate the electrochemical performance and safety of Li–S batteries. Optimization of conventional organic solvents(including ether and carbonate) by fluorination to form fluorinated electrolytes is a promising strategy for the practical application of Li–S batteries. The fluorinated electrolytes, owing to the high electronegativity of fluorine, possesses attractive physicochemical properties, including low melting point,high flash point, and low solubility of lithium polysulfide, and can form a compact and stable solid electrolyte interphase(SEI) with the lithium metal anode. Herein, we review recent advancements in the development of fluorinated electrolytes for use in Li–S batteries. The effect of solvent molecular structure on the performance of Li–S batteries and the formation mechanism of SEI on the cathode and anode sides are analyzed and discussed in detail. The remaining challenges and future perspectives of fluorinated electrolytes for Li–S batteries are also presented.

Proton belt variations traced back to Fengyun-1C satellite observations

We used historical data to trace trapped protons observed by the Fengyun-1C(FY-1C)satellite at low Earth orbits(~800 km)and chose data at 5–10 MeV,10–40 MeV,40–100 MeV,and^100–300 MeV from 25 March to 18 April 2000 to analyze the proton variations.Only one isolated strong storm was associated with a solar proton event during this period,and there was no influence from previous proton variations.Complex dynamic phenomena of proton trapping and loss were affected by this disturbance differently depending on the energy and L location.The flux of 5–10 MeV protons increased and created new trapping with a maximum at L^2.0,and the peak flux was significantly higher than that at the center of the South Atlantic Anomaly.However,at higher L,the flux showed obvious loss,with retreat of the outer boundary from L^2.7 to L^2.5.The increase in the 10–40 MeV proton flux was similar to that of the 5–10 MeV flux;however,the peak flux intensity was lower than that at the center of the South Atlantic Anomaly.The loss of the 10–40 MeV proton flux was closer to the Earth side,and the outer boundary was reduced from L^2.3 to L^2.25.For the higher energy protons of 40–100 MeV and 100–300 MeV,no new trapping was found.Loss of the 40–100 MeV protons was observed,and the outer boundary shifted from L^2.0 to L^1.9.Loss was not obvious for the 100–400 MeV protons,which were distributed within L<1.8.New proton trapping was more likely to be created at lower energy in the region of solar proton injection by the strong magnetic storm,whereas loss occurred in a wide energy range and reduced the outer boundary on the Earth side.Similar dynamic changes were observed by the NOAA-15 satellite in the same period,but the FY-1C satellite observed more complex changes in lower energy protons.These results revealed that the dynamic behavior of protons with different L-shells was due to differences in the pitch angle.Possible mechanisms related to new trapping and loss are also discussed.These mechanisms are very important for understanding the behavior of the proton belt in the coming solar cycle.

Overview to the Hard X-ray Modulation Telescope (Insight-HXMT) Satellite

As China’s first X-ray astronomical satellite, the Hard X-ray Modulation Telescope (HXMT), which was dubbed as Insight-HXMT after the launch on June 15, 2017, is a wide-band(1-250 ke V) slat-collimator-based X-ray astronomy satellite with the capability of all-sky monitoring in 0.2-3 Me V. It was designed to perform pointing, scanning and gamma-ray burst(GRB)observations and, based on the Direct Demodulation Method (DDM), the image of the scanned sky region can be reconstructed.Here we give an overview of the mission and its progresses, including payload, core sciences, ground calibration/facility, ground segment, data archive, software, in-orbit performance, calibration, background model, observations and some preliminary results.