Microstructure evolution of 55Ni−23Cr−13Co nickel-based superalloy during high-temperature cyclic deformation

The cyclic deformation behavior and microstructure evolution of the 55Ni−23Cr−13Co nickel-based superalloy were studied at 750℃ under the strain amplitudes from 0.35%to 0.6%.Coffin−Manson−Basquin and Smith−Watson−Topper relationships were employed,which satisfactorily predicted the fatigue life of the alloy under various strain amplitudes.The superalloy showed an initial cyclic hardening as a result of the interaction between the dislocations and the precipitates,and following cyclic softening behavior mainly due to the shearing of theγ′phase by dislocations and dislocations recovery under all strain amplitudes.Microstructure analyses showed that the M_(23)C_(6) carbides exhibited a continuous-chain distribution at lower strain amplitudes,while they showed a discontinuous distribution at higher strain amplitudes.As the strain amplitude increased,the size of theγ′phase decreased as the consequence of repeated shearing by dislocations.Fracture mechanisms were analyzed.Under higher strain amplitudes,cavities preferred to form around grain boundaries.

Flavonoid oligomers from Chinese dragon’s blood,the red resins of Dracaena cochinchinensis

A detailed chemical investigation of the red resins from Dracaena cochinchinensis(Chinese dragon’s blood)yielded five new flavonoid oligomers,named cochinchinenins D-H(1-5),together with a known biflavonoid,cinnabarone(6),and a mixture of two known biflavonoids,socotrin-4'-ol(7)and homoisosocotrin-4'-ol(8).Of these new compounds,1-3 were biflavonoids and 4 and 5 were triflavonoids.Their structures were determined on the basis of spectroscopic analysis.The isolated compounds were tested for cytotoxicity(Cdc25),antibacterial(PEPT)and antifungal(YNG)activities.

Microstructure and grain boundary engineering of a novel Fe-Cr-Ni alloy weldment made with self-developed composition-matched weld filler metal

The microstructure,texture,and yield strength of an advanced heat-resistant alloy weldment made with composition-matched weld filler were investigated.Scanning electron microscopy,energy dispersive spectroscopy,and electron backscatter diffraction were used to characterize the microstructural and textural changes.Various grain boundary engineering(GBE)processes were performed on the weldment.The yield strengths of the weldment at 973 K were obtained before and after GBE processing,and were mostly consistent with the theoretically predicted values.The coincident-site lattices,misorientation,and recrystallization of the weld metal after GBE were analyzed,and the results indicate that the increase in dislocation density and the improvement in special grain boundaries in the weld metal are the main reasons for the yield strength elevation of the weldment after GBE.The variation in elongation after high-temperature tests has the same tendency as that in the impact toughness with different GBE parameters,which is related to the coarsening behavior of carbides.

Effect of Si content on impact-abrasive wear resistance of Al2O3p/steel composites prepared by squeeze casting

The 40Cr steel matrix composites were reinforced with Al203 particulates （Al2O3p） through Si adding to improve the impact-abrasive wear resistance, in which Si powder ranging up to 25% of the AlzO3p weight was added into the Al2O3p preforms; then, the composites were fabricated by squeeze casting. For all composites, alumina particles are evenly distributed, and Si powder is dissolved in the matrix. Without Si powder addition, the 40Cr steel matrix contains only pearlite; however, ferrite appears and increases with Si powder addition. In the impact-abrasive wear tests, the impact frequency is 80 min^-1 and the impacting energy is 2 J. With increasing Si powder, the wear of the composites first decreases obviously, reaches the minimum at 10% and then increases. The effect of Si addition on the wear resistance can be attributed to two reasons： one is increasing the hardness of the matrix, and the other is improving the interfacial bonding between Al2O3p and steel. The wear mechanism of the composites is abrasive wear when the Si powder is 〈 10 wt%. Otherwise, it is a mixed mode of abrasive and delamination wear.