Adsorption of Neutral Red (NR) onto peanut husk in aqueous solutions was investigated at 295 K. Experiments were carried out as function of pH, adsorbent dosage, contact time, and initial concentration. The equilibriu...Adsorption of Neutral Red (NR) onto peanut husk in aqueous solutions was investigated at 295 K. Experiments were carried out as function of pH, adsorbent dosage, contact time, and initial concentration. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, and Toth isotherm models. The results indicated that the Toth and Langmuir models provided the best correlation of the experimental data. The adsorption capacity of peanut husk for the removal of NR was deter...展开更多
Novel donor-acceptor-donor structured small molecular hole transporting materials are developed through a facile route by crosslinking dithienopyrrolobenzothiadiazole and phenothiazine or triarylamine-based donor unit...Novel donor-acceptor-donor structured small molecular hole transporting materials are developed through a facile route by crosslinking dithienopyrrolobenzothiadiazole and phenothiazine or triarylamine-based donor units. The strong push/pull electron capability of dithienopyrrolobenzothiadiazole/ phenothiazine and large π-conjugated dithienopyrrolobenzothiadiazole facilitate hole mobility and high conductivity. The devices using the dithienopyrrolobenzothiadiazole/phenothiazine-based hole trans-porting material achieved a power conversion efficiency of 14.2% under 1 sun illumination and improved stability under 20% relative humidity at room temperature without encapsulation. The present finding highlights the potential of dithienopyrrolobenzothiadiazole-based donor-acceptor-donor small molecular hole transporting materials for perovskite solar cells.展开更多
Inhomogeneous Pb/Sn elemental distribution and the resulted phase segregation in mixed Pb-Sn halide perovskites would result in energy disorder(band structure and phase distribution disorder),which greatly limits thei...Inhomogeneous Pb/Sn elemental distribution and the resulted phase segregation in mixed Pb-Sn halide perovskites would result in energy disorder(band structure and phase distribution disorder),which greatly limits their photovoltaic performance.Here,Pb S quantum dot has been synthesized and demonstrated as seeds for modulation crystallization dynamics of the mixed Pb-Sn inorganic perovskites,allowing an enhanced film quality and significantly suppressing phase segregation.With this additive power conversion efficiency of 8%and 6%is obtained under irradiation of full sunlight in planar and mesoporous structured solar cells in combination with CsPb_(0.5) Sn_(0.5)I_(2)Br inorganic perovskite,respectively.Our finding reveals exploring the actual Pb/Sn atoms location in perovskite structure and its influence on developing efficient and stable low-bandgap perovskite solar cells.展开更多
Here,we investigated the nonlinear optical(NLO)characteristics of carboxyl-functionalized graphene oxide(GO-COOH)in the near-infrared(NIR)region.The results revealed that GO-COOH samples exhibit strong saturable absor...Here,we investigated the nonlinear optical(NLO)characteristics of carboxyl-functionalized graphene oxide(GO-COOH)in the near-infrared(NIR)region.The results revealed that GO-COOH samples exhibit strong saturable absorption at low pump levels and a gradual transition to reverse saturable absorption(RSA)with increasing pump power.Then the saturable absorber(SA)by depositing the GO-COOH on the side-polished fiber(SPF)was employed in Yb-and Er-doped fiber lasers.Stable ultrashort pulses operating in the dissipative soliton(DS)and conventional soliton(CS)regimes were obtained with pulse widths of 26.6 ps and 968 fs,respectively.Besides,the dissipative soliton resonance(DSR)phenomenon caused by the RSA of GO-COOH was also observed with increasing pump power.The high-stable DSR mode-locked pulses with the maximum pulse energy of 1.91 nJ and 0.74 nJ were obtained in YDFL and EDFL respectively.These results not only reveal the potentiality of GO-COOH in ultrafast photonics applications but also open a new avenue to explore high-pulse-energy laser sources based on twodimensional materials.展开更多
基金the China PostdoctoralScience Foundation (No. 20070420811)the Edu-cation Department of Henan Province in China (No.200510459016)
文摘Adsorption of Neutral Red (NR) onto peanut husk in aqueous solutions was investigated at 295 K. Experiments were carried out as function of pH, adsorbent dosage, contact time, and initial concentration. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, and Toth isotherm models. The results indicated that the Toth and Langmuir models provided the best correlation of the experimental data. The adsorption capacity of peanut husk for the removal of NR was deter...
基金Financial support from the 973 Program of China(No.2014CB643506)the NSFC Major International(Regional)Joint Research Project NSFC-SNSF(51661135023)+2 种基金NSFC(21673091,21702147)the Fundamental Research Funds For the Central Universities HUST(2018KFYXKJC034)the Opening Project of Zhejiang Provincial Top Key Discipline of Pharmaceutical Sciences
文摘Novel donor-acceptor-donor structured small molecular hole transporting materials are developed through a facile route by crosslinking dithienopyrrolobenzothiadiazole and phenothiazine or triarylamine-based donor units. The strong push/pull electron capability of dithienopyrrolobenzothiadiazole/ phenothiazine and large π-conjugated dithienopyrrolobenzothiadiazole facilitate hole mobility and high conductivity. The devices using the dithienopyrrolobenzothiadiazole/phenothiazine-based hole trans-porting material achieved a power conversion efficiency of 14.2% under 1 sun illumination and improved stability under 20% relative humidity at room temperature without encapsulation. The present finding highlights the potential of dithienopyrrolobenzothiadiazole-based donor-acceptor-donor small molecular hole transporting materials for perovskite solar cells.
基金Financial support from the National Key Research and Development Program of China (2019YFE0101300, 2018YFB1502900)the National Natural Science Foundation of China (No. 21975088)+1 种基金the National Natural Science Foundation of China Major International (Regional) Joint Research Project (No. 51961165106)the double first-class research funding of China-EU Institute for Clean and Renewable Energy (3011187029)。
文摘Inhomogeneous Pb/Sn elemental distribution and the resulted phase segregation in mixed Pb-Sn halide perovskites would result in energy disorder(band structure and phase distribution disorder),which greatly limits their photovoltaic performance.Here,Pb S quantum dot has been synthesized and demonstrated as seeds for modulation crystallization dynamics of the mixed Pb-Sn inorganic perovskites,allowing an enhanced film quality and significantly suppressing phase segregation.With this additive power conversion efficiency of 8%and 6%is obtained under irradiation of full sunlight in planar and mesoporous structured solar cells in combination with CsPb_(0.5) Sn_(0.5)I_(2)Br inorganic perovskite,respectively.Our finding reveals exploring the actual Pb/Sn atoms location in perovskite structure and its influence on developing efficient and stable low-bandgap perovskite solar cells.
基金the National Natural Science Foundation of China(12174223,12274263,12004213,21872084,52072351,62175128)the Natural Science Foundation of Shandong Province(ZR2022QF063)+2 种基金the China Postdoctoral Science Foundation(2022M711936)the Postdoctoral Innovation Project of Shandong Province(Grant No.SDCX-ZG-202201006)the Qingdao Postdoctoral Application Research Funded Project.H.Chu and Z.Pan thank Shandong University for financial support.
文摘Here,we investigated the nonlinear optical(NLO)characteristics of carboxyl-functionalized graphene oxide(GO-COOH)in the near-infrared(NIR)region.The results revealed that GO-COOH samples exhibit strong saturable absorption at low pump levels and a gradual transition to reverse saturable absorption(RSA)with increasing pump power.Then the saturable absorber(SA)by depositing the GO-COOH on the side-polished fiber(SPF)was employed in Yb-and Er-doped fiber lasers.Stable ultrashort pulses operating in the dissipative soliton(DS)and conventional soliton(CS)regimes were obtained with pulse widths of 26.6 ps and 968 fs,respectively.Besides,the dissipative soliton resonance(DSR)phenomenon caused by the RSA of GO-COOH was also observed with increasing pump power.The high-stable DSR mode-locked pulses with the maximum pulse energy of 1.91 nJ and 0.74 nJ were obtained in YDFL and EDFL respectively.These results not only reveal the potentiality of GO-COOH in ultrafast photonics applications but also open a new avenue to explore high-pulse-energy laser sources based on twodimensional materials.
