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VOCs治理工程安全评价体系研究与构建 被引量:6
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作者 杨忠霖 解强 +1 位作者 郝郑平 周红阳 《洁净煤技术》 CAS 北大核心 2022年第2期77-85,共9页
近年来我国VOCs治理工程事故频发,根本原因在于VOCs治理项目设计、建设和运行中缺乏系统科学的安全理论、方法和工具的指导。剖析了VOCs治理工程的本质,概述了化工安全评价的理论、方法和常用工具,对比分析了VOCs治理工程项目与化工项... 近年来我国VOCs治理工程事故频发,根本原因在于VOCs治理项目设计、建设和运行中缺乏系统科学的安全理论、方法和工具的指导。剖析了VOCs治理工程的本质,概述了化工安全评价的理论、方法和常用工具,对比分析了VOCs治理工程项目与化工项目的异同。在此基础上结合VOCs治理工程特点选取并修正了化工安全评价方法,确定了信息共享模式,初步构建出集安全检查表、HAZOP、风险矩阵、LOPA、FTA和冲击波超压计算于一体的VOCs治理工程安全评价体系。HAZOP分析得到的初始事件频率和后果严重程度可作为风险矩阵分析的数据来源,风险矩阵对事故风险等级的判断可筛选出较严重的事故,以便进一步开展LOPA分析,HAZOP识别出的初始事件还可以为FTA分析提供原因事件。该体系对VOCs治理工程具有针对性,能够扬长避短、将多种方法紧密结合,实现评价方法之间数据的有效共享,评价过程系统、高效、有层次。 展开更多
关键词 挥发性有机物(VOCs) 治理工程 安全评价体系 风险矩阵
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Long-term monitoring and source apportionment of PM_(2.5)/PM_(10) in Beijing,China 被引量:65
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作者 WANG Hailin ZHUANG Yahui +4 位作者 WANG Ying SUN Yele YUAN Hui ZHUANG Guoshun hao zhengping 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2008年第11期1323-1327,共5页
During 2001-2006,PM2.5 (particle matter with aerodynamic diameter less than 2.5 microns) and PM10 (particle matter with aerodynamic diameter less than 10 microns) were collected at the Beijng Normal University (BNU) s... During 2001-2006,PM2.5 (particle matter with aerodynamic diameter less than 2.5 microns) and PM10 (particle matter with aerodynamic diameter less than 10 microns) were collected at the Beijng Normal University (BNU) site,China,and in 2006,at a background site in Duolun (DL).The long-term monitoring data of elements,ions,and black carbon showed that the major constituents of PM2.5 were black carbon (BC) crustal elements,nitrates,ammonium salts,and sulfates.These five major components accounted for 20%-80% of... 展开更多
关键词 PM2.5 PM10 MONITORING source apportionment
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LaFe_(x)Al_(12)-xO_(19)六铝酸盐催化剂上氨分解制氢性能
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作者 赵雅绪 张凤莲 +4 位作者 段潇潇 蒋国霞 徐欣 郝郑平 周华荣 《环境化学》 CAS CSCD 北大核心 2022年第7期2170-2179,共10页
采用并流共沉淀法制备了系列Fe取代的LaFe_(x)Al_(12-x)O_(19)(LaFex,其中x=0,2,4,6,8)六铝酸盐催化剂,分别考察了Fe取代量、反应温度、空速对NH_(3)分解反应活性的影响。研究结果表明,升高温度有利于提高NH_(3)的转化率;NH_(3)分解反... 采用并流共沉淀法制备了系列Fe取代的LaFe_(x)Al_(12-x)O_(19)(LaFex,其中x=0,2,4,6,8)六铝酸盐催化剂,分别考察了Fe取代量、反应温度、空速对NH_(3)分解反应活性的影响。研究结果表明,升高温度有利于提高NH_(3)的转化率;NH_(3)分解反应活性随着Fe取代量的增加先增加后降低,其中LaFe_(4)具有最佳的催化性能,在550℃即可实现NH_(3)的完全转化,并能稳定运行50 h以上。采用X射线衍射仪(XRD)、氮气吸脱附(BET)、程序升温还原(TPR)和X射线光电子能谱(XPS)等技术手段对催化剂进行了表征,结果表明,氨分解活性应该与反应温度、催化剂的氧化还原性能以及催化剂中八面体配位的Fe^(3+)的数量密切相关。 展开更多
关键词 氨分解 制氢 Fe取代六铝酸盐 催化性能 活性相
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Characterization and assessment of volatile organic compounds (VOCs) emissions from typical industries 被引量:62
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作者 WANG HaiLin NIE Lie +4 位作者 LI Jing WANG YuFei WANG Gang WANG JunHui hao zhengping 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第3期724-730,共7页
VOCs play an increasingly important role in affecting air quality and threatening human health in China in recent years,where industry activities show a significant contribution to VOCs emission.In this article we rep... VOCs play an increasingly important role in affecting air quality and threatening human health in China in recent years,where industry activities show a significant contribution to VOCs emission.In this article we report our long term study of industrial VOCs emissions of six major industries (vehicle manufacturing,printing,equipment coating,electronic manufacturing,furniture manufacturing and bio-pharming) on the aspects of emission characteristics,environmental impact and health risk assessment,and control challenge analysis with the purpose to obtain in-depth understanding of industry VOCs emissions and offer some original basements for national control and management of industry VOCs emissions.This study shows that all these industries give middle or low emission with total VOCs concentration less than 1000 mg/m3 at each exhaust pipe.Benzenes,esters,alcohols,ketones,alkanes,chloroalkanes and alkenes were detected as the major emission components and the most frequently monitored VOCs were benzenes,which varied obviously with different processes and industries.The environmental impact assessments indicate that vehicle manufacturing and benzenes should be prior controlled with the purpose to reduce air pollution.While,health risk assessments suggest that furniture manufacturing and chloroalkanes should be firstly controlled.Control analysis indicates that developing technologies with low cost and high efficiency and establishing and completing specific industry emission standards/regulations are the two key issues in VOCs emission management at present stage. 展开更多
关键词 VOCS typical industries emission characteristics ASSESSMENT control analysis
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Source apportionment for urban PM_(10) and PM_(2.5) in the Beijing area 被引量:22
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作者 ZHANG Wei GUO JingHua +4 位作者 SUN YeLe YUAN Hui ZHUANG GuoShun ZHUANG YaHui hao zhengping 《Chinese Science Bulletin》 SCIE EI CAS 2007年第5期608-615,共8页
Airborne particulate matter (PM2.5 and PM10) samples were collected at the Beijing Normal University sampling site in the urban area of Beijing, China in dry and wet seasons during 2001―2004. Concen-trations of 23 el... Airborne particulate matter (PM2.5 and PM10) samples were collected at the Beijing Normal University sampling site in the urban area of Beijing, China in dry and wet seasons during 2001―2004. Concen-trations of 23 elements and 14 ions in particulate samples were determined by ICP-AES and IC, re-spectively. Source apportionment results derived from both Positive Matrix Factorization (PMF) and Chemical Mass Balance (CMB) models indicate that the major contributors of PM2.5 and PM10 in Beijing are: soil dust, fossil fuel combustion, vehicle exhausts, secondary particulate, biomass burning and some industrial sources. We have identified both regional common sources, such as vehicular emis-sions, particulate of secondary origin and biomass burning, as well as country-specific problems, such as sand storms and soil dust that should be addressed for effective air quality control. 展开更多
关键词 北京地区 城区 空气颗粒物 PM10 PM2.5 污染源
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