Bioinspired cellulose-integrated MXene-based hydrogels for multifunctional sensing and electromagnetic interference shielding

Bioinspired hydrogels are complex materials with distinctive properties comparable to biological tissues.Their exceptional sensitivity to various external stimuli leads to substantial application potential in wearable smart devices.However,these multifaceted hydrogels are often challenging to be combined with pattern customization,stimulus responsiveness,self-healing,and biocompatibility.Herein,inspired by mussel secretions,a printable,self-healing,and biocompatible MXene-based composite hydrogel was designed and prepared by incorporating Ti3C2Tx MXene nanosheets into the hydrogel framework through the chelation of calcium ions(Ca2+)with polyacrylic acid and cellulose nanofibers at alkaline conditions.The biocompatible conductive hydrogel exhibited sensitivity(gauge factor of 2.16),self-healing(within 1 s),recognition,and adhesion,distinguishing it as an ideal candidate for wearable multifunctional sensors toward strain sensing,vocal sensing,signature detection,and Morse code transmission.Additionally,the multifunctional hydrogel manifested efficient electromagnetic interference shielding properties(reaching more than 30 dB at a thickness of 2.0 mm),protecting electronics and humans from electromagnetic radiation and pollution.Therefore,the presented work represents a versatile strategy for developing environmentally friendly conductive hydrogels,demonstrating the perspectives of intelligent hydrogels for multifunctional applications.

Nanocellulose-assisted preparation of electromagnetic interference shielding materials with diversified microstructure

Sustainable and renewable nanocellulose attracts more and more attention in various fields due to its high strength-to-weight ratio,small diameter,large aspect ratio,and abundant functional groups.The excellent properties and structural characteristics enabled a great potential of nanocellulose for efficient interactions with functional nanomaterials such as carbon nanotube,graphene,transition metal carbides/nitrides(MXenes),and metal nanoparticles,which is beneficial for preparing high-performance electromagnetic interference(EMI)shields.We review the advances in the nanocelluloseassisted preparation of composite films and aerogels for EMI shielding application.The nanocellulose-based composites are evaluated in terms of their EMI shielding performance and the shielding mechanisms,including conduction,polarization,and multiple reflections are summarized.In addition to the constituent structure and contents,we highlight the significance of the microstructure design in enhancing the EMI shielding performance of the nanocellulose-based EMI shields.Finally,the current challenges and outlook for these fascinating nanocellulose-based EMI shielding composites are discussed.