Wide temperature range-and damage-tolerant microsupercapacitors from salt-tolerant, anti-freezing and self-healing organohydrogel via dynamic bonds modulation

The advance of microelectronics requires the micropower of microsupercapacitors(MSCs) to possess wide temperature-and damage-tolerance beyond high areal energy density.The properties of electrolyte are crucial for MSCs to meet the above requirements.Here,an organohydrogel electrolyte,featured with high salt tolerance,ultralow freezing point,and strong self-healing ability,is experimentally realized via modulating its inner dynamic bonds.Spectroscopic and theoretical analysis reveal that dimethyl sulfoxide has the ability to reconstruct Li^(+)solvation structure,and interact with free water and polyvinyl alcohol chains via forming hydrogen bonds.The organohydrogel electrolyte is employed to build MSCs,which show a boosted energy density,promising wide temperature range-and damage-tolerant ability.These attractive features make the designed organohydrogel electrolyte have great potential to advance MSCs.

Enhancing electrolyte ion diffusion via direct ink writing pillar array structure of graphene electrodes for high-performance microsupercapacitors

The graphene-based microsupercapacitors(MSCs)suffer from graphene aggregation issue in electrodes.It reduces the electrolyte ions transportation in the electrodes to degrade the charge storage ability of MSCs,hampering their practical application.Increasing the electrolyte ions transportation in the electrodes can boost the charge storage ability of MSCs.Herein,we design and experimentally realize pillar array structure of graphene electrodes for MSCs by direct ink writing technology.The graphene electrodes with pillar array structure increase the contact area with electrolyte and short the electrolyte ions transport path,facilitating electrolyte ions transport in electrodes.The MSCs exhibit high areal capacitance of 25.67 mF·cm^(−2),high areal energy density of 20.54μWh·cm^(−2),and high power density of 1.45 mW·cm^(−2).One single MSCs can power timer for 10 min and pressure sensor more than 160 min,showing high practical application possibility.This work provides a new avenue for developing high performance MSCs.