A novel three-component copolymer (PFDP),derived from 9,9-dihexylfluorene,diketopyrrolopyrrole(DPP),and 10-octylphenothiazine,was synthesized through palladium-catalyzed Suzuki polycondensation in good yields. PFDP po...A novel three-component copolymer (PFDP),derived from 9,9-dihexylfluorene,diketopyrrolopyrrole(DPP),and 10-octylphenothiazine,was synthesized through palladium-catalyzed Suzuki polycondensation in good yields. PFDP possessed moderate molecular weight and polydispersity,well-defined structure,and excellent thermal properties with an onset decomposition temperature at 357℃. PFDP in thin film exhibited red photoluminescence from DPP chromophore exclusively,with a peak at 602 nm. Electron-rich phenothiazine units sighificantly improved the injection and transport of holes by incorporating into polymer backbone. Light-emitting device was fabricated in the ITO/PEDOT:PSS/PVK/ polymer/Ba/Al configuration using PFDP as the emitting layer. The device based on PFDP showed red emission [CIE coordinate value (0.62,0.38)] that was close to the standard red (0.66,0.34). The results on electroluminescent performance revealed that PFDP may be a promising candidate for the red emitter with a maximum brightness of 259 cd/m2 and a maximum external quantum efficiency of 0.25%.展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 20872038)Science and Technology Planning Project of Guangdong Province, China (Grant No. 2007A010500011)Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20060561024)
文摘A novel three-component copolymer (PFDP),derived from 9,9-dihexylfluorene,diketopyrrolopyrrole(DPP),and 10-octylphenothiazine,was synthesized through palladium-catalyzed Suzuki polycondensation in good yields. PFDP possessed moderate molecular weight and polydispersity,well-defined structure,and excellent thermal properties with an onset decomposition temperature at 357℃. PFDP in thin film exhibited red photoluminescence from DPP chromophore exclusively,with a peak at 602 nm. Electron-rich phenothiazine units sighificantly improved the injection and transport of holes by incorporating into polymer backbone. Light-emitting device was fabricated in the ITO/PEDOT:PSS/PVK/ polymer/Ba/Al configuration using PFDP as the emitting layer. The device based on PFDP showed red emission [CIE coordinate value (0.62,0.38)] that was close to the standard red (0.66,0.34). The results on electroluminescent performance revealed that PFDP may be a promising candidate for the red emitter with a maximum brightness of 259 cd/m2 and a maximum external quantum efficiency of 0.25%.
