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亲锂电解液在LiNi_(0.6)Mn_(0.2)Co_(0.2)O_(2)/Li二次锂金属电池中的电化学性能 被引量:1
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作者 黄杜斌 王培民 邬金龙 《应用化学》 CAS CSCD 北大核心 2022年第2期298-306,共9页
金属锂电池被认为是具有良好前景的下一代高能量密度电池。然而,传统的碳酸酯类电解液与锂的亲和性差,在循环过程中由于锂枝晶的生长和固体电解质膜(SEI)的不稳定导致金属锂电池性能快速衰减。采用1.2 mol/L六氟磷酸锂(LiPF_(6))/二氟... 金属锂电池被认为是具有良好前景的下一代高能量密度电池。然而,传统的碳酸酯类电解液与锂的亲和性差,在循环过程中由于锂枝晶的生长和固体电解质膜(SEI)的不稳定导致金属锂电池性能快速衰减。采用1.2 mol/L六氟磷酸锂(LiPF_(6))/二氟草酸硼酸锂(LiDFOB)/氟代碳酸乙烯酯(FEC)/碳酸二乙酯(DEC),并添加了双三氟甲磺酰亚胺锂(LiTFSI)作为电解液,对其在LiNi_(0.6)Mn_(0.2)Co_(0.2)O_(2)/40μm-Li(单位面积上负/正极材料的实际容量的比N/P=2.85)电池中的电化学性能进行了研究。LiNi_(0.6)Mn_(0.2)Co_(0.2)O_(2)/40μm-Li电池表现出优异的循环稳定性(循环120圈后,容量保持率>93%)和倍率性能(3C倍率下放电比容量为110 mA·h/g)。良好的电化学性能主要归因于该电解液可以在金属锂表面形成致密且稳定的SEI,并抑制锂枝晶的产生。 展开更多
关键词 金属锂电池 双三氟甲磺酰亚胺锂 LiNi_(0.6)Mn_(0.2)Co_(0.2)O_(2) 薄锂
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Preparation of Carbon-coated Tourmaline and the Degradation of Methylene Blue
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作者 WANG Yuesong CHUAN Xiuyun +1 位作者 LI Lin huang du-bin 《矿物学报》 CAS CSCD 北大核心 2013年第S1期105-105,共1页
An attempt was made to prepare carbon coated tourmaline by mixing tourmaline powders and polyvinyl alcohol (PVA), followed by heat treatment in argon atmosphere. All samples were characterized by powder X-ray diffract... An attempt was made to prepare carbon coated tourmaline by mixing tourmaline powders and polyvinyl alcohol (PVA), followed by heat treatment in argon atmosphere. All samples were characterized by powder X-ray diffraction, high-resolution transmission electron microscopy, UV diffuse reflectance spectroscopy. Results showed that the residual carbon content was influenced by heat treatment temperature and the amount of PVA. The degradation of methylene blue by Carbon-coated tourmaline was also studied. The experiments pointed out that the carbon coated effects are best when the heating temperature was 900℃ and the weight content of PVA was 70%. And the tourmaline prepared under 900℃ in the oxidation atmosphere has the best degrade efficiency. The results also proved that the infrared radiation of tourmaline is not effect in the degrade progress. 展开更多
关键词 TOURMALINE carbon COATED METHYLENE BLUE DEGRADATION
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