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Rationally designing electrolyte additives for highly improving cyclability of LiNi_(0.5)Mn_(1.5)O_(4)/Graphite cells
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作者 Zhiyong Xia Kuan Zhou +8 位作者 Xiaoyan Lin Zhangyating Xie Qiurong Chen Xiaoqing Li Jie Cai Suli Li Hai Wang Mengqing Xu Weishan Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期266-275,共10页
High voltage is necessary for high energy lithium-ion batteries but difficult to achieve because of the highly deteriorated cyclability of the batteries.A novel strategy is developed to extend cyclability of a high vo... High voltage is necessary for high energy lithium-ion batteries but difficult to achieve because of the highly deteriorated cyclability of the batteries.A novel strategy is developed to extend cyclability of a high voltage lithium-ion battery,LiNi_(0.5)Mn_(1.5)O_(4)/Graphite(LNMO/Graphite)cell,which emphasizes a rational design of an electrolyte additive that can effectively construct protective interphases on anode and cathode and highly eliminate the effect of hydrogen fluoride(HF).5-Trifluoromethylpyridine-trime thyl lithium borate(LTFMP-TMB),is synthesized,featuring with multi-functionalities.Its anion TFMPTMB-tends to be enriched on cathode and can be preferentially oxidized yielding TMB and radical TFMP-.Both TMB and radical TFMP can combine HF and thus eliminate the detrimental effect of HF on cathode,while the TMB dragged on cathode thus takes a preferential oxidation and constructs a protective cathode interphase.On the other hand,LTFMP-TMB is preferentially reduced on anode and constructs a protective anode interphase.Consequently,a small amount of LTFMP-TMB(0.2%)in 1.0 M LiPF6in EC/DEC/EMC(3/2/5,wt%)results in a highly improved cyclability of LNMO/Graphite cell,with the capacity retention enhanced from 52%to 80%after 150 cycles at 0.5 C between 3.5 and 4.8 V.The as-developed strategy provides a model of designing electrolyte additives for improving cyclability of high voltage batteries. 展开更多
关键词 Electrolyte additive Design and synthesis CYCLABILITY High voltage batteries Cathode and anode interphases
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Distributed Matching Theory-Based Task Re-Allocating for Heterogeneous Multi-UAV Edge Computing
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作者 Yangang Wang Xianglin Wei +3 位作者 Hai Wang Yongyang Hu Kuang Zhao Jianhua Fan 《China Communications》 SCIE CSCD 2024年第1期260-278,共19页
Many efforts have been devoted to efficient task scheduling in Multi-Unmanned Aerial Vehicle(UAV)edge computing.However,the heterogeneity of UAV computation resource,and the task re-allocating between UAVs have not be... Many efforts have been devoted to efficient task scheduling in Multi-Unmanned Aerial Vehicle(UAV)edge computing.However,the heterogeneity of UAV computation resource,and the task re-allocating between UAVs have not been fully considered yet.Moreover,most existing works neglect the fact that a task can only be executed on the UAV equipped with its desired service function(SF).In this backdrop,this paper formulates the task scheduling problem as a multi-objective task scheduling problem,which aims at maximizing the task execution success ratio while minimizing the average weighted sum of all tasks’completion time and energy consumption.Optimizing three coupled goals in a realtime manner with the dynamic arrival of tasks hinders us from adopting existing methods,like machine learning-based solutions that require a long training time and tremendous pre-knowledge about the task arrival process,or heuristic-based ones that usually incur a long decision-making time.To tackle this problem in a distributed manner,we establish a matching theory framework,in which three conflicting goals are treated as the preferences of tasks,SFs and UAVs.Then,a Distributed Matching Theory-based Re-allocating(DiMaToRe)algorithm is put forward.We formally proved that a stable matching can be achieved by our proposal.Extensive simulation results show that Di Ma To Re algorithm outperforms benchmark algorithms under diverse parameter settings and has good robustness. 展开更多
关键词 edge computing HETEROGENEITY matching theory service function unmanned aerial vehicle
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Adaptive Trajectory Tracking Control for Nonholonomic Wheeled Mobile Robots:A Barrier Function Sliding Mode Approach
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作者 Yunjun Zheng Jinchuan Zheng +3 位作者 Ke Shao Han Zhao Hao Xie Hai Wang 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第4期1007-1021,共15页
The trajectory tracking control performance of nonholonomic wheeled mobile robots(NWMRs)is subject to nonholonomic constraints,system uncertainties,and external disturbances.This paper proposes a barrier function-base... The trajectory tracking control performance of nonholonomic wheeled mobile robots(NWMRs)is subject to nonholonomic constraints,system uncertainties,and external disturbances.This paper proposes a barrier function-based adaptive sliding mode control(BFASMC)method to provide high-precision,fast-response performance and robustness for NWMRs.Compared with the conventional adaptive sliding mode control,the proposed control strategy can guarantee that the sliding mode variables converge to a predefined neighborhood of origin with a predefined reaching time independent of the prior knowledge of the uncertainties and disturbances bounds.Another advantage of the proposed algorithm is that the control gains can be adaptively adjusted to follow the disturbances amplitudes thanks to the barrier function.The benefit is that the overestimation of control gain can be eliminated,resulting in chattering reduction.Moreover,a modified barrier function-like control gain is employed to prevent the input saturation problem due to the physical limit of the actuator.The stability analysis and comparative experiments demonstrate that the proposed BFASMC can ensure the prespecified convergence performance of the NWMR system output variables and strong robustness against uncertainties/disturbances. 展开更多
关键词 Adaptive sliding mode barrier function nonholonomic wheeled mobile robot(NWMR) trajectory tracking control
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Large-aperture Telescope Tracking Control Based on Time-synchronization Strategy
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作者 Yun Li Yu Ye +7 位作者 Shi-Hai Yang Ling-Zhe Xu Jin Xu Hai Wang Zhuang-Zhuang Deng Rui-Qiang Liu Xiao-Jie Gu Bo-Zhong Gu 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2024年第3期34-46,共13页
A time-synchronization strategy for packetized transmission of target position about a large-aperture telescope observation control system has been proposed in this study.Compared with the existing telescope tracking ... A time-synchronization strategy for packetized transmission of target position about a large-aperture telescope observation control system has been proposed in this study.Compared with the existing telescope tracking strategy,the target position packing and sending strategy based on the time synchronization method proposed in this paper has the advantages of high stability and reliability.First,the telescope tracking observation control method was elaborated in this paper,including the motion pattern during telescope tracking.Then,the strategy for packetizes transmission of target positions based on time-synchronization is established and lists the detailed steps.Finally,the performance of the tracking strategy is verified using the 2.5 m telescope for the simulated uniform speed star and the blind-tracking fixed star HIP 31216,respectively.The test results show that the accuracy root mean square of the tracking strategy proposed in this paper is less than 0".02 at 30 minutes,and the performance is much better than the design requirement of 0".3.The most important advantage of this tracking strategy is that the telescope can guarantee normal tracking for a certain period of time even if the hardware or software of the host computer is abnormal. 展开更多
关键词 miscellaneous-telescopes-methods observational-methods ANALYTICAL
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GaN based ultraviolet laser diodes
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作者 Jing Yang Degang Zhao +9 位作者 Zongshun Liu Yujie Huang Baibin Wang Xiaowei Wang Yuheng Zhang Zhenzhuo Zhang Feng Liang Lihong Duan Hai Wang Yongsheng Shi 《Journal of Semiconductors》 EI CAS CSCD 2024年第1期6-15,共10页
In the past few years,many groups have focused on the research and development of GaN-based ultraviolet laser diodes(UV LDs).Great progresses have been achieved even though many challenges exist.In this article,we ana... In the past few years,many groups have focused on the research and development of GaN-based ultraviolet laser diodes(UV LDs).Great progresses have been achieved even though many challenges exist.In this article,we analyze the challenges of developing GaN-based ultraviolet laser diodes,and the approaches to improve the performance of ultraviolet laser diode are reviewed.With these techniques,room temperature(RT)pulsed oscillation of AlGaN UVA(ultraviolet A)LD has been realized,with a lasing wavelength of 357.9 nm.Combining with the suppression of thermal effect,the high output power of 3.8 W UV LD with a lasing wavelength of 386.5 nm was also fabricated. 展开更多
关键词 DIODES LASER GAN
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The Effect of Soil Enzymes and Polysaccharides Secreted by the Roots of Salvia miltiorrhiza Bunge under Drought,High Temperature,and Nitrogen and Phosphorus Deficits
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作者 Yong Qin Xiaoyu Li +3 位作者 Yanhong Wu Hai Wang Guiqi Han Zhuyun Yan 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第1期119-135,共17页
Root exudates serve as crucial mediators for information exchange between plants and soil,and are an important evolutionary mechanism for plants’adaptation to environmental changes.In this study,15 different abiotic ... Root exudates serve as crucial mediators for information exchange between plants and soil,and are an important evolutionary mechanism for plants’adaptation to environmental changes.In this study,15 different abiotic stress models were established using various stress factors,including drought(D),high temperature(T),nitrogen deficiency(N),phosphorus deficiency(P),and their combinations.We investigated their effects on the seedling growth of Salvia miltiorrhiza Bunge and the activities of Solid-Urease(S-UE),Solid-Nitrite Reductase(S-NiR),Solid-Nitrate Reductase(S-NR),Solid-Phosphotransferase(S-PT),and Solid-Catalase(S-CAT),as well as the contents of polysaccharides in the culture medium.The results showed that the growth of S.miltiorrhiza was inhibited under 15 stress conditions.Among them,13 stress conditions increased the root-shoot ratio.These 15 stress conditions significantly reduced the activity of S-NR,two combinations significantly improved the activity of S-NIR,they were synergistic stresses of high temperature and nitrogen deficiency(TN),and synergistic stresses of drought and nitrogen deficiency(DN)(p<0.05).The activity of S-UE was significantly improved under N,D,T,synergistic stresses of drought and high temperature(DT),DN,synergistic stresses of drought and phosphorus deficiency(DP),and synergistic stresses of high temperature,nitrogen,and phosphorus deficiency(TNP)stress conditions(p<0.05).Most stress combinations reduced the activity of S-PT,but D and T significantly improved it.(p<0.05).The N,DN,and TN stress conditions significantly reduced S-CAT activity.The P,DT,and synergistic stresses of drought,high temperature,and phosphorus deficiency(DTP)significantly decreased the total polysaccharide content of the soil(p<0.05).The research suggested that abiotic stress hindered the growth of S.miltiorrhiza and altered the behavior of root secretion.Roots regulated the secretion of several substances in response to various abiotic stresses,including soil nitrogen cycle enzymes,phosphorus transport-related enzymes,and antioxidant enzymes.In conclusion,plants regulate the utilization of rhizosphere substances in response to abiotic stresses by modulating the exudation of soil enzymes and polysaccharides by the root system.At the same time,soil carbon sequestration was affected by the adverse environment,which restricted the input of organic matter into the soil. 展开更多
关键词 Abiotic stress Salvia miltiorrhiza soil enzymes total polysaccharides soil carbon sequestration
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Transparent cap adjusted the stent placed for stenosis after endoscopic injection of esophageal varices:A case report
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作者 Fu-Long Zhang Jing Xu +8 位作者 Yuan-Dong Zhu Qian-Neng Wu Yan Shi Lei Fang Dan Zhou Hai Wang Chao-JunHuang Chun-Hua Zhou Qun Zhu 《World Journal of Clinical Cases》 SCIE 2024年第15期2614-2620,共7页
BACKGROUND The stent embedded in the esophageal mucosa is one of the complications after stenting for esophageal stricture.We present a case of stent adjustment with the aid of a transparent cap after endoscopic injec... BACKGROUND The stent embedded in the esophageal mucosa is one of the complications after stenting for esophageal stricture.We present a case of stent adjustment with the aid of a transparent cap after endoscopic injection of an esophageal varices stent.CASE SUMMARY A 61-year-old male patient came to the hospital with discomfort of the chest after the stent implanted for the stenosis because of endoscopic injection of esophageal varices.The gastroscopy was performed,and the stent embedded into the esophageal mucosa.At first,we pulled the recycling line for shrinking the stent,however,the mucosa could not be removed from the stent.Then a forceps was performed to remove the mucosa in the stent,nevertheless,the bleeding form the mucosa was obvious.And then,we used a transparent cap to scrape the mucosa along the stent,and the mucosa were removed successfully without bleeding.CONCLUSION A transparent cap helps gastroscopy to remove the mucosa embedded in the stent after endoscopic injection of the esophageal varices stent. 展开更多
关键词 STENT Transparent cap STENOSIS Endoscopic injection Esophageal varices Case report
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Effect of N_(2) partial pressure on comprehensive properties of antibacterial TiN/Cu nanocomposite coating
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作者 Hui Liu Yanhui Zhao +10 位作者 Chuanshi Sui Yi Li Muhammad Ali Siddiqui Susu Li Tong Li Shuyuan Zhang Hai Wang Tao Jin Ling Ren Ke Yang Ning Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第1期131-143,共13页
Foreign body reactions to the wear debris and corrosion products from the implants,and bacterial infections are the main factors leading to the implant failures.In order to resolve these problems,the antibacterial TiN... Foreign body reactions to the wear debris and corrosion products from the implants,and bacterial infections are the main factors leading to the implant failures.In order to resolve these problems,the antibacterial TiN/Cu nanocomposite coatings with various N_(2) partial pressures were deposited on 304 stainless steels(SS)using an arc ion plating(AIP)system,named TiN/Cu-x(x=0.5,1.0,1.5 Pa).The results of X-ray diffraction analysis,energy-dispersive X-ray spectroscopy,and scanning electron microscopy showed that the N_(2) partial pressures determined the Cu contents,surface defects,and crystallite sizes of TiN/Cu nanocomposite coatings,which further influenced the comprehensive abilities.And the hardness and wear resistances of TiN/Cu coatings were enhanced with increase of the crystallite sizes.Under the co-actions of surface defects,crystallite sizes,and Cu content,TiN/Cu-1.0 and TiN/Cu-1.5 coatings possessed excellent corrosion resistance.Besides,the biological tests proved that all the TiN/Cu coatings showed no cytotoxicity with strong antibacterial ability.Among them,TiN/Cu-1.5 coating significantly promoted the cell proliferation,which is expected to be a novel antibacterial,corrosion-resistant,and wear-resistant coating on the surfaces of medical implants. 展开更多
关键词 N_(2)partial pressure TiN/Cu coating wear resistance corrosion behavior antibacterial ability CYTOCOMPATIBILITY
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Genesis of the Jiajika superlarge lithium deposit,Sichuan,China:constraints from He–Ar–H–O isotopes
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作者 Tao Liu Hai Wang +6 位作者 Shihong Tian Denghong Wang Xianfang Li Xiaofang Fu Xuefeng Hao Yujie Zhang Kejun Hou 《Acta Geochimica》 EI CAS CSCD 2023年第3期517-534,共18页
The Jiajika granitic-and pegmatite-type lithium deposit,which is in the Songpan-Garze Orogenic Belt in western Sichuan Province,China,is the largest in Asia.Previous studies have examined the geochemistry and mineralo... The Jiajika granitic-and pegmatite-type lithium deposit,which is in the Songpan-Garze Orogenic Belt in western Sichuan Province,China,is the largest in Asia.Previous studies have examined the geochemistry and mineralogy of pegmatites and their parental source rocks to determine the genesis of the deposit.However,the evolution of magmatic-hydrothermal fluids has received limited attention.We analyzed He–Ar–H–O isotopes to decipher the ore-fluid nature and identify the contribution of fluids to mineralization in the late stage of crystallization differentiation.In the Jiajika ore field,two-mica granites,pegmatites(including common pegmatites and spodumene pegmatites),metasandstones,and schists are the dominant rock types exposed.Common pegmatites derived from early differentiation of the two-mica granitic magmas before they evolved into spodumene pegmatites during the late stage of the magmatic evolution.Common pegmatites have~3He/~4He ratios that vary from 0.18 to 4.68 Ra(mean1.62 Ra),and their~(40)Ar/~(36)Ar ratios range from 426.70 to 1408.06(mean 761.81);spodumene pegmatites have~3He/~4He ratios that vary from 0.18 to 2.66 Ra(mean 0.87Ra)and their~(40)Ar/~(36)Ar ratios range from 402.13 to 1907.34(mean 801.65).These data indicate that the hydrothermal fluids were shown a mixture of crust-and mantle-derived materials,and the proportion of crustderived materials in spodumene pegmatites increases significantly in the late stage of the magmatic evolution.Theδ~(18)OH_(2)O–VSMOWvalues of common pegmatites range from 6.2‰to 10.9‰,with a mean value of 8.6‰,andδDV–SMOWvalues vary from-110‰to-72‰,with a mean o f-85‰.Theδ~(18)OH_(2)O–VSMOWvalues of spodumene pegmatites range from 5.3‰to 13.2‰,with a mean of 9.1‰,andδDV–SMOWvalues vary from-115‰to-77‰,with a mean of-91‰.These data suggest that the ore-forming fluids came from primary magmatic water gradually mixing with more meteoric water in the late stage of the magmatic evolution.Based on the He–Ar–H–O and other existing data,we propose that the oreforming metals are mainly derived from the upper continental crust with a minor contribution from the mantle,and the fluid exsolution and addition of meteoric water during the formation of pegmatite contributed to the formation of the Jiajika superlarge lithium deposit. 展开更多
关键词 He–Ar–H–O isotopes Magmatic-hydrothermal fluids Common pegmatites Spodumene pegmatites Jiajika superlarge lithium deposit SICHUAN
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A machine learning-based study of multifactor susceptibility and risk control of induced seismicity in unconventional reservoirs
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作者 Gang Hui Zhang-Xin Chen +5 位作者 Hai Wang Zhao-Jie Song Shu-Hua Wang Hong-Liang Zhang Dong-Mei Zhang Fei Gu 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2232-2243,共12页
A comprehensive dataset from 594 fracturing wells throughout the Duvernay Formation near Fox Creek, Alberta, is collected to quantify the influences of geological, geomechanical, and operational features on the distri... A comprehensive dataset from 594 fracturing wells throughout the Duvernay Formation near Fox Creek, Alberta, is collected to quantify the influences of geological, geomechanical, and operational features on the distribution and magnitude of hydraulic fracturing-induced seismicity. An integrated machine learning-based investigation is conducted to systematically evaluate multiple factors that contribute to induced seismicity. Feature importance indicates that a distance to fault, a distance to basement, minimum principal stress, cumulative fluid injection, initial formation pressure, and the number of fracturing stages are among significant model predictors. Our seismicity prediction map matches the observed spatial seismicity, and the prediction model successfully guides the fracturing job size of a new well to reduce seismicity risks. This study can apply to mitigating potential seismicity risks in other seismicity-frequent regions. 展开更多
关键词 Induced seismicity Hydraulic fracturing Seismicity susceptibility Risk control Machine learning
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Highly improved cyclic stability of Ni-rich/Li batteries with succinic anhydride as electrolyte additive and underlying mechanism
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作者 Shu Yang Guanjie Li +7 位作者 Xiaoyan Lin Changyong Mo Xianggui Zhou Lijiao Quan Kuan Zhou Suli Li Hai Wang Weishan Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第3期80-90,I0003,共12页
Lithium-metal battery based on Ni-rich cathode provides high energy density but presents poor cyclic stability due to the unstable electrode/electrolyte interfaces on both cathode and anode.In this work,we report a ne... Lithium-metal battery based on Ni-rich cathode provides high energy density but presents poor cyclic stability due to the unstable electrode/electrolyte interfaces on both cathode and anode.In this work,we report a new strategy to address this issue.It is found that the cyclic stability of Ni-rich/Li battery can be significantly improved by using succinic anhydride(SA) as an electrolyte additive.Specifically,the capacity retention of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)/Li cell is improved from 14% to 83% after 200cycles at 1 C between 3.0 and 4.35 V by applying 5% SA.The underlying mechanism of SA contribution is understood by comparing the effects of malic anhydride(MA) and citraconic anhydride(CA), both of which share a similar molecular structure to SA but show different effects.On anode side,SA can but MA and CA cannot form a protective solid electrolyte interphase(SEI) on Li anode.On cathode side,three anhydrides can suppress the formation of hydrogen fluoride from electrolyte oxidation decomposition,but SA behaves best.Typically,MA shows adverse effects on the interface stability of Li anode and NCM811 cathode,which originates from its high acidity.Though the acidity of MA can be mitigated by substituting a methyl for one H atom at its C=C bond,the substituent CA cannot compete with SA in cyclic stability improvement of the cell,because the SEI resulting from CA is not as robust as that from SA,which is related to the binding energy of the SEI components.This understanding reveals the importance of the electrolyte acidity on the Ni-rich cathode and the robustness of the SEI on Li anode,which is helpful for rationally designing new electrolyte additives to further improve the cyclic stability of high-energydensity Ni-rich/Li batteries. 展开更多
关键词 Lithium-metal battery Ni-rich cathode Electrolyte additives Succinic Anhydride Cyclic stability
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An OP-TEE Energy-Efficient Task Scheduling Approach Based on Mobile Application Characteristics
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作者 Hai Wang Xuan Hao +3 位作者 Shuo Ji Jie Zheng Yuhui Ma Jianfeng Yang 《Intelligent Automation & Soft Computing》 SCIE 2023年第8期1621-1635,共15页
Trusted Execution Environment(TEE)is an important part of the security architecture of modern mobile devices,but its secure interaction process brings extra computing burden to mobile devices.This paper takes open por... Trusted Execution Environment(TEE)is an important part of the security architecture of modern mobile devices,but its secure interaction process brings extra computing burden to mobile devices.This paper takes open portable trusted execution environment(OP-TEE)as the research object and deploys it to Raspberry Pi 3B,designs and implements a benchmark for OP-TEE,and analyzes its program characteristics.Furthermore,the application execution time,energy consumption and energy-delay product(EDP)are taken as the optimization objectives,and the central processing unit(CPU)frequency scheduling strategy of mobile devices is dynamically adjusted according to the characteristics of different applications through the combined model.The experimental result shows that compared with the default strategy,the scheduling method proposed in this paper saves 21.18%on average with the Line Regression-Decision Tree scheduling model with the shortest delay as the optimization objective.The Decision Tree-Support Vector Regression(SVR)scheduling model,which takes the lowest energy consumption as the optimization goal,saves 22%energy on average.The Decision Tree-K-Nearest Neighbor(KNN)scheduling model with the lowest EDP as the optimization objective optimizes about 33.9%on average. 展开更多
关键词 Trusted execution environment energy efficiency optimization CPU scheduling governor machine learning
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钢铁冶炼台车加热炉低氮烟气回流管风机的改造设计
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作者 盖京方 王海 +1 位作者 盖克洲 马德明 《风机技术》 2023年第S01期52-55,共4页
钢铁冶炼系统,采用台车加热炉,通过回流管将高温气体低氮烟气回流到锅炉系统内。为了获知煤气加热炉的用风量,需要计算煤气充分燃烧需要的气体和产生的气体在标准状态下的体积流量;通过改进加热炉回流管的设计,进而确定新风机的性能参... 钢铁冶炼系统,采用台车加热炉,通过回流管将高温气体低氮烟气回流到锅炉系统内。为了获知煤气加热炉的用风量,需要计算煤气充分燃烧需要的气体和产生的气体在标准状态下的体积流量;通过改进加热炉回流管的设计,进而确定新风机的性能参数。重新对新风机进行结构设计和选型计算,经性能测试检验,新风机的效率提升了2%~3%,且满足了加热炉系统的环保排放氮氧化物的要求。 展开更多
关键词 加热炉环保风机 煤气燃烧 回流管设计 高温力学特性
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原发性胃淋巴瘤中APC蛋白的表达及其意义
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作者 艾晓辉 李小荣 +7 位作者 雷庆良 廖国庆 罗博 刘蔚东 王海 刘安文 付江涛 刘合利 《中国现代医学杂志》 CAS 2018年第20期41-45,共5页
目的研究分析原发性胃淋巴瘤(PGL)组织中腺瘤性结肠息肉病(APC)蛋白的表达,以及与临床病理特征的关系,探讨APC蛋白在PGL发生、发展中的作用及意义。方法选取2006年6月-2011年12月中南大学湘雅医院、湖南省邵阳市中医医院PGL术后患者的... 目的研究分析原发性胃淋巴瘤(PGL)组织中腺瘤性结肠息肉病(APC)蛋白的表达,以及与临床病理特征的关系,探讨APC蛋白在PGL发生、发展中的作用及意义。方法选取2006年6月-2011年12月中南大学湘雅医院、湖南省邵阳市中医医院PGL术后患者的临床资料和手术病理标本。采用免疫组织化学法检测45例PGL和30例胃正常黏膜组织中APC蛋白的表达。结果 PGL和胃正常黏膜组织中APC蛋白阳性表达率分别为37.78%和90.0%,差异有统计学意义(P<0.05)。PGL组织中有无淋巴结转移和不同临床分期的APC蛋白阳性表达率比较,差异有统计学意义(P<0.05)。不同年龄、性别及大体形态的APC蛋白阳性表达率比较,差异无统计学意义(P>0.05)。结论 APC蛋白在PGL中低表达,是PGL发生的一个重要原因,提示APC蛋白可作为PGL发生的一个重要检测指标。 展开更多
关键词 原发性胃淋巴瘤 腺瘤性结肠息肉病蛋白 免疫组织化学法
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通过CeO_x修饰提高金纳米颗粒在CO氧化反应中的催化活性和耐久性(英文) 被引量:3
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作者 王凌翔 王亮 +2 位作者 张建 王海 肖丰收 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第10期1608-1614,共7页
CO催化氧化是一个重要的经典反应,与许多应用息息相关,包括痕量CO气体检测、汽车尾气净化和安全防护等,吸引了人们广泛的研究兴趣.负载型Au纳米颗粒在CO氧化等许多反应中有着与众不同的催化活性,具有广泛的应用前景,但依然存在着稳定性... CO催化氧化是一个重要的经典反应,与许多应用息息相关,包括痕量CO气体检测、汽车尾气净化和安全防护等,吸引了人们广泛的研究兴趣.负载型Au纳米颗粒在CO氧化等许多反应中有着与众不同的催化活性,具有广泛的应用前景,但依然存在着稳定性差、易团聚失活的问题.人们通过应用多孔载体隔离Au纳米颗粒,在Au纳米颗粒表面覆盖金属氧化物、二氧化硅或碳,以及对Au纳米粒子进行封装等方法解决这些问题.尤其是利用金属氧化物与Au纳米粒子间的强相互作用对其进行覆盖或封装,有效地提高了Au催化材料的稳定性.但以上策略操作流程复杂,不利于应用.本文发展了一种简单有效的方法,通过EDTA的络合作用引入CeO_x对Au纳米粒子进行修饰,得到的CeO_x@Au/SiO_2催化剂活性和耐久性明显提升.采用X射线衍射(XRD)和高分辨透射电子显微镜(HRTEM)证明了CeO_x成功地修饰在Au纳米颗粒上.且通过EDTA引入CeO_x所制备的CeO_x@Au/SiO_2催化剂结构明显不同于直接加入纳米CeO_2所得到的CeO_x-Au/SiO_2的结构.EDTA的络合作用能有效地连结Ce与Au物种,经焙烧消除EDTA后,加强了CeO_x与Au间相互作用,最终在Au纳米粒子表面形成丰富的CeO_x颗粒与原子级厚度的CeO_x层.进一步应用X射线光电子能谱(XPS)和氢气程序升温还原(H_2-TPR)等手段研究了CeO_x修饰对Au纳米粒子的影响.XPS结果表明,CeO_x@Au/SiO_2催化剂带正电的Au^+和Au^(3+)的浓度明显高于一般的Au/SiO_2和直接加入CeO_2制备得到的CeO_x-Au/SiO_2催化剂.H_2-TPR同样表明,CeO_x修饰调变了Au纳米粒子的氧化还原性.这些均对其在CO催化氧化反应中的催化活性具有重要影响将CeO_x@Au/SiO_2催化剂用于CO催化氧化反应中,160℃时,CO转化率达98.8%,至180℃后实现了CO的完全转化.而一般的Au/SiO_2催化剂在160℃时CO转化率仅为4.0%,CO的完全转化则需340℃.直接加入纳米CeO_2所得到的CeO_x-Au/SiO_2催化剂,其催化活性略有提升,CO完全转化所需的温度为300℃.这充分证明了通过CeO_x修饰Au纳米粒子,能有效提升其催化活性.原位漫反射红外光谱(DRIFT)结果表明,CeO_x修饰促进了CO在Au表面的吸附,并能形成[Au(CO)_2]^(δ+)物种;同时还观察到大量的单齿CO_3^(2-)物种信号,反映了CeO_x@Au/SiO_2催化剂表面存在丰富的活性氧物种.通入O_2后,观察到了大量CO_3^(2-)物种信号和气相CO_2,印证了催化剂表面发生的CO催化氧化过程,也表明其具有非常高的催化活性.考察了CeO_x@Au/SiO_2催化剂的耐久性,发现经50hCO氧化反应,催化剂依然能有效保持活性.相比之下,Au/SiO_2催化剂经10 h反应后,开始明显失活.由此可见,CeO_x@Au/SiO_2催化剂具有相当高的耐久性.在600℃将催化剂焙烧3 h,发现Au/SiO_2催化剂中Au纳米粒子存在明显团聚现象,而CeO_x@Au/SiO_2催化剂的Au纳米粒子依然均匀分布在载体表面,且粒径未发生明显变化. 展开更多
关键词 一氧化碳氧化 二氧化铈 界面 抗烧结
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氧化锰晶体作为催化材料调控氨氧化反应产物选择性
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作者 王海 罗青松 +4 位作者 王亮 惠宇 秦玉才 宋丽娟 肖丰收 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第12期2164-2172,共9页
有机腈类化合物作为一类重要的化工原料,被广泛应用于医药/农药制造、精细化学品合成和高性能纤维/橡胶生产中.传统合成有机腈类化合物一般使用剧毒的氰化物作为腈化试剂,这类氰化物在危害人体健康的同时,也会严重污染生态环境.针对无... 有机腈类化合物作为一类重要的化工原料,被广泛应用于医药/农药制造、精细化学品合成和高性能纤维/橡胶生产中.传统合成有机腈类化合物一般使用剧毒的氰化物作为腈化试剂,这类氰化物在危害人体健康的同时,也会严重污染生态环境.针对无氰化物的腈化过程,发展了很多新的反应路线,其中,采用氨气作为氮源的直接氨氧化引起了广泛关注.在该反应中,高温气固相氨氧化反应容易发生过氧化等副反应.与之相比,液相体系中的氨氧化过程反应条件则相对温和,可以有效抑制过氧化.但是,在液相反应中,腈类产物很容易被水合成酰胺类化合物,从而导致该反应的产物选择性大幅降低.本文研究发现,通过改变氧化锰晶体结构可以有效地调控醇类分子氨氧化反应中腈和酰胺产物的选择性.MnO_(2)(包括α,β,γ和δ相)催化的氨氧化过程中,主要得到了酰胺(选择性>99.0%),而在相同反应条件下,α-Mn_(2)O_(3)却可以高选择性地催化醇氨氧化到腈类产物(选择性>99.0%),在该体系中,即使额外增加反应体系中水和催化剂的用量,腈类产物依然不会转化为酰胺产物.动力学研究结果表明,α-Mn_(2)O_(3)催化腈水合到酰胺的反应速率几乎为零,这说明该类催化剂可以有效抑制腈水合反应.原位红外光谱结果表明,α-Mn_(2)O_(3)表面无法有效活化水分子,并且对腈类分子的吸附较弱,这些因素都导致了腈水合反应难以进行,从而可以高选择性地形成腈类化合物.与之相反,MnO_(2)催化材料则可以高效地活化水分子,并且对腈类分子吸附较强,从而有效促进了水合反应并获得了酰胺产物.综上,通过调控氧化锰的晶体类型就可以简单、有效地改变氨氧化反应中的产物选择性.即使在苛刻的反应条件下,例如较大量的水存在下,α-Mn_(2)O_(3)催化的反应体系中依然可以高选择性地获得腈类化合物.本文为高效调控氨氧化反应的产物选择性提供了一个可靠方案. 展开更多
关键词 氧化锰 氨氧化 腈类化合物 酰胺类化合物 晶体结构
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Fuzzy self-tuning PID control of the operation temperatures in a two-staged membrane separation process 被引量:8
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作者 Lei Wang Wencai Du +1 位作者 Hai Wang Hong Wu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第4期409-414,共6页
为从精炼厂气体的氢恢复的一个二阶段的膜分离过程被介绍。煤气的膜分离过程的原则和操作温度的影响被分析。因为常规 PID 控制器是困难的使操作温度稳定,一个模糊自我调节的 PID 控制算法被建议。申请证明算法是有效的,两个阶段的操... 为从精炼厂气体的氢恢复的一个二阶段的膜分离过程被介绍。煤气的膜分离过程的原则和操作温度的影响被分析。因为常规 PID 控制器是困难的使操作温度稳定,一个模糊自我调节的 PID 控制算法被建议。申请证明算法是有效的,两个阶段的操作温度能稳定地被控制,并且氢恢复单位的操作灵活性和适应性安全地被提高。这研究打一个基础优化膜分离进程的控制并且因此保证膜性能。 展开更多
关键词 合成气装置 天然气 丙烯 回收
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Radial Basis Function Neural Networks-Based Modeling of the Membrane Separation Process: Hydrogen Recovery from Refinery Gases 被引量:6
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作者 Lei Wang Cheng Shao +1 位作者 Hai Wang Hong Wu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2006年第3期230-234,共5页
Membrane technology has found wide applications in the petrochemical industry, mainly in the purification and recovery of the hydrogen resources. Accurate prediction of the membrane separation performance plays an imp... Membrane technology has found wide applications in the petrochemical industry, mainly in the purification and recovery of the hydrogen resources. Accurate prediction of the membrane separation performance plays an important role in carrying out advanced process control (APC). For the first time, a soft-sensor model for the membrane separation process has been established based on the radial basis function (RBF) neural networks. The main performance parameters, i.e, permeate hydrogen concentration, permeate gas flux, and residue hydrogen concentration, are estimated quantitatively by measuring the operating temperature, feed-side pressure, permeate-side pressure, residue-side pressure, feed-gas flux, and feed-hydrogen concentration excluding flow structure, membrane parameters, and other compositions. The predicted results can gain the desired effects. The effectiveness of this novel approach lays a foundation for integrating control technology and optimizing the operation of the gas membrane separation process. 展开更多
关键词 membrane separation hydrogen recovery soft sensor RBF neural networks REFINERY operation optimization
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Room-temperature continuous-wave operation of GaN-based blue-violet laser diodes with a lifetime longer than 1000h 被引量:4
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作者 Feng Liang Jing Yang +9 位作者 Degang Zhao Zongshun Liu Jianjun Zhu Ping Chen Desheng Jiang Yongsheng Shi Hai Wang Lihong Duan Liqun Zhang Hui Yang 《Journal of Semiconductors》 EI CAS CSCD 2019年第2期39-42,共4页
GaN-based continuous-wave operated blue-violet laser diodes(LDs) with long lifetime are demonstrated, which are grown on a c-plane GaN substrate by metal organic chemical vapor deposition with a 10 × 600 μm^2 ri... GaN-based continuous-wave operated blue-violet laser diodes(LDs) with long lifetime are demonstrated, which are grown on a c-plane GaN substrate by metal organic chemical vapor deposition with a 10 × 600 μm^2 ridge waveguide structure.The electrical and optical characteristics of a blue-violet LD are investigated under direct-current injection at room temperature(25 °C). The stimulated emission wavelength and peak optical power of the LD are around 413 nm and over 600 mW, respectively.In addition, the threshold current density and voltage are as small as 1.46 kA/cm^2 and 4.1 V, respectively. Moreover, the lifetime is longer than 1000 hours under room-temperature continuous-wave operation. 展开更多
关键词 GAN-BASED blue-violet laser DIODES long LIFETIME THRESHOLD voltage
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A rat model of high altitude polycythemia rapidly established by hypobaric hypoxia exposure 被引量:4
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作者 Pei-bing LI Hong-jing NIE +5 位作者 Wei LIU Bing-nan DENG Hui-li ZHU Rui-feng DUAN Zhao-li CHEN Hai WANG 《中国应用生理学杂志》 CAS CSCD 2014年第6期526-531,共6页
Objective To investigate the effects of simple hypobaric hypoxia on parameters of hematology and blood rheology in order to establish a rat model of simulated high altitude polycythemia(HAPC) for the study of pathophy... Objective To investigate the effects of simple hypobaric hypoxia on parameters of hematology and blood rheology in order to establish a rat model of simulated high altitude polycythemia(HAPC) for the study of pathophysiologic mechanisms and medical prevention and treatment of HAPC.Methods Fortyeight male Wistar rats were randomly divided into three normal control groups and three hypoxia model groups.Normal control group rats were bred in normoxia conditions,and hypoxia group rats were subjected to hypoxic exposure for 8 hours per day at simulated 5 500 m high altitude in a hypobaric chamber.After hypoxic exposure for 2,4,12 weeks,one group of normal control and hypoxia model rats were killed and blood was collected,respectively.Then parameters of erythrocyte and blood rheology were examined.Results Mucous membrane of hypoxia model rats showed obviously cyanosis after 2 weeks hypoxic exposure.Hemoglobin concentration of hypoxia model rats were beyond 210 g/L after 2 weeks,4 weeks and 12 weeks hypoxia exposure and significantly increased than that of normal control rats respectively.Besides,RBC counts,hematocrit,whole blood viscosity,erythrocyte aggregation index of hypoxia model rats were all notably higher than those of normal control rats respectively.Conclusion A rat model of high altitude polycythemia can be rapidly established by hypobaric hypoxia exposure at simulated 5 500 m high altitude for 8 hours daily. 展开更多
关键词 红细胞压积 低压缺氧 动物模型 增多症 低氧 高原 WISTAR大鼠 大鼠模型
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