A new carboxylate-phosphonate, [Zn3（O3PCH（CH3）COO）2（H2O）] 1, has been successfully synthesized by hydrothermal technique and characterized by X-ray single-crystal structure analysis, elemental analysis and infra...A new carboxylate-phosphonate, [Zn3（O3PCH（CH3）COO）2（H2O）] 1, has been successfully synthesized by hydrothermal technique and characterized by X-ray single-crystal structure analysis, elemental analysis and infrared spectroscopy. It crystallizes in monoclinic, space group P2 1/c with a = 4.9521（5）, b = 21.953（3）, c = 13.2266（18） A, β = 100.704（2）°, V= 1412.9（3） A3, Z= 4, Mr = 516.19, Dc= 2.427 g/cm^3, F（000） = 1016,μ（MoKα） = 5.332 mm^-1 and T= 293（2） K. The final R = 0.0605 and wR = 0.1354 for 2957 observed reflections with I 〉 2σ（I）. The thermogravimetric analysis （TGA） and fluorescent measurement have been done. The structure of compound 1 is a 3D open framework with 32-atom channels.展开更多
Treatment of bis(diphenylphosphino)methane(dppm)and 2-(diphenylphosphanyl)pyridine(dpppy)with Cu(CH_(3)CN)_(4)BF_(4)afforded a dinuclear Cu(I)complex[Cu_(2)(dpppy)_(2)(dppm)(CH_(3)CN)](BF_(4))_(2)·3CH_(2)Cl_(2)(1...Treatment of bis(diphenylphosphino)methane(dppm)and 2-(diphenylphosphanyl)pyridine(dpppy)with Cu(CH_(3)CN)_(4)BF_(4)afforded a dinuclear Cu(I)complex[Cu_(2)(dpppy)_(2)(dppm)(CH_(3)CN)](BF_(4))_(2)·3CH_(2)Cl_(2)(1).Complex 1 was structurally characterized by X-ray single-crystal analysis and its photophysical properties were studied in detail.It crystallizes in triclinic space group P1^(-)with a=13.0834(8),b=13.5568(8),c=21.8544(11)Å,α=76.090(5)°,β=80.803(5)°,γ=64.582(6)°,V=3391.3(3)Å^(3),Z=2,M_(r)=1507.42,D_(c)=1.476 g/cm^(3),F(000)=1532,GOOF=1.071,the final R=0.0700 for 9041 observed reflections with I>2σ(I)and wR=0.2063 for all data.The complex contains a Cu_(2)-core structure surrounded by one dppm and two dpppy ligands in a head-to-head arrangement.In the crystalline phase,complex 1 exhibits bright bluish-green photoluminescence(λ_(max)=488 nm)with high quantum yield(ϕ=0.57)at room temperature.It is still a relatively high emission quantum yield(ϕ=0.36)in doped PMMA thin film with 20 wt%dopant of complex 1.The emission peaks of 1 in dichloromethane solution and doped PMMA(20 wt%)thin films are 510 and 494 nm,respectively,showing a very slight bathochromic shift compared to that in crystalline phase.This phenomenon might be attributed to its rigid conformation that precludes the possible distortion of copper centers in the excited state.展开更多
基金This research was supported by the State Key Laboratory of Structural Chemistry, the National Ministry of Science and Technology of China (001CB1089), the Chinese Academy of Sciences (CAS), the National Natural Science Foundation of China (20333070 and 90206040), the Natural Science Foundation of CAS and Fujian Province (2005HZ01-1, 2004HZ01-1, 2003J042, 2004J041 and Z0513022)
文摘A new carboxylate-phosphonate, [Zn3（O3PCH（CH3）COO）2（H2O）] 1, has been successfully synthesized by hydrothermal technique and characterized by X-ray single-crystal structure analysis, elemental analysis and infrared spectroscopy. It crystallizes in monoclinic, space group P2 1/c with a = 4.9521（5）, b = 21.953（3）, c = 13.2266（18） A, β = 100.704（2）°, V= 1412.9（3） A3, Z= 4, Mr = 516.19, Dc= 2.427 g/cm^3, F（000） = 1016,μ（MoKα） = 5.332 mm^-1 and T= 293（2） K. The final R = 0.0605 and wR = 0.1354 for 2957 observed reflections with I 〉 2σ（I）. The thermogravimetric analysis （TGA） and fluorescent measurement have been done. The structure of compound 1 is a 3D open framework with 32-atom channels.
基金supported by the Natural Science Foundation of Fujian Province(2017J01576)。
文摘Treatment of bis(diphenylphosphino)methane(dppm)and 2-(diphenylphosphanyl)pyridine(dpppy)with Cu(CH_(3)CN)_(4)BF_(4)afforded a dinuclear Cu(I)complex[Cu_(2)(dpppy)_(2)(dppm)(CH_(3)CN)](BF_(4))_(2)·3CH_(2)Cl_(2)(1).Complex 1 was structurally characterized by X-ray single-crystal analysis and its photophysical properties were studied in detail.It crystallizes in triclinic space group P1^(-)with a=13.0834(8),b=13.5568(8),c=21.8544(11)Å,α=76.090(5)°,β=80.803(5)°,γ=64.582(6)°,V=3391.3(3)Å^(3),Z=2,M_(r)=1507.42,D_(c)=1.476 g/cm^(3),F(000)=1532,GOOF=1.071,the final R=0.0700 for 9041 observed reflections with I>2σ(I)and wR=0.2063 for all data.The complex contains a Cu_(2)-core structure surrounded by one dppm and two dpppy ligands in a head-to-head arrangement.In the crystalline phase,complex 1 exhibits bright bluish-green photoluminescence(λ_(max)=488 nm)with high quantum yield(ϕ=0.57)at room temperature.It is still a relatively high emission quantum yield(ϕ=0.36)in doped PMMA thin film with 20 wt%dopant of complex 1.The emission peaks of 1 in dichloromethane solution and doped PMMA(20 wt%)thin films are 510 and 494 nm,respectively,showing a very slight bathochromic shift compared to that in crystalline phase.This phenomenon might be attributed to its rigid conformation that precludes the possible distortion of copper centers in the excited state.
