In recent years,chiral discrete supramolecular coordination complexes have attracted increasing interest as simple enzyme mimetics owing to their aesthetic architectures and potential applications in chiral science.Th...In recent years,chiral discrete supramolecular coordination complexes have attracted increasing interest as simple enzyme mimetics owing to their aesthetic architectures and potential applications in chiral science.This review summarizes the recent advances on chiral coordination metallacy-cles/metallacages with inherent cavities for enanti on selective recog nition and separation,including their design principles and synthesis,the in troduc-tion of chirality and functionality,structural adaptability,and host-guest bonding in enantioselective process.Finally,the perspectives on the remain-ing challenges and future opportunities are presented.展开更多
1.Introduction Metal ions have played a vital role in various living systems and in-dustrial applications for a long time[1].Among them,Fe3+is a basic component of hemoglobin,and undertakes the responsibility of biolo...1.Introduction Metal ions have played a vital role in various living systems and in-dustrial applications for a long time[1].Among them,Fe3+is a basic component of hemoglobin,and undertakes the responsibility of biolog-ical processes related to oxygen transport,proteins and transcriptional events[2].展开更多
基金This work was supported by the National Natural Science Foundation of China(Grants 21671002,21603001,22025107 and 21722105)the National Youth Top-notch Talent Support Program of China,the Anhui Provinee Natural Science Funds for Distin-guished Young Scholar(Grants 1808085J25)the Provincial Natural Science Research Program of Higher Education Institutions of Anhui Province(KJ2019A0071).
文摘In recent years,chiral discrete supramolecular coordination complexes have attracted increasing interest as simple enzyme mimetics owing to their aesthetic architectures and potential applications in chiral science.This review summarizes the recent advances on chiral coordination metallacy-cles/metallacages with inherent cavities for enanti on selective recog nition and separation,including their design principles and synthesis,the in troduc-tion of chirality and functionality,structural adaptability,and host-guest bonding in enantioselective process.Finally,the perspectives on the remain-ing challenges and future opportunities are presented.
基金supported by the National Natural Science Foundation of China(Nos.22171002 and 21603001)the Wanjiang Scholar Program,and the Natural Science Foundation of Anhui Province(No.2108085MB54).
文摘1.Introduction Metal ions have played a vital role in various living systems and in-dustrial applications for a long time[1].Among them,Fe3+is a basic component of hemoglobin,and undertakes the responsibility of biolog-ical processes related to oxygen transport,proteins and transcriptional events[2].
