Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating '...Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating ''facial amphiphiles'' by conformational analysis based on NOE-MD method.展开更多
A polyunsaturated mixed-acid phosphatidylcholine,1-palmitoyl-2-linolenoy1 snglycerophosphocholine (1) Prepared from D-mannitol as an optically active starting materialis described.
The structure of a saccharide component (Abs), with pronounced activity of improving immunity system, isolated from the root of Achyranthes bidentata Blume, a traditional Chinese herbal medicine, was studied. Based on...The structure of a saccharide component (Abs), with pronounced activity of improving immunity system, isolated from the root of Achyranthes bidentata Blume, a traditional Chinese herbal medicine, was studied. Based on C-13 NMR, HPLC, and methylation analyses, Abs was shown to be a mixture of short-chain fructans with an average dp of 8, containing more (2-->B) than (2-->1) linked beta-D-fructofuranosyl residues, with branching at O-6 or O-1 of 18% of the D-fructofuranosyl residues.展开更多
Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers,...Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers, in aqueous solution. The aggregates morphology was characterized by transmission electron microscopy (TEM) after negative staining. The superstructures of these aggregates seemed to be determined by the geometry and the head group's properties of the corresponding amphiphiles..展开更多
The structure of a radiation-protective sulfated polysaccharide, SP-APS, isolated from Spirulina platensis, was investigated by methylation analysis, partial acetolysis and H-1-NMR spectroscopy. The repeating-unit of ...The structure of a radiation-protective sulfated polysaccharide, SP-APS, isolated from Spirulina platensis, was investigated by methylation analysis, partial acetolysis and H-1-NMR spectroscopy. The repeating-unit of SP-APS as branched structures was elucidated.展开更多
The important intermediate for syntheses of various anti-HIV nucleoside analogues, methyl 2,3-dideoxy-3-fluoro-6-O-(p-methylbenzoyl)-alpha-D-ribofuranoside, was synthesized starting from 2-deoxy-D-ribose in 5 steps Wi...The important intermediate for syntheses of various anti-HIV nucleoside analogues, methyl 2,3-dideoxy-3-fluoro-6-O-(p-methylbenzoyl)-alpha-D-ribofuranoside, was synthesized starting from 2-deoxy-D-ribose in 5 steps With an overall yield of 24%. This strategy can be also used for synthesizing other analogues with various substitutions at 3-C position.展开更多
文摘Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating ''facial amphiphiles'' by conformational analysis based on NOE-MD method.
文摘A polyunsaturated mixed-acid phosphatidylcholine,1-palmitoyl-2-linolenoy1 snglycerophosphocholine (1) Prepared from D-mannitol as an optically active starting materialis described.
基金Project supported by the State Science and Technology Commission of China.
文摘The structure of a saccharide component (Abs), with pronounced activity of improving immunity system, isolated from the root of Achyranthes bidentata Blume, a traditional Chinese herbal medicine, was studied. Based on C-13 NMR, HPLC, and methylation analyses, Abs was shown to be a mixture of short-chain fructans with an average dp of 8, containing more (2-->B) than (2-->1) linked beta-D-fructofuranosyl residues, with branching at O-6 or O-1 of 18% of the D-fructofuranosyl residues.
文摘Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers, in aqueous solution. The aggregates morphology was characterized by transmission electron microscopy (TEM) after negative staining. The superstructures of these aggregates seemed to be determined by the geometry and the head group's properties of the corresponding amphiphiles..
基金Project supported by the State Science and Technology Commission of China.
文摘The structure of a radiation-protective sulfated polysaccharide, SP-APS, isolated from Spirulina platensis, was investigated by methylation analysis, partial acetolysis and H-1-NMR spectroscopy. The repeating-unit of SP-APS as branched structures was elucidated.
文摘The important intermediate for syntheses of various anti-HIV nucleoside analogues, methyl 2,3-dideoxy-3-fluoro-6-O-(p-methylbenzoyl)-alpha-D-ribofuranoside, was synthesized starting from 2-deoxy-D-ribose in 5 steps With an overall yield of 24%. This strategy can be also used for synthesizing other analogues with various substitutions at 3-C position.
