It was found that micro amounts of oxalate showed a very strong catalytic effect on the slow reaction between K 2Cr 2O 7 and Orange Ⅳ in a diluted sulfuric acid medium in a water bath at 70 ℃ . Orange Ⅳ exhib...It was found that micro amounts of oxalate showed a very strong catalytic effect on the slow reaction between K 2Cr 2O 7 and Orange Ⅳ in a diluted sulfuric acid medium in a water bath at 70 ℃ . Orange Ⅳ exhibited a sensitive second order derivative polarographic wave at -0 50 V( vs . SCE). This provides the basis for a sensitive and selective catalytic kinetic method for oxalate determination with second order derivative oscillopolarography. The effects of sulphuric acid, K 2Cr 2O 7, and orange Ⅳ concentrations, reaction temperature and reaction time were investigated. A calibration curve of oxalate in the range of 0 1-2 0 μg/mL was obtained by the fixed time procedure. The detection limit was 0 03 μg/ mL. The possible interference from co existing substances or ions was examined. The new method has a high sensitivity and a good selectivity compared to other existing methods for oxalic acid determination. It has been applied to the determination of micro amounts of oxalate in real urine samples with satisfactory results.展开更多
临界安全作为乏燃料组件运输容器的一项重要安全指标,需经过计算和分析以判断其是否满足法规标准。为分析中国核工业集团有限公司(China National Nuclear Corporation,CNSC)乏燃料组件运输容器临界安全设计是否满足《放射性物品安全运...临界安全作为乏燃料组件运输容器的一项重要安全指标,需经过计算和分析以判断其是否满足法规标准。为分析中国核工业集团有限公司(China National Nuclear Corporation,CNSC)乏燃料组件运输容器临界安全设计是否满足《放射性物品安全运输规程》的要求,使用蒙特卡罗程序MCNP(Monte Carlo N Particle Transport Code)构建了保守临界计算模型,对正常和事故工况下CNSC乏燃料组件运输容器进行了临界计算分析。分析表明:正常运输条件下单个货包和货包阵列的keff最大值为0.804 25,小于次临界限值,临界安全指数为0;事故工况下单个货包和货包阵列的keff最大值为0.813 17,小于次临界限值,临界安全指数为0。可见,正常和事故工况下,CNSC乏燃料组件运输容器的keff最大值均小于0.94的次临界限值,临界安全指数为0,满足法规标准要求。展开更多
文摘It was found that micro amounts of oxalate showed a very strong catalytic effect on the slow reaction between K 2Cr 2O 7 and Orange Ⅳ in a diluted sulfuric acid medium in a water bath at 70 ℃ . Orange Ⅳ exhibited a sensitive second order derivative polarographic wave at -0 50 V( vs . SCE). This provides the basis for a sensitive and selective catalytic kinetic method for oxalate determination with second order derivative oscillopolarography. The effects of sulphuric acid, K 2Cr 2O 7, and orange Ⅳ concentrations, reaction temperature and reaction time were investigated. A calibration curve of oxalate in the range of 0 1-2 0 μg/mL was obtained by the fixed time procedure. The detection limit was 0 03 μg/ mL. The possible interference from co existing substances or ions was examined. The new method has a high sensitivity and a good selectivity compared to other existing methods for oxalic acid determination. It has been applied to the determination of micro amounts of oxalate in real urine samples with satisfactory results.
文摘临界安全作为乏燃料组件运输容器的一项重要安全指标,需经过计算和分析以判断其是否满足法规标准。为分析中国核工业集团有限公司(China National Nuclear Corporation,CNSC)乏燃料组件运输容器临界安全设计是否满足《放射性物品安全运输规程》的要求,使用蒙特卡罗程序MCNP(Monte Carlo N Particle Transport Code)构建了保守临界计算模型,对正常和事故工况下CNSC乏燃料组件运输容器进行了临界计算分析。分析表明:正常运输条件下单个货包和货包阵列的keff最大值为0.804 25,小于次临界限值,临界安全指数为0;事故工况下单个货包和货包阵列的keff最大值为0.813 17,小于次临界限值,临界安全指数为0。可见,正常和事故工况下,CNSC乏燃料组件运输容器的keff最大值均小于0.94的次临界限值,临界安全指数为0,满足法规标准要求。
