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华北克拉通恒山地区晚太古代变质火山岩的地球化学特征及构造意义
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作者 高山松 李秋根 +2 位作者 胡鹏月 Yasin Rahim 李泓莹 《北京大学学报(自然科学版)》 EI CAS CSCD 北大核心 2023年第1期143-160,共18页
对恒山地区出露的变质火山岩开展岩相学、地球化学、锆石U-Pb年代学和Hf同位素研究,旨在确定其形成时代,探讨岩石成因及地球动力学意义。锆石U-Pb定年结果表明,这些变质火山岩喷发于新太古代晚期(2508±20 Ma)。地球化学分析结果显... 对恒山地区出露的变质火山岩开展岩相学、地球化学、锆石U-Pb年代学和Hf同位素研究,旨在确定其形成时代,探讨岩石成因及地球动力学意义。锆石U-Pb定年结果表明,这些变质火山岩喷发于新太古代晚期(2508±20 Ma)。地球化学分析结果显示,恒山变质火山岩由变质玄武岩和变质玄武安山岩组成,SiO_(2)(45.51%~62.67%)、FeO_(T)(4.43%~15.72%)和MgO(3.75%~8.14%)含量变化幅度大,是幔源岩浆经单斜辉石、角闪石和磁铁矿分离结晶的产物。这些变质火山岩富集轻稀土(LREE)和大离子亲石元素(LILE),亏损重稀土(HREE)和高场强元素(HFSE),具有相对高的Th含量和Th/Yb比值,呈现钙碱性岛弧火山岩的特征。结合不相容元素比值Nb/Yb,Zr/Yb和(Nb/La)_(N)的特点,推测其来源于俯冲带具流体交代特征的富集地幔源区。结合区域构造背景,推断恒山变质火山岩形成于新太古晚期大陆弧环境。 展开更多
关键词 恒山地区 新太古代晚期 变质火山岩 地球化学 大陆弧
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在富集氯离子环境中钢丝绳吊索结构的腐蚀性能分析 被引量:1
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作者 宁永刚 胡鹏越 +1 位作者 王帅 李胜利 《公路工程》 北大核心 2018年第4期110-115,126,共7页
氯离子是海洋大气中的重要成分,往往会腐蚀钢丝绳吊索。采用与西堠门大桥直径为60 mm的吊索类似结构的钢丝绳,利用室内加速试验模拟海洋大气中氯离子对钢丝绳吊索的腐蚀环境,研究了不同浓度氯离子环境下钢丝绳的腐蚀,并利用SEM(扫描电... 氯离子是海洋大气中的重要成分,往往会腐蚀钢丝绳吊索。采用与西堠门大桥直径为60 mm的吊索类似结构的钢丝绳,利用室内加速试验模拟海洋大气中氯离子对钢丝绳吊索的腐蚀环境,研究了不同浓度氯离子环境下钢丝绳的腐蚀,并利用SEM(扫描电子显微镜)和XRD(X射线衍射)对腐蚀产物及形貌进行分析。结果表明:吊索结构钢丝绳在其它条件相同的情况下腐蚀速率随氯离子浓度的增加而增大,钢丝绳的腐蚀与其钢丝缠绕紧密程度密切相关,并且腐蚀产物积累分布不均匀,在钢丝缝隙处较多;吊索结构钢丝绳在条件相同的情况下腐蚀速率随时间的推移而减小;吊索结构钢丝绳与钢片腐蚀的微观物理结构有显著差异,即钢丝绳腐蚀无腐蚀裂缝而钢片腐蚀有腐蚀裂缝。 展开更多
关键词 氯离子 钢丝绳 吊索 室内试验 腐蚀
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软坚清脉颗粒质量标准研究
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作者 黄雨婷 胡鹏跃 +2 位作者 李国文 史秀峰 谢燕 《中国药业》 CAS 2022年第24期62-67,共6页
目的 建立软坚清脉颗粒的质量标准。方法 采用薄层色谱(TLC)法对制剂中垂盆草、蒲黄、豨莶草进行定性鉴别;采用高效液相色谱法测定垂盆草中3种成分及蒲黄中2种成分的含量,色谱柱为Kromasil C_(18)柱(250 mm×4.6 mm,5μm),流动相为... 目的 建立软坚清脉颗粒的质量标准。方法 采用薄层色谱(TLC)法对制剂中垂盆草、蒲黄、豨莶草进行定性鉴别;采用高效液相色谱法测定垂盆草中3种成分及蒲黄中2种成分的含量,色谱柱为Kromasil C_(18)柱(250 mm×4.6 mm,5μm),流动相为甲醇-0.1%磷酸水溶液(44∶56,V/V;垂盆草中3种成分)和乙腈-0.05%磷酸水溶液(14∶86,V/V;蒲黄中2种成分),流速为1.0 mL/min,检测波长为360 nm(垂盆草中3种成分)和254 nm(蒲黄中2种成分),柱温为30℃,进样量为10μL。结果 垂盆草、蒲黄、豨莶草的TLC图斑点清晰,分离度好,阴性对照无干扰。垂盆草中槲皮素、山柰素、异鼠李素和蒲黄中香蒲新苷、异鼠李素-3-O-新橙皮苷质量浓度分别在10.0-83.2μg/mL,2.0-16.0μg/mL,5.6-44.8μg/mL,4.1-41.2μg/mL,4.2-42.4μg/mL范围内与峰面积线性关系良好(r均大于0.999 2),定量限分别为9.40 ng,21.36 ng,21.08 ng,20.24 ng,20.48 ng,检测限分别为2.81 ng,6.42 ng,6.30 ng,6.88 ng,6.96 ng;精密度、稳定性、重复性试验结果的RSD均小于5.0%,平均加样回收率分别为97.52%,109.10%,107.25%,103.56%,103.84%,RSD分别为1.38%,1.24%,1.24%,3.58%,2.94%(n=6)。结论 所建标准可用于软坚清脉颗粒的质量控制。 展开更多
关键词 软坚清脉颗粒 槲皮素 山柰素 异鼠李素 香蒲新苷 异鼠李素-3-O-新橙皮苷 质量标准
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The Metamorphism and Its Tectonic Implications of Indosinian High Pressure Granulites from the Badu Complex of the Cathaysia Block, Southwestern Zhejiang Province, South China
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作者 ZHENG Changqing XU Xuechun +4 位作者 ZHOU Xiwen ZHOU Xiao GUO Tengda YANG Yan hu pengyue 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第S01期91-91,共1页
The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The... The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The degree of indosinian metamorphism reaches granulite facies. However, there is still insufficient understanding of the characteristics of the Indosinian granulite metamorphism in the Cathaysia and many interpretations of its tectonic significance. Therefore, we present detailed petrology, mineral chemistry and LA-ICP-MS zircon U-Pb age in this paper from pelitic granulites of the Badu Complex, which is composed of "sillimanite + garnet + cordierite + spinel + biotite + k-feldspar" assemblage and garnet pyroxenite with garnet amphibolite which is consists of "garnet + clinopyroxene + orthopyroxene + amphibole + plagioclase". By comprehensive study we get following new findings: Pelitic granulites record four stages of metamorphic mineral assemblages, including prograde(M1), pressure peak(M2), Peak(M3) and post-peak decompressional and then cooling(M4) stages. The prograde M1 assemblage consists of garnet1(core) + staurolite + kyanite + biotite + quartz ± rutile ± chlorite;The pressure peak M2 assemblage consists of garnet1(mantle) + sudoite + rutile + kyanite + corundum + biotite + quartz;The peak M3 have garnet2(rim-mantle) + biotite + sillimanite + quartz ± K-feldspar ± plagioclase ± ilmenite assemblag;the M4 stage is consist of garnet + cordierite + biotite + sillimanite + quartz + ilmenite ± spine ± K-feldspar. The garnet pyroxenite and garnet amphibolites have experienced three stages of metamorphic evolution. Peak high-pressure granulite facies stage M2 consists of garnet + sahlite ± ilmenite ± quartz;Post-peak near isothermal decompression medium granulite facies stage M3 is characterized by typical decompression reaction textures and assemblage of orthopyroxene + plagioclase(An=90–92);amphibolites facies retrograde metamorphic stage M4 is characterized by amphibole + plagioclase(An=33–35) + ilmenite ± sahlite ± quartz mineral assemblage. By means of phase equilibrium simulation and traditional thermobarometer, P-T conditions of 785–820 ℃ and 8.9–9.9 kbar for M3 stage, 780–860 ℃ and 5.7–6.2 kbar for decompressional M4 stage, 705–720 ℃ and 4.5–4.7 kbar for cooling M4 stage in pelitic granulites were obtained. And also 11.6–12.5 kbar and 780–840 ℃ for M2 stage, 7.4–8.2 kbar and 800–880 ℃ for M3 stage, 6.6–7.5 kbar and 500–560 ℃ for M4 stage were obtained in garnet pyroxenite and garnet amphibolite. A clockwise P-T path is confirmed in the two type rocks of the Badu Complex which reflected a near-isothermal decompressional metamorphic process. The peak metamorphism can reach highpressure granulite facies. In addition, the mineral assemblage of garnet + rutile + kyanite + corundum in the peak metamorphic stage of pelitic granulite indicates that it may underwent ultra-high-pressure metamorphism, and the acidic plagioclase exsolution of clinopyroxene in garnet pyroxenite also suggests that it may be retrograded eclogites, which indicates that the deeper Cathaysian block may have eclogite metamorphism. Analyses of LA-ICP-MS zircon U-Pb dating indicate that the metamorphic age of pelitic granulite is 233.5 Ma–subduction/collision followed by rapid exhumation and cooling events. The events may relate with the amalgamation of the Indochina BlockSouth China Block North China Block in the paleo-Tethyan domain. 展开更多
关键词 pelitic granulite garnet pyroxenite metamorphic evolution phase equilibrium INDOSINIAN Cathaysia block
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熟地黄、石菖蒲防治阿尔茨海默病作用机制研究进展 被引量:16
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作者 胡鹏跃 李国文 谢燕 《上海中医药大学学报》 CAS 2020年第6期99-104,共6页
熟地黄、石菖蒲分别是重要的补血药、开窍药,两者均具有防治阿尔茨海默病(AD)的药理作用,亦能根据辨证配伍使用,其防治AD的机制主要有:抗氧化、抗炎、神经保护、调节中枢神经递质等。对近年熟地黄、石菖蒲治疗AD的作用机制进行综述,为... 熟地黄、石菖蒲分别是重要的补血药、开窍药,两者均具有防治阿尔茨海默病(AD)的药理作用,亦能根据辨证配伍使用,其防治AD的机制主要有:抗氧化、抗炎、神经保护、调节中枢神经递质等。对近年熟地黄、石菖蒲治疗AD的作用机制进行综述,为进一步研究熟地黄、石菖蒲防治AD提供参考。 展开更多
关键词 熟地黄 石菖蒲 阿尔茨海默病 作用机制 综述
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