Two palladium complexes, （Ph3P）2PdBr2 and （PhsP）2PdI2, were synthesized by a new method and their structures were confirmed by NMR, elemental analysis and X-ray crystallography. The catalytic activity of the two p...Two palladium complexes, （Ph3P）2PdBr2 and （PhsP）2PdI2, were synthesized by a new method and their structures were confirmed by NMR, elemental analysis and X-ray crystallography. The catalytic activity of the two palladium complexes was evaluated in Mizoroki-Heck cross-coupling reaction of aryl halide with acrylate, and the results show that they all have high catalytic activity to many different substrates.展开更多
Three new Pd-pyridine enlianced precatalyst preparation stabilization and initiation(PEPPSI)complexes with halogen groups on the N-heterocyclic carbene and pyridine were prepared.Tlieir structures have been clearly ch...Three new Pd-pyridine enlianced precatalyst preparation stabilization and initiation(PEPPSI)complexes with halogen groups on the N-heterocyclic carbene and pyridine were prepared.Tlieir structures have been clearly characterized by nuclear magnetic resonance spectroscopy and X-ray single-crystal di fraction.The e fleets of the electronic properties of halogen groups on the catalytic activity in the Suzuki-Miyaura cross-coupling of aryl chlo-rides were investigated.These Pd-PEPPSI complexes could catalyze the cross-coupling reaction efficiently with a low catalyst loading(0.05%,molar ratio)at room temperature and the products were obtained in high yields.展开更多
基金Supported by the Natural Science Foundation of Tianjin, China（No. 16JCYBJC19700） and the Innovation Team Plan of the Tianjin Education Committee, China（No. TD 12 -5037）.
文摘Two palladium complexes, （Ph3P）2PdBr2 and （PhsP）2PdI2, were synthesized by a new method and their structures were confirmed by NMR, elemental analysis and X-ray crystallography. The catalytic activity of the two palladium complexes was evaluated in Mizoroki-Heck cross-coupling reaction of aryl halide with acrylate, and the results show that they all have high catalytic activity to many different substrates.
基金Supported by the Natural Science Foundation of Tianjin City,China(No.16JCYBJC 19700)the National Natural Science Foundation of China(No.21771138)the Foundation of Development Program of Future Expert in Tianjin Normal University,China(No.WLQR201704).
文摘Three new Pd-pyridine enlianced precatalyst preparation stabilization and initiation(PEPPSI)complexes with halogen groups on the N-heterocyclic carbene and pyridine were prepared.Tlieir structures have been clearly characterized by nuclear magnetic resonance spectroscopy and X-ray single-crystal di fraction.The e fleets of the electronic properties of halogen groups on the catalytic activity in the Suzuki-Miyaura cross-coupling of aryl chlo-rides were investigated.These Pd-PEPPSI complexes could catalyze the cross-coupling reaction efficiently with a low catalyst loading(0.05%,molar ratio)at room temperature and the products were obtained in high yields.
