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海藻酸钠对鸟粪石结晶的影响及机理研究 被引量:10
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作者 韦林 洪天求 +2 位作者 李如忠 张强 陈天虎 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2017年第8期2941-2946,共6页
鸟粪石结晶沉淀法回收剩余污泥中磷工艺具有良好应用前景,然而污泥中的一些有机物,特别是胞外聚合物(EPS)将对鸟粪石结晶产生一定的影响.海藻酸钠(SA)在物化性质上接近于EPS,为较深入地探究此影响机理,以SA作为EPS的代用化合物采用恒组... 鸟粪石结晶沉淀法回收剩余污泥中磷工艺具有良好应用前景,然而污泥中的一些有机物,特别是胞外聚合物(EPS)将对鸟粪石结晶产生一定的影响.海藻酸钠(SA)在物化性质上接近于EPS,为较深入地探究此影响机理,以SA作为EPS的代用化合物采用恒组分、恒p H实验来考察EPS对鸟粪石结晶的影响,并借助红外光谱(FTIR)和X射线光电子能谱(XPS)分析来探讨SA与鸟粪石晶体之间的作用机理.结果表明,在SA浓度0~250mg/L范围内,随其浓度的增大鸟粪石结晶生长速率降低,鸟粪石晶体的尺寸有所减小,其原因是海藻酸阴离子吸附并掩蔽鸟粪石表面生长活性点上阻碍晶体生长.这种吸附作用是由鸟粪石表面Mg2+、磷酸羟基团(POH)分别与SA中COOH、C=O、COC键合共同引起的,而鸟粪石表面的NH_4^+并未参与反应. 展开更多
关键词 鸟粪石 海藻酸钠 恒组分实验 晶体生长
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FUZZY MODEL FOR TWO-DIMENSIONAL RIVER WATER QUALITY SIMULATION UNDER SUDDEN POLLUTANTS DISCHARGED 被引量:11
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作者 LI Ru-zhong SHIGEKI Masunaga +1 位作者 hong tian-qiu QIAN Jia-zhong 《Journal of Hydrodynamics》 SCIE EI CSCD 2007年第4期434-441,共8页
Based on the fuzziness and impreciseness of water environmental system, the fuzzy arithmetic was used to simulate the fuzzy and imprecise relations in modeling river water quality. By defining the parameters of water ... Based on the fuzziness and impreciseness of water environmental system, the fuzzy arithmetic was used to simulate the fuzzy and imprecise relations in modeling river water quality. By defining the parameters of water quality model as symmetrical triangular fuzzy numbers, a two-dimensional fuzzy water quality model for sudden pollutant discharge is established. From the fuzzy model, the pollutant concentrations, corresponding to the specified confidence level of a, can be obtained by means of the a-cut technique and arithmetic operations of triangular fuzzy numbers. Study results reveal that it is feasible in theory and reliable on calculation applying triangular fuzzy numbers to the simulation of river water quality. 展开更多
关键词 fuzzy water quality simulation model triangular fuzzy number membership function a-cut technique
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