A new acid-base fluorescent switch containing both imidazo[4,5-f][1,10]-phenanthroline and triphenylamine groups has been synthesized.Its fluorescence emissions and absorptions can be reversibiy changed through proton...A new acid-base fluorescent switch containing both imidazo[4,5-f][1,10]-phenanthroline and triphenylamine groups has been synthesized.Its fluorescence emissions and absorptions can be reversibiy changed through protonation/deprotonation of imidazole and amine moiety by controlling the intramolecular charge transfer（ICT） process,leading to off-on-off fluorescent molecular switching.展开更多
A new two-photon absorption compound, 2-{4-[（dicyanomethylidene-5,5-dimethylcyclohexl）vinyl]phenyl}imidazo[4,5- f][1,10]phenanthroline （DDVPIP）, was synthesized and characterized. The one-photon excited fluorescen...A new two-photon absorption compound, 2-{4-[（dicyanomethylidene-5,5-dimethylcyclohexl）vinyl]phenyl}imidazo[4,5- f][1,10]phenanthroline （DDVPIP）, was synthesized and characterized. The one-photon excited fluorescence （OPEF） and two- photon excited fluorescence （TPEF） of DDVP1P are sensitive to the acid/base of the solution, which are enhanced in basic solution but weakened in acidic solution. Charge-transfer （CT） states of DDVPIP were calculated through theory methods to explain its acid/ base-sensitive fluorescent properties.展开更多
基金the financial support of the State National Natural Science Foundation of China (No.50325311)National 863 Project Foundation of China(No.2007AA10Z334)
文摘A new acid-base fluorescent switch containing both imidazo[4,5-f][1,10]-phenanthroline and triphenylamine groups has been synthesized.Its fluorescence emissions and absorptions can be reversibiy changed through protonation/deprotonation of imidazole and amine moiety by controlling the intramolecular charge transfer（ICT） process,leading to off-on-off fluorescent molecular switching.
基金support of the State National Natural Science Foundation of China (No.50325311)National 863 Project Foundation of China(No.2007AA10Z334)
文摘A new two-photon absorption compound, 2-{4-[（dicyanomethylidene-5,5-dimethylcyclohexl）vinyl]phenyl}imidazo[4,5- f][1,10]phenanthroline （DDVPIP）, was synthesized and characterized. The one-photon excited fluorescence （OPEF） and two- photon excited fluorescence （TPEF） of DDVP1P are sensitive to the acid/base of the solution, which are enhanced in basic solution but weakened in acidic solution. Charge-transfer （CT） states of DDVPIP were calculated through theory methods to explain its acid/ base-sensitive fluorescent properties.
