Modified lithium manganese oxides were prepared by solid-state reaction of LiMn_(2)O_(4)and LiCoO_(2)as raw materials.A study was carried out by TG-DSC,XRD,DSC and electrochemical to analyse the reaction process and s...Modified lithium manganese oxides were prepared by solid-state reaction of LiMn_(2)O_(4)and LiCoO_(2)as raw materials.A study was carried out by TG-DSC,XRD,DSC and electrochemical to analyse the reaction process and structural characterization of products.The results show that the LiMn_(2)O_(4)reacts chemically with LiCoO_(2)at high temperature.All of Li and partial Co atoms can insert into the LiMn_(2)O_(4)crystal lattice and a newly formed spinel phase-modified LiMn_(2)O_(4)was obtained.The distribution of Co content is even in modified LiMn_(2)O_(4)compound.The modified LiMn_(2)O_(4)compound exhibits improved cycling stability at room and elevated temperature in comparison with the pure LiMn_(2)O_(4).展开更多
文摘Modified lithium manganese oxides were prepared by solid-state reaction of LiMn_(2)O_(4)and LiCoO_(2)as raw materials.A study was carried out by TG-DSC,XRD,DSC and electrochemical to analyse the reaction process and structural characterization of products.The results show that the LiMn_(2)O_(4)reacts chemically with LiCoO_(2)at high temperature.All of Li and partial Co atoms can insert into the LiMn_(2)O_(4)crystal lattice and a newly formed spinel phase-modified LiMn_(2)O_(4)was obtained.The distribution of Co content is even in modified LiMn_(2)O_(4)compound.The modified LiMn_(2)O_(4)compound exhibits improved cycling stability at room and elevated temperature in comparison with the pure LiMn_(2)O_(4).