不同试验条件下沉积在EGR(exhaust gas recirculation)冷却器换热管内表面的颗粒物会形成不同表面微观结构的沉积层。为了量化分析沉积处表面微观结构的分布特征和三维表面的起伏特征,提出采用沉积层表面结构特征面积占比和表面分形盒...不同试验条件下沉积在EGR(exhaust gas recirculation)冷却器换热管内表面的颗粒物会形成不同表面微观结构的沉积层。为了量化分析沉积处表面微观结构的分布特征和三维表面的起伏特征,提出采用沉积层表面结构特征面积占比和表面分形盒维数两个参数分析沉积层的表面微观结构变化规律,并利用其分析碳氢化合物(HC,hydrocarbons)浓度对沉积层表面微观结构的影响。结果表明:试验气体中的HC等挥发性物质的析出会影响EGR气体中颗粒物的尺寸,改变沉积层表面凹坑和凸起结构的数量和尺寸分布;随着HC浓度的增加,沉积层表面凸起结构所占的面积百分比逐渐增加,凹坑结构所占面积百分比变化较小;用于表征沉积层表面起伏程度的沉积层表面分形盒维数随试验气体中HC浓度的增加而逐渐增加。展开更多
We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experime...We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.展开更多
Hydroxyl terminated polybutadiene（HTPB） based polyurethane（PU）-polystyrene（PS） interpenetrating polymer network（IPN） was prepared and characterized by FTIR, TGA, WCA, swelling experiments, and SEM. The IPN was...Hydroxyl terminated polybutadiene（HTPB） based polyurethane（PU）-polystyrene（PS） interpenetrating polymer network（IPN） was prepared and characterized by FTIR, TGA, WCA, swelling experiments, and SEM. The IPN was used for pervaporation（PV） recovery of butanol. Both the permeation flux and separation factor increased with feed temperature, and both water and butanol fluxes increased with feed concentration while no obvious effect of concentration on separation factor was found. Through the formation of IPN structure, the total flux of HTPB based PU increased greatly with the decrease of separation factor. At the feed temperature of 60 °C, the IPN membrane obtained a total flux of 613.3 g/m^2 h with a separation factor of 6.15.展开更多
The present study aimed to improve the pervaporation（PV） performances of polydimethylsiloxane（PDMS） membranes by using special cross-linkers. The γ-methacryloxypropyl trimethoxy silane（KH-570） cross-linked PDMS...The present study aimed to improve the pervaporation（PV） performances of polydimethylsiloxane（PDMS） membranes by using special cross-linkers. The γ-methacryloxypropyl trimethoxy silane（KH-570） cross-linked PDMS membranes were fabricated and characterized by FTIR, TGA, WCA, DSC, SEM, and swelling properties. Experimental results showed that the separation factor of the membrane increased slightly with the feed temperature whereas permeate flux increased. Butanol flux increased slowly with the feed concentration while the water flux decreased. The overall result indicated that the separation factor decreased slowly with the feed concentration. The membrane, with a thickness of 55 μm, showed a total flux of 308.4 g/m^2h with a separation factor of 26.8 at 70 ℃, and butanol permeability reached 11.13×10~5 Barrer with a membrane selectivity of 56.0.展开更多
文摘不同试验条件下沉积在EGR(exhaust gas recirculation)冷却器换热管内表面的颗粒物会形成不同表面微观结构的沉积层。为了量化分析沉积处表面微观结构的分布特征和三维表面的起伏特征,提出采用沉积层表面结构特征面积占比和表面分形盒维数两个参数分析沉积层的表面微观结构变化规律,并利用其分析碳氢化合物(HC,hydrocarbons)浓度对沉积层表面微观结构的影响。结果表明:试验气体中的HC等挥发性物质的析出会影响EGR气体中颗粒物的尺寸,改变沉积层表面凹坑和凸起结构的数量和尺寸分布;随着HC浓度的增加,沉积层表面凸起结构所占的面积百分比逐渐增加,凹坑结构所占面积百分比变化较小;用于表征沉积层表面起伏程度的沉积层表面分形盒维数随试验气体中HC浓度的增加而逐渐增加。
基金the Core Research Facilities of College of Chemistry and Molecular Sciences and Wuhan University Test Center and Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Special Fund for Industrial and informatization Industry Foundation Reconstruction and High Quality Development of Manufacturing Industry(No.TC220H068)。
文摘We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.
基金Funded by the Innovation Foundation from China Southern Power Grid(GDKJQQ20152050)
文摘Hydroxyl terminated polybutadiene（HTPB） based polyurethane（PU）-polystyrene（PS） interpenetrating polymer network（IPN） was prepared and characterized by FTIR, TGA, WCA, swelling experiments, and SEM. The IPN was used for pervaporation（PV） recovery of butanol. Both the permeation flux and separation factor increased with feed temperature, and both water and butanol fluxes increased with feed concentration while no obvious effect of concentration on separation factor was found. Through the formation of IPN structure, the total flux of HTPB based PU increased greatly with the decrease of separation factor. At the feed temperature of 60 °C, the IPN membrane obtained a total flux of 613.3 g/m^2 h with a separation factor of 6.15.
基金Funded by the Innovation Foundation from China Southern Power Grid(GDKJQQ20152050)
文摘The present study aimed to improve the pervaporation（PV） performances of polydimethylsiloxane（PDMS） membranes by using special cross-linkers. The γ-methacryloxypropyl trimethoxy silane（KH-570） cross-linked PDMS membranes were fabricated and characterized by FTIR, TGA, WCA, DSC, SEM, and swelling properties. Experimental results showed that the separation factor of the membrane increased slightly with the feed temperature whereas permeate flux increased. Butanol flux increased slowly with the feed concentration while the water flux decreased. The overall result indicated that the separation factor decreased slowly with the feed concentration. The membrane, with a thickness of 55 μm, showed a total flux of 308.4 g/m^2h with a separation factor of 26.8 at 70 ℃, and butanol permeability reached 11.13×10~5 Barrer with a membrane selectivity of 56.0.
