Gold nanoparticles (GNs) are prepared through in situ reduction using NaBH4 in the presence of homopolymer PDMAEMA. The sizes of the GNs can be adjusted by alternating the molar ratio of gold to DMAEMA. Pure PDMAEMA a...Gold nanoparticles (GNs) are prepared through in situ reduction using NaBH4 in the presence of homopolymer PDMAEMA. The sizes of the GNs can be adjusted by alternating the molar ratio of gold to DMAEMA. Pure PDMAEMA aqueous solution shows a phase-transition at 50°C at pH 10 and 25°C at pH 14, while PDMAEMA-supported GNs aqueous solution shows a phase-transition at 47°C at pH 10 because of the increasing hydrophobic property resulting from GNs. Due to the pH and temperature-responsible characteristics of PDMAEMA, the resulting PDMAEMA-supported GNs exhibit pH adjustable temperature-responsive characteristics in optic and catalytic aspects. Under an acidic condition (pH 2), the GNs show unchanged surface Plasmon absorbance with a peak of 518 nm in a temperature range from 20 to 65°C. Under a basic condition (pH 10), the GNs first show the same absorbance with a peak at 518 nm in a temperature range from 20 to 40°C, and then the absorbance red shifts from 518 to 545 nm as temperature increases from 40 to 65°C. When the GNs are used as catalysts to catalyze the reduction of p-nitrophenol, the catalytic activity can be adjusted by changing the permeation of reactants in the PDMAEMA layer at low and high temperatures, respectively.展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 20774051)Program for New Century Excellent Talents in Universitiesthe Outstanding Youth Fund (Grant No. 50625310)
文摘Gold nanoparticles (GNs) are prepared through in situ reduction using NaBH4 in the presence of homopolymer PDMAEMA. The sizes of the GNs can be adjusted by alternating the molar ratio of gold to DMAEMA. Pure PDMAEMA aqueous solution shows a phase-transition at 50°C at pH 10 and 25°C at pH 14, while PDMAEMA-supported GNs aqueous solution shows a phase-transition at 47°C at pH 10 because of the increasing hydrophobic property resulting from GNs. Due to the pH and temperature-responsible characteristics of PDMAEMA, the resulting PDMAEMA-supported GNs exhibit pH adjustable temperature-responsive characteristics in optic and catalytic aspects. Under an acidic condition (pH 2), the GNs show unchanged surface Plasmon absorbance with a peak of 518 nm in a temperature range from 20 to 65°C. Under a basic condition (pH 10), the GNs first show the same absorbance with a peak at 518 nm in a temperature range from 20 to 40°C, and then the absorbance red shifts from 518 to 545 nm as temperature increases from 40 to 65°C. When the GNs are used as catalysts to catalyze the reduction of p-nitrophenol, the catalytic activity can be adjusted by changing the permeation of reactants in the PDMAEMA layer at low and high temperatures, respectively.
