广东省龙川县深孔碳酸地热水的水化学特征

碳酸泉以富含游离CO_(2)为特征,主要分布在深大断裂带和地震活动带上.通过针对广东省龙川县3个不同深度的钻孔数据对碳酸地热水的水文地球化学特征进行研究,揭示其水化学组分主要为碳酸盐矿物溶解控制,游离CO_(2)运移过程中强化了水的溶滤作用.Na-K-Mg三角图解和PHREEQC计算表明水-岩作用处于不平衡状态,通过石英温标、玉髓温标及多矿物水-岩平衡估算了地热水的热储温度为60—102℃,循环深度为1692—3548 m.该水化学特征成果可以进一步讨论碳酸泉的形成机理,反映气体在深部地热流和温度剖面中的作用,为研究深部流体对地震的同震响应及地热资源开发提供依据.

Geochemistry of rare-earth elements in shallow groundwater, northeastern Guangdong Province, China

Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+.

广西北流-广东化州MS5.2级地震前后阳江新洲深部地热关联地下水异常研究

介绍了广东阳江新洲地热田深部地下水关联井水显著异常,广西北流—广东化州MS 5.2级地震发震前,新洲地热田监测井中两次延续数十小时的水位上涌现象,该现象解析是由于地热田东西向断层被挤压,引起深部地下水上升受阻而向地热田周边浅层地下水排泄,最终导致监测井中水位上涨。这意味着新洲地热田浅层地下水受深部地下水的影响,这种地下水体系对地应力活动引起的应变更敏感。研究结果对地震先兆、深部水文、深部地热均有参考意义。