The behaviour of baron segregation at grain boundaries in Fe-3% Si has been studied by means of particle tracking autoradiography(PTA).The results indicate that the tendency of equilibrium segregation of B at grain bo...The behaviour of baron segregation at grain boundaries in Fe-3% Si has been studied by means of particle tracking autoradiography(PTA).The results indicate that the tendency of equilibrium segregation of B at grain boundaries in Fe-3% Si is higher than that in austenitic alloys.No observable nonequilibrium segregation of B at grain boundaries was revealed in Fe-3% Si alloy during cooling and isothermal holding.The binding energy between boron at- oms and grain boundaries is 55.7±1.7 kJ/mol.Based on the complex mechanism of B segre- gation of quenching-induce-nonequilibrium segregation,different behaviours of B segrega- tion in γ-Fe and bcc Fe-3% Si alloy were discussed.展开更多
The characteristics of inclusions in two types of low-carbon steels by different deoxidization methods have been investigated by using the welding thermal simulation,the optical microscopy and scanning electron micros...The characteristics of inclusions in two types of low-carbon steels by different deoxidization methods have been investigated by using the welding thermal simulation,the optical microscopy and scanning electron microscopy.In addition,the effects of inclusions on microstructure and properties of heat-affected-zone were studied.The nucleation and growth of intragranular acicular ferrite was observed in situ by the laser scanning confocal microscopy.The distribution of Mn element near the inclusion was also analyzed by the auger electron spectroscopy.The results showed that the inclusions in Al killed steel are mainly aluminum oxides,manganese sulfide and titanium nitrides,and that the inclusions in Ti killed steel are mainly titanium oxide,manganese sulfide complex inclusion and single manganese sulfide.The auger electron spectroscopy showed that there is an Mn-depleted zone near the interface of TiO x /MnS complex inclusion in the size of 1-3 m.It could be the effective nucleus of intragranular acicular ferrite which could divide the prior austenite grains,inhibit the growth of low-temperature microstruc-ture,and refine the final microstructure,so as to improve the toughness of heat-affected-zone significantly.展开更多
文摘The behaviour of baron segregation at grain boundaries in Fe-3% Si has been studied by means of particle tracking autoradiography(PTA).The results indicate that the tendency of equilibrium segregation of B at grain boundaries in Fe-3% Si is higher than that in austenitic alloys.No observable nonequilibrium segregation of B at grain boundaries was revealed in Fe-3% Si alloy during cooling and isothermal holding.The binding energy between boron at- oms and grain boundaries is 55.7±1.7 kJ/mol.Based on the complex mechanism of B segre- gation of quenching-induce-nonequilibrium segregation,different behaviours of B segrega- tion in γ-Fe and bcc Fe-3% Si alloy were discussed.
基金supported by the National Basic Research Program of China ("973" Program) (Grant No. 2010CB630801)
文摘The characteristics of inclusions in two types of low-carbon steels by different deoxidization methods have been investigated by using the welding thermal simulation,the optical microscopy and scanning electron microscopy.In addition,the effects of inclusions on microstructure and properties of heat-affected-zone were studied.The nucleation and growth of intragranular acicular ferrite was observed in situ by the laser scanning confocal microscopy.The distribution of Mn element near the inclusion was also analyzed by the auger electron spectroscopy.The results showed that the inclusions in Al killed steel are mainly aluminum oxides,manganese sulfide and titanium nitrides,and that the inclusions in Ti killed steel are mainly titanium oxide,manganese sulfide complex inclusion and single manganese sulfide.The auger electron spectroscopy showed that there is an Mn-depleted zone near the interface of TiO x /MnS complex inclusion in the size of 1-3 m.It could be the effective nucleus of intragranular acicular ferrite which could divide the prior austenite grains,inhibit the growth of low-temperature microstruc-ture,and refine the final microstructure,so as to improve the toughness of heat-affected-zone significantly.
