Furfural is directly converted to levulinate esters（isopropyl levulinate and furan-2-ylmethyl-levulinate） as potential biofuel feedstocks, through a combined catalytic strategy. Nb;O;-ZrO;mixed oxide microspheres ar...Furfural is directly converted to levulinate esters（isopropyl levulinate and furan-2-ylmethyl-levulinate） as potential biofuel feedstocks, through a combined catalytic strategy. Nb;O;-ZrO;mixed oxide microspheres are used as bifunctional catalysts for hydrogen-transfer hydrogenation and acid-catalyzed alcoholysis in isopropanol. Bifunctional catalysts improve sustainability of furfural conversion through process intensification. Hydrogen transfer hydrogenation from isopropanol avoids dangerous hydrogen gas, and abates process and environmental costs. Isopropyl levulinate and furan-2-ylmethyl-levulinate are the main products that can be applied as blending components in biodiesel or hydrocarbon fuels.展开更多
The steel roof of Jiangmen gymnasium is the large-span spatial pipe truss structure, which is composed of main truss, secondary truss and stable truss. This paper systematically expounds the construction simulation an...The steel roof of Jiangmen gymnasium is the large-span spatial pipe truss structure, which is composed of main truss, secondary truss and stable truss. This paper systematically expounds the construction simulation analysis, the composition of the construction monitoring system, the monitoring method, and the arrangement of measuring points. The construction simulation analysis simulates the whole process of the main truss cumulative lifting installation, the secondary truss and auxiliary structure hoisting, and then the main truss for overall unloading, which is the difficulty of the whole project. The results of the structural construction monitoring show that the roof structure is in a safe state, and the fine construction simulation analysis provides a theoretical basis for the construction process, and the theoretical value of the simulation analysis is in good agreement with the measured data. In addition, vertical displacement and stress are obvious mutations in the unloading stage of roof support, but the stress of each measuring point is in elastic working condition, which meets the design requirements, indicating the correctness of the model and method in construction simulation analysis and calculation, and also provides reference for the design and construction of related projects in the future.展开更多
基金supported by the National Natural Science Foundation of China (21403248, 21174148, 21101161, and 21304101)
文摘Furfural is directly converted to levulinate esters（isopropyl levulinate and furan-2-ylmethyl-levulinate） as potential biofuel feedstocks, through a combined catalytic strategy. Nb;O;-ZrO;mixed oxide microspheres are used as bifunctional catalysts for hydrogen-transfer hydrogenation and acid-catalyzed alcoholysis in isopropanol. Bifunctional catalysts improve sustainability of furfural conversion through process intensification. Hydrogen transfer hydrogenation from isopropanol avoids dangerous hydrogen gas, and abates process and environmental costs. Isopropyl levulinate and furan-2-ylmethyl-levulinate are the main products that can be applied as blending components in biodiesel or hydrocarbon fuels.
文摘The steel roof of Jiangmen gymnasium is the large-span spatial pipe truss structure, which is composed of main truss, secondary truss and stable truss. This paper systematically expounds the construction simulation analysis, the composition of the construction monitoring system, the monitoring method, and the arrangement of measuring points. The construction simulation analysis simulates the whole process of the main truss cumulative lifting installation, the secondary truss and auxiliary structure hoisting, and then the main truss for overall unloading, which is the difficulty of the whole project. The results of the structural construction monitoring show that the roof structure is in a safe state, and the fine construction simulation analysis provides a theoretical basis for the construction process, and the theoretical value of the simulation analysis is in good agreement with the measured data. In addition, vertical displacement and stress are obvious mutations in the unloading stage of roof support, but the stress of each measuring point is in elastic working condition, which meets the design requirements, indicating the correctness of the model and method in construction simulation analysis and calculation, and also provides reference for the design and construction of related projects in the future.
