The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)res...The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)results confirmed the formationof AlN as a result of N+ion implantation.The atomic force microscope(AFM)results showed that grains of larger scale are formedby increasing N+energy which can be due to heat accumulation in the sample during implantation causing higher rate of diffusion inthe sample,hence decreasing the number of defects.Corrosion resistance of the samples was studied by the electrochemicalimpedance spectroscopy(EIS)measurements.Results showed that corrosion resistance of implanted Al increases with increasing N+ion energy.The equivalent circuits for the N+implanted Al samples with different energies were obtained,using the EIS data whichshowed strong dependence of the equivalent circuit elements on the surface morphology of the samples.Finally,the relationshipbetween corrosion inhibition and equivalent circuit elements was investigated.展开更多
基金University of Tehran and the Iran National Science Foundation(INSF)center of excellence for structural and microscopic properties of matter,Department of Physics,University of Tehran for partial support of this work
文摘The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)results confirmed the formationof AlN as a result of N+ion implantation.The atomic force microscope(AFM)results showed that grains of larger scale are formedby increasing N+energy which can be due to heat accumulation in the sample during implantation causing higher rate of diffusion inthe sample,hence decreasing the number of defects.Corrosion resistance of the samples was studied by the electrochemicalimpedance spectroscopy(EIS)measurements.Results showed that corrosion resistance of implanted Al increases with increasing N+ion energy.The equivalent circuits for the N+implanted Al samples with different energies were obtained,using the EIS data whichshowed strong dependence of the equivalent circuit elements on the surface morphology of the samples.Finally,the relationshipbetween corrosion inhibition and equivalent circuit elements was investigated.
